Physical Sciences and Mathematics Commons^™

Identification And Characterization Of Fine Particulate Matter Hot Spots On An Urban Arterial Corridor Integrating Probe Vehicle, Traffic And Land Use Data, Katherine Eleanor Bell

Dissertations and Theses

The purpose of this study is to explore the use of integrated probe vehicle, traffic and land use data to identify and characterize fine particulate matter (PM[subscript 2.5]) hot spot locations on urban arterial corridors. In addition, a preliminary analysis is conducted to consider volatile organic compound (VOC) hot spot locations. A pollutant hot spot is defined as a location on a corridor in which the mean pollutant concentrations are consistently above the 85th percentile of pollutant concentrations when compared to all locations along the corridor. In order to collect data for this study, an electric vehicle was equipped with …

Methyl Halide Production By Calcareous Periphyton Mats From The Florida Everglades, Ann Eileen Raffel

Dissertations and Theses

Methyl halides are trace gases with both natural and anthropogenic origins. Once generated, these gases transport chlorine and bromine into the stratosphere, where they play an important role in ozone depleting catalytic cycles. The Florida Everglades is one location where methyl halide emissions have been proposed to be elevated due to high primary production and ionic halogens. This region also provides a unique study environment due to salt water intrusions, which occur during storm or low marsh water level-high tide events. The purpose of this research was twofold. First, quantification of methyl chloride (CH₃Cl) and methyl bromide (CH …

Effects Of Runoff Sensitivity And Catchment Characteristics On Regional Actual Evapotranspiration Trends In The Conterminous Us, Il-Won Jung, Heejun Chang, John Risley

Geography Faculty Publications and Presentations

An understanding of the role of hydro-climatic and geographic regimes on regional actual evapotranspiration (AET) change is essential to improving our knowledge on predicting water availability in a changing climate. This study investigates the relationship between AET change for a 60 year period (1951–2010) and the runoff sensitivity in 255 undisturbed catchments over the US. The runoff sensitivity to climate change is simply defined as the relative magnitude between runoff and precipitation changes with time. Runoff sensitivity can readily explain the conflicting directions of AET changes under similar precipitation change. Under increasing precipitation, AET decreases when runoff is increasing more …

Characterization Of Secondary Organic Aerosol Precursors Using Two-Dimensional Gas Chromatography With Time Of Flight Mass Spectrometry (Gc×Gc/Tofms), Melissa Jordan Roskamp

Dissertations and Theses

The oxidation of volatile organic compounds (VOCs) plays a role in both regional and global air quality through the formation of secondary organic aerosols (SOA). More than 1000TgC/yr of non-methane VOCs are emitted from biogenic sources (significantly greater than from anthropogenic sources). Despite this magnitude and potential importance for air quality, the body of knowledge around the identities, quantities and oxidation processes of these compounds is still incomplete (e.g., Goldstein & Galbally, 2007; Robinson et al., 2009). Two-dimensional gas chromatography paired with time-of-flight mass spectrometry (GC×GC/TOFMS) is a powerful analytical technique which is explored here for its role in better …

Incorporating Chemical Activity And Relative Humidity Effects In Regional Air Quality Modeling Of Organic Aerosol Formation, Marguerite Colasurdo Marks

Dissertations and Theses

Atmospheric particulate matter is known to have significant effects on human health, visibility, and global climate. The magnitudes of these effects, however, depend in complex ways on chemical composition, relative humidity, temperature, phase state, and other parameters. Current regional air quality models such as CMAQ (Community Multiscale Air Quality model) ignore many of these considerations, and consider that the formation of secondary organic aerosol (SOA) can be calculated by assuming thermodynamic ideality in the organic particulate matter (OPM) phase as well as negligible uptake of water into the OPM phase. Theoretical predictions and model simulations considering non-ideality and water uptake …

Classifying Reanalysis Surface Temperature Probability Density Functions (Pdfs) Over North America With Cluster Analysis, Paul C. Loikith, Benjamin R. Lintner, Jinwon Kim, Huikyo Lee

Geography Faculty Publications and Presentations

An important step in projecting future climate change impacts on extremes involves quantifying the underlying probability distribution functions (PDFs) of climate variables. However, doing so can prove challenging when multiple models and large domains are considered. Here an approach to PDF quantification using k-means clustering is considered. A standard clustering algorithm (with k = 5 clusters) is applied to 33 years of daily January surface temperature from two state-of-the-art reanalysis products, the North American Regional Reanalysis and the Modern Era Retrospective Analysis for Research and Applications. The resulting cluster assignments yield spatially coherent patterns that can be broadly related to …

Interspecific Variation In Leaf-Level Biogenic Emissions Of The Bambuseae, Andrea Natalie Melnychenko

Dissertations and Theses

Plants emit a diverse range of biogenic volatile organic compounds (BVOCs) into the atmosphere, of which isoprene is the most abundantly emitted. Isoprene significantly affects biological and atmospheric processes, but the range of isoprene and BVOCs present in bamboos has not been well characterized. In this thesis I explore the range of isoprene emission found in bamboos and relate it to plant morphological and physiological characteristics. In addition, I measure and relate the entire suite of BVOCs present in the bamboos to their fundamental isoprene emission rate.

Interspecific variation in isoprene emission documented in a comprehensive survey of bamboos. Two …

The Production Of Organic Nitrates In Portland Oregon And The Columbia River Gorge, Holly Ann Neill

Dissertations and Theses

This work studied the production of aerosol-phase organic nitrates in both Portland and the Columbia River Gorge (CRG). Ozone and NO_x species were investigated for correlation with organic nitrate aerosol, as they function as precursors to the production of organic nitrates. These ambient gas-phase measurements were collected in the same locations as high-volume (Hi-Vol) filters samples, in an urban and rural gorge setting to investigate correlations at the origin of the pollution plume and downwind. A novel Soxhlet extraction method for Hi-Vol filters was developed based on literature and EPA standard methods. Analysis for nitrate production was done by …

Effects Of Molecular Structure Of The Oxidation Products Of Reactive Atmospheric Hydrocarbons On The Formation Of Secondary Organic Particulate Matter, Including The Effects Of Water, Negar Niakan

Dissertations and Theses

Organic aerosols have significant effects on human health, air quality and climate. Secondary organic aerosols (SOA) are produced by the oxidation of primary-volatile organic compounds (VOC). For example, α-pinene reacts with oxidants such as hydroxyl radical (OH), ozone (O₃), and nitrate radical (NO₃), accounting for a significant portion of total organic aerosol in the atmosphere. Experimental studies have shown that the oxidation process between α-pinene and ozone has the most significant impact in the formation of SOA (Hoffmann et al., 1997). Most of the models used to predict SOA formation, however, are limited in that they …

Analyzing Experimental Data And Model Parameters: Implications For Predictions Of Soa Using Chemical Transport Models, Kelley Barsanti, Annmarie G. Carlton, Serena H. Chung

Civil and Environmental Engineering Faculty Publications and Presentations

Despite critical importance for air quality and climate predictions, accurate representation of secondary organic aerosol (SOA) formation remains elusive. An essential addition to the ongoing discussion of improving model predictions is an acknowledgement of the linkages between experimental conditions, parameter optimization and model output, as well as the linkage between empirically-derived partitioning parameters and the physicochemical properties of SOA they represent in models. In this work, a "best available" set of SOA modeling parameters is selected by comparing predicted SOA yields and mass concentrations with observed yields and mass concentrations from a comprehensive list of published smog chamber studies. Evaluated …