Physical Sciences and Mathematics | Open Access Articles

Contributions Of Wood Smoke And Vehicle Emissions To Ambient Concentrations Of Volatile Organic Compounds And Particulate Matter During The Yakima Wintertime Nitrate Study, Graham Vanderschelden, Benjamin De Foy, Courtney Herring, Susan D. Kaspari, Tim Vanreken, Bertram Jobson

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A multiple linear regression (MLR) chemical mass balance model was applied to data collected during an air quality field experiment in Yakima, WA, during January 2013 to determine the relative contribution of residential wood combustion (RWC) and vehicle emissions to ambient pollutant levels. Acetonitrile was used as a chemical tracer for wood burning and nitrogen oxides (NOx) as a chemical tracer for mobile sources. RWC was found to be a substantial source of gas phase air toxics in wintertime. The MLR model found RWC primarily responsible for emissions of formaldehyde (73%), acetaldehyde (69%), and black carbon (55%) and mobile sources …

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Twentieth Century Dust Lows And The Weakening Of The Westerly Winds Over The Tibetan Plateau, Bjorn Grigholm, P. A. Mayewski, S. Kang, Y. Zhang, U. Morgenstern, M. Schwikowski, Susan D. Kaspari, V. Aizen, E. Aizen, N. Takeuchi, K. A. Maasch, S. Birkel, M. Handley, S. Sneed

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Understanding past atmospheric dust variability is necessary to put modern atmospheric dust into historical context and assess the impacts of dust on the climate. In Asia, meteorological data of atmospheric dust is temporally limited, beginning only in the 1950s. High‐resolution ice cores provide the ideal archive for reconstructing preinstrumental atmospheric dust concentrations. Using a ~500 year (1477–1982 A.D.) annually resolved calcium (Ca) dust proxy from a Tibetan Plateau (TP) ice core, we demonstrate the lowest atmospheric dust concentrations in the past ~500 years during the latter twentieth century. Declines in late nineteenth to twentieth century Ca concentrations significantly correspond with …

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Optimized Method For Black Carbon Analysis In Ice And Snow Using The Single Particle Soot Photometer, I. A. Wendl, James A. Menking, R. Färber, M. Gysel, Susan D. Kaspari, M. J. G. Laborde, M. Schwikowski

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In this study we attempt to optimize the method for measuring black carbon (BC) in snow and ice using a Single Particle Soot Photometer (SP2). Beside the previously applied ultrasonic (CETAC) and Collison-type nebulizers we introduce a jet (Apex Q) nebulizer to aerosolize the aqueous sample for SP2 analysis. Both CETAC and Apex Q require small sample volumes (a few milliliters) which makes them suitable for ice core analysis. The Apex Q shows the least size-dependent nebulizing efficiency in the BC particle diameter range of 100–1000 nm. The CETAC has the advantage that air and liquid flows can be monitored …

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Seasonal And Elevational Variations Of Black Carbon And Dust In Snow And Ice In The Solu-Khumbu, Nepal And Estimated Radiative Forcings, Susan Kaspari, T. H. Painter, M. Gysel, S. M. Skiles, M. Schwikowski

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Black carbon (BC) and dust deposited on snow and glacier surfaces can reduce the surface albedo, accelerate snow and ice melt, and trigger albedo feedback. Assessing BC and dust concentrations in snow and ice in the Himalaya is of interest because this region borders large BC and dust sources, and seasonal snow and glacier ice in this region are an important source of water resources. Snow and ice samples were collected from crevasse profiles and snow pits at elevations between 5400 and 6400 m a.s.l. from Mera glacier located in the Solu-Khumbu region of Nepal during spring and fall 2009, …

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Influence Of Regional Precipitation Patterns On Stable Isotopes In Ice Cores From The Central Himalayas, H. Pang, S. Hou, Susan Kaspari, P. A. Mayewski

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Several ice cores have been recovered from the Dasuopu (DSP) Glacier and the East Rongbuk (ER) Glacier in the central Himalayas since the 1990s. Although the distance between the DSP and the ER ice core drilling sites is only 125 km, the stable isotopic record (18O or D) of the DSP core is interpreted in previous studies as a temperature proxy, while the ER core is interpreted as a precipitation proxy. Thus, the climatological significance of the stable isotopic records of these Himalayan ice cores remains a subject of debate. Based on analysis of regional precipitation patterns over the region, …

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Atmospheric Circulation Change In The Central Himalayas Indicated By A High-Resolution Ice Core Deuterium Excess Record, Hongxi Pang, Shugui Hou, Susan Kaspari, Paul Mayewski, Douglas Introne, Valérie Masson-Delmotte, Jean Jouzel, Zhenchao Li, Yuanqing He, Sungmin Hong, Dahe Qin

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Continuous measurements of both δD and δ18O were performed along a 108.8 m ice core recovered from the East Rongbuk Glacier on the northeast saddle of Mt. Qomolangma (Everest) (28.03° N, 86.96° E, 6518 m above sea level) in September 2002. They provide the first high-resolution historical record of deuterium excess (d) in the central Himalayas. In this paper, we focus on d variability from 1951 to 2001 and its relationship with large scale atmospheric circulation. The d record exhibits significant seasonal variations, with low values in summer and high values in winter, reflecting the atmospheric circulation shift between winter …

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Estimation Of Iron Solubility From Observations And A Global Aerosol Model, Chao Luo, N. M. Mahowald, N. Meskhidze, Y. Chen, R. L. Siefert, A. R. Baker, Anne M. Johansen

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Mineral aerosol deposition is the dominant source of iron to the open ocean. Soil iron is typically insoluble and understanding the atmospheric processes that convert insoluble iron to the more soluble forms observed over the oceans is crucial. In this paper, we model several proposed processes for the conversion of Fe(III) to Fe(II), and compare with cruise observations. The comparisons show that the model results in similar averaged magnitudes of iron solubility as measured during 8 cruises in 2001–2003. Comparisons show that results of cases including cloud, SO₂ and hematite processing are better than the other approaches used using …

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Chemical Characterization Of Ambient Aerosol Collected During The Northeast Monsoon Season Over The Arabian Sea: Anions And Cations, Anne M. Johansen, Michael R. Hoffmann

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Ambient aerosol samples were collected over the Arabian Sea during the month of March 1997, aboard the German R/V Sonne, as part of the German JGOFS project (Joint Global Ocean Flux Study). This is the third study in a series of analogous measurements taken over the Arabian Sea during different seasons of the monsoon. Dichotomous high volume collector samples were analyzed for anions and cations upon return to the laboratory. Anthropogenic pollutant concentrations were larger during the first part of the cruise, when air masses originated over the Indian subcontinent. Total NSS‐SO₄²⁻ concentrations amounted to 2.94 ± …

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Chemical Characterization Of Ambient Aerosol Collected During The Northeast Monsoon Season Over The Arabian Sea: Labile-Fe(Ii) And Other Trace Metals, Anne M. Johansen, Michael R. Hoffmann

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Ambient aerosol samples were collected over the Arabian Sea during the month of March of 1997, aboard the German R/V Sonne, as part of the German Joint Global Ocean Flux Study (JGOFS) project. This is the third study in a series of analogous measurements taken over the Arabian Sea during different seasons of the monsoon. Dichotomous high‐volume collector samples were analyzed for ferrous iron immediately after collection, while trace metals, anions, and cations were determined upon return to the laboratory. The main crustal component was geochemically well represented by the average crustal composition and amounted to 5.94 ± 3.08 …

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Atmospheric Turbulence Conditions Leading To Focused And Folded Sonic Boom Wave Fronts, Andrew A. Piacsek

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The propagation and subsequent distortion of sonic booms with rippled wave fronts are investigated theoretically using a nonlinear time-domain finite-difference scheme. This work seeks to validate the rippled wave front approach as a method for explaining the significant effects of turbulence on sonic booms [A. S. Pierce and D. J. Maglieri, J. Acoust. Soc. Am. 51, 702–721 (1971)]. A very simple description of turbulence is employed in which velocity perturbations within a shallow layer of the atmosphere form strings of vortices characterized by their size and speed. Passage of a steady-state plane shock front through such a vortex layer …

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Full-Text Articles in Physical Sciences and Mathematics

Contributions Of Wood Smoke And Vehicle Emissions To Ambient Concentrations Of Volatile Organic Compounds And Particulate Matter During The Yakima Wintertime Nitrate Study, Graham Vanderschelden, Benjamin De Foy, Courtney Herring, Susan D. Kaspari, Tim Vanreken, Bertram Jobson

All Faculty Scholarship for the College of the Sciences

Twentieth Century Dust Lows And The Weakening Of The Westerly Winds Over The Tibetan Plateau, Bjorn Grigholm, P. A. Mayewski, S. Kang, Y. Zhang, U. Morgenstern, M. Schwikowski, Susan D. Kaspari, V. Aizen, E. Aizen, N. Takeuchi, K. A. Maasch, S. Birkel, M. Handley, S. Sneed

All Faculty Scholarship for the College of the Sciences

Optimized Method For Black Carbon Analysis In Ice And Snow Using The Single Particle Soot Photometer, I. A. Wendl, James A. Menking, R. Färber, M. Gysel, Susan D. Kaspari, M. J. G. Laborde, M. Schwikowski

All Faculty Scholarship for the College of the Sciences

Seasonal And Elevational Variations Of Black Carbon And Dust In Snow And Ice In The Solu-Khumbu, Nepal And Estimated Radiative Forcings, Susan Kaspari, T. H. Painter, M. Gysel, S. M. Skiles, M. Schwikowski

All Faculty Scholarship for the College of the Sciences

Influence Of Regional Precipitation Patterns On Stable Isotopes In Ice Cores From The Central Himalayas, H. Pang, S. Hou, Susan Kaspari, P. A. Mayewski

All Faculty Scholarship for the College of the Sciences

Atmospheric Circulation Change In The Central Himalayas Indicated By A High-Resolution Ice Core Deuterium Excess Record, Hongxi Pang, Shugui Hou, Susan Kaspari, Paul Mayewski, Douglas Introne, Valérie Masson-Delmotte, Jean Jouzel, Zhenchao Li, Yuanqing He, Sungmin Hong, Dahe Qin

All Faculty Scholarship for the College of the Sciences

Estimation Of Iron Solubility From Observations And A Global Aerosol Model, Chao Luo, N. M. Mahowald, N. Meskhidze, Y. Chen, R. L. Siefert, A. R. Baker, Anne M. Johansen

All Faculty Scholarship for the College of the Sciences

Chemical Characterization Of Ambient Aerosol Collected During The Northeast Monsoon Season Over The Arabian Sea: Anions And Cations, Anne M. Johansen, Michael R. Hoffmann

All Faculty Scholarship for the College of the Sciences

Chemical Characterization Of Ambient Aerosol Collected During The Northeast Monsoon Season Over The Arabian Sea: Labile-Fe(Ii) And Other Trace Metals, Anne M. Johansen, Michael R. Hoffmann

All Faculty Scholarship for the College of the Sciences

Atmospheric Turbulence Conditions Leading To Focused And Folded Sonic Boom Wave Fronts, Andrew A. Piacsek

All Faculty Scholarship for the College of the Sciences