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Full-Text Articles in Physical Sciences and Mathematics

Imaging Second-Harmonic Radiation And Scattering Patterns In Zno Micro/Nanostructures, Katrina Marie Geren May 2009

Imaging Second-Harmonic Radiation And Scattering Patterns In Zno Micro/Nanostructures, Katrina Marie Geren

Graduate Theses and Dissertations

The optical characteristics of ZnO nanostructures have recently garnered interest due to the inclusion of these structures in many nanoscale optical and optoelectronic devices. This thesis will address several characteristics involving second harmonic generation and scattering in ZnO nano- and microstructures. A method will be presented for determining the nonlinear coefficients of the second order susceptibility in a single ZnO rod. This method uses transmission geometry where previous methods have employed back-reflected irradiation. The nonlinear coefficients found using this new technique were consistent with previous data from similar structures. Models will be presented for predicting the second harmonic scattering patterns …


Synthesis And Characterization Of Homoleptic And Heteroleptic Ruthenium Polypyridine Complexes, Anwar A. Bhuiyan, S. Kudo, C. Wade, R. F. Davis Jan 2009

Synthesis And Characterization Of Homoleptic And Heteroleptic Ruthenium Polypyridine Complexes, Anwar A. Bhuiyan, S. Kudo, C. Wade, R. F. Davis

Journal of the Arkansas Academy of Science

The homoleptic ruthenium(II) complex Ru(C13H10N2)3(PF6)2, and heteroleptic ruthenium(II) complexes Ru(C13H10N2)2(C10H8N2)(PF6)2, and Ru(C13H10N2)(C10H8N2)2(PF6)2 have been prepared by following the standard synthetic procedure. These complexes were then purified by repeated column chromatography. The identity and the integrity of the complexes were confirmed by elemental analysis and mass spectroscopy. The calculated and the experimental values for the elemental analysis were in good agreement. The calculated and the experimental molar masses obtained were also identical. Ultravioletvisible absorption and emission spectroscopic methods were used to investigate the properties of these complexes. The absorption spectra of all complexes consist of a series of absorption bands in …