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Full-Text Articles in Physical Sciences and Mathematics

Measurement Of Proton Transfer Reaction Rates In A Microwave Cavity Discharge Flowing Afterglow, George M. Brooke Iv Apr 2003

Measurement Of Proton Transfer Reaction Rates In A Microwave Cavity Discharge Flowing Afterglow, George M. Brooke Iv

Physics Theses & Dissertations

The reaction rate coefficients between the hydronium ion and the molecules ethene (C2H4), propene (C3H6), 1-butene (C4H8) and hydrogen sulfide (H2S) were measured at 296 K. The measured reaction rates were compared to collision rates calculated using average dipole orientation (ADO) theory. Reaction efficiency depends primarily upon the proton affinity of the molecules. All the measurements were obtained using the newly developed microwave cavity discharge flowing afterglow (MCD-FA) apparatus. This device uses an Asmussen-type microwave cavity discharge ion source that is …


Near-Surface Currents In Desoto Canyon (1997–99): Comparison Of Current Meters, Satellite Observation, And Model Simulation, Dong-Ping Wang, Lie-Yauw Oey, Tal Ezer, Peter Hamilton Jan 2003

Near-Surface Currents In Desoto Canyon (1997–99): Comparison Of Current Meters, Satellite Observation, And Model Simulation, Dong-Ping Wang, Lie-Yauw Oey, Tal Ezer, Peter Hamilton

CCPO Publications

This study evaluates a data-assimilated model simulation of near-surface circulation in DeSoto Canyon (DSC), Gulf of Mexico, with emphasis on analyzing moored current-meter observations and comparing them with satellite data and model results. The study period is for two years from April 1997 to April 1999. The model results are from a high-resolution Gulf of Mexico model forced by analyzed wind and surface heat flux. Two types of data are used to deduce near-surface circulation: moored current meters at 13 locations in the DSC, and satellite sea level anomaly. The moored currents are mapped through multivariate objective analysis to produce …


New Evidence For Enhanced Ocean Primary Production Triggered By Tropical Cyclone, I. Lin, W. Timothy Liu, Chun-Chieh Wu, George T. F. Wong, Chuanmin Hu, Zhiqiang Chen, Wen-Der Liang, Yih Yang, Kon-Kee Liu Jan 2003

New Evidence For Enhanced Ocean Primary Production Triggered By Tropical Cyclone, I. Lin, W. Timothy Liu, Chun-Chieh Wu, George T. F. Wong, Chuanmin Hu, Zhiqiang Chen, Wen-Der Liang, Yih Yang, Kon-Kee Liu

OES Faculty Publications

[1] New evidence based on recent satellite data is presented to provide a rare opportunity in quantifying the long-speculated contribution of tropical cyclones to enhance ocean primary production. In July 2000, moderate cyclone Kai-Tak passed over the South China Sea (SCS). During its short 3-day stay, Kai-Tak triggered an average 30-fold increase in surface chlorophyll-a concentration. The estimated carbon fixation resulting from this event alone is 0.8 Mt, or 2-4% of SCS's annual new production. Given an average of 14 cyclones passing over the SCS annually, we suggest the long-neglected contribution of tropical cyclones to SCS's annual new production may …