Physical Sciences and Mathematics Commons^™

Diffuse Spectra Model Of Photoluminescence In Carbon Quantum Dots, S. E. Kumekov, N. K. Saitova, Karen S. Martirosyan

Physics and Astronomy Faculty Publications and Presentations

The attractive aspect of excitation related to fluorescence nature in carbon quantum dots (CQD) has guided to several assumptions correlated with clusters size distribution, shapes as well as presence of different emissive states. In this study, a dimer–excimer model of photoluminescence (PL) in CQD describing discrete multiple electronic states for the excitation-dependent emission is described. The functional dependence of the characteristic width of the diffuse spectra of PL on the size of a quantum dots are calculated. The effective width of PL spectrum can be tuned from 0.1 to 1 eV.

Measurements Of The 16c + 12c And 16c + 13c Fusion Cross Sections With Implications For Astrophysics, Ashley Ann Hood

LSU Doctoral Dissertations

The fusion of neutron-rich nuclei is of interest to nuclear astrophysics and nuclear structure. X-ray superbursts are powered by runaway thermonuclear burning deep inside of a neutron star, where heating from the pycnonuclear fusion of neutron-rich isotopes is an important heat source. Experimental measurements of fusion cross sections of neutron-rich isotopes have provided insights regarding nucleon transfer and nuclear structure properties affecting fusion. Recently, the ¹⁵C + ¹²C total fusion cross section was measured using a ¹⁵C beam produced by the in-flight beam production facility, which is part of the Argonne Tandem LINAC Accelerator System (ATLAS) at …

Astromimetics: The Dawn Of A New Era For (Bio)Materials Science?, Vuk Uskoković, Victoria M. Wu

Pharmacy Faculty Articles and Research

Composite, multifunctional fine particles are likely to be at the frontier of materials science in the foreseeable future. Here we present a submicron composite particle that mimics the stratified structure of the Earth by having a zero-valent iron core, a silicate/silicide mantle, and a thin carbonaceous crust resembling the biosphere and its biotic deposits. Particles were formulated in a stable colloidal form and made to interact with various types of healthy and cancer cells in vitro. A selective anticancer activity was observed, promising from the point of view of the intended use of the particles for tumor targeting across the …

Thin Film Carbon Nanofuses For Permanent Data Storage, Kevin Robert Laughlin

Theses and Dissertations

We have fabricated nanofuses from thin-film, arc-evaporation carbon for use in permanent data storage. Thin film carbon fuses have fewer fabrication barriers and retain the required resistivity and structural stability to work as a data storage medium. Carbon thin films were characterized for their electrical, microstructural, and chemical bonding properties. Annealing the thin-film carbon in an argon environment at 400°C reduced the resistivity from about 4*10^-2 Ω cm as deposited down to about 5*10^-4 Ω cm, allowing a lower blowing voltage. Nanofuses with widths ranging from 200 nm down to 60 nm were fabricated and tested. They blow …

Crystallographically-Oriented Carbon Nanotubes Grown On Few-Layer Graphene Films, Douglas R. Strachan, David P. Hunley

Physics and Astronomy Faculty Patents

A thermal and electrical conducting apparatus includes a few-layer graphene film having a thickness D where D≦1.5 nm and a plurality of carbon nanotubes crystallographically aligned with the few-layer graphene film.

Crystallographically-Oriented Carbon Nanotubes Grown On Few-Layer Graphene Films, David P. Hunley, Douglas R. Strachan

Physics and Astronomy Faculty Patents

A thermal and electrical conducting apparatus includes a few-layer graphene film having a thickness D where D≦1.5 nm and a plurality of carbon nanotubes crystallographically aligned with the few-layer graphene film.

Small Carbon Chains In Circumstellar Envelopes, R. J. Hargreaves, K. Hinkle, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Observations of carbon-rich circumstellar envelopes were made using the Phoenix spectrograph on the Gemini South telescope to determine the abundance of small carbon chain molecules. Vibration-rotation lines of the ν3 antisymmetric stretch of C₃ near 2040 cm^-1 (4.902 μm) have been used to determine the column density for four carbon-rich circumstellar envelopes: CRL 865, CRL 1922, CRL 2023 and IRC +10216. We additionally calculate the column density of C₅ for IRC +10216, and provide an upper limit for five more objects. An upper limit estimate for the C₇ column density is also provided for IRC+10216. A …

Line Lists For The A2Π-X 2Σ+ (Red) And B2Σ+-X 2Σ+ (Violet) Systems Of Cn, 13c14n, And 12c15n, And Application To Astronomicalspectra, Christopher Sneden, Sara Lucatello, Ram S. Ram, James S. A. Brooke, Peter Bernath

Chemistry & Biochemistry Faculty Publications

New red and violet system line lists for the CN isotopologues ¹³C¹⁴N and ¹²C¹⁵N have been generated. These new transition data are combined with those previously derived for ¹²C¹⁴N, and applied to the determination of CNO abundances in the solar photosphere and in four red giant stars: Arcturus, the bright, very low-metallicity star HD 122563, and the carbon-enhanced metal-poor stars HD 196944 and HD 201626. When both red and violet system lines are detectable in a star, their derived N abundances are in good agreement. The mean N abundances determined in …

Search For Higgs Shifts In White Dwarfs, Roberto Onofrio, Gary A. Wegner

Dartmouth Scholarship

We report on a search for differential shifts between electronic and vibronic transitions in carbon-rich white dwarfs BPM 27606 and Procyon B. The absence of differential shifts within the spectral resolution and taking into account systematic effects such as space motion and pressure shifts allows us to set the first upper bound of astrophysical origin on the coupling between the Higgs field and the Kreschmann curvature invariant. Our analysis provides the basis for a more general methodology to derive bounds to the coupling of long-range scalar fields to curvature invariants in an astrophysical setting complementary to the ones available from …

Improved Line Data For The Swan System 12c13c Isotopologue, Ram S. Ram, James S. A. Brooke, Peter F. Bernath, Christopher Sneden, Sara Lucatello

Chemistry & Biochemistry Faculty Publications

We present new, accurate predictions for rotational line positions, excitation energies, and transition probabilities of the ¹²C ¹³C isotopologue Swan d³Π-a³Π system 0-0, 0-1, 0-2, 1-0, 1-1, 1-2, 2-0, 2-1, and 2-2 vibrational bands. The line positions and energy levels were predicted through new analyses of published laboratory data for the ¹²C¹³C lines. Transition probabilities were derived from recent computations of transition dipole moments and related quantities. The ¹²C¹³C line data were combined with similar data for ¹²C₂, reported in a companion paper, and applied …

Ch In Stellar Atmospheres: An Extensive Linelist, T. Masseron, B. Plez, S. Van Eck, R. Colin, I. Daoutidis, M. Godefroid, P.-F. Coheur, P. Bernath, A. Jorissen, N. Christleib

Chemistry & Biochemistry Faculty Publications

The advent of high-resolution spectrographs and detailed stellar atmosphere modelling has strengthened the need for accurate molecular data. Carbon-enhanced metal-poor (CEMP) stars spectra are interesting objects with which to study transitions from the CH molecule. We combine programs for spectral analysis of molecules and stellar-radiative transfer codes to build an extensive CH linelist, including predissociation broadening as well as newly identified levels. We show examples of strong predissociation CH lines in CEMP stars, and we stress the important role played by the CH features in the Bond-Neff feature depressing the spectra of barium stars by as much as 0.2 mag …

A Study Of Carbon Features In Type Ia Supernova Spectra, Jerod T. Parrent, R. C. Thomas, Robert A. Fesen, G. H. Marion

Dartmouth Scholarship

One of the major differences between various explosion scenarios of Type Ia supernovae (SNe Ia) is the remaining amount of unburned (C+O) material and its velocity distribution within the expanding ejecta. While oxygen absorption features are not uncommon in the spectra of SNe Ia before maximum light, the presence of strong carbon absorption has been reported only in a minority of objects, typically during the pre-maximum phase. The reported low frequency of carbon detections may be due to low signal-to-noise data, low abundance of unburned material, line blending between C II 6580 and Si II 6355, ejecta temperature differences, asymmetrical …

Metallic Nanoscale Fibers From Stable Iodine-Doped Carbon Nanotubes, Peter C. Eklund, Leonid Grigorian, Keith A. Williams, Gamini U. Sumanasekera, Shaoli Fang

Physics and Astronomy Faculty Patents

A method of doping involves soaking single-walled carbon nanotubes in molten iodine. Excess physisorbed iodine may then be removed by annealing.

Optically Thin Broad-Line Clouds In Active Galactic Nuclei, Joseph C. Shields, Gary J. Ferland, Bradley M. Peterson

Physics and Astronomy Faculty Publications

The broad-line region (BLR) in Seyfert galaxy nuclei exhibits correlated variations in continuum and emission-line luminosity that are qualitatively consistent with photoionization of ionization-bounded (optically thick) clouds. However, evidence is growing that a nonnegligible fraction of the BLR cloud population is optically thin to the Lyman continuum and fully ionized in hydrogen. We consider the implications of this nebular component for observed line emission and find that inclusion of thin clouds in photoionization calculations can resolve several outstanding puzzles of Seyfert variability, notably the behavior of the C IV λ1549/Lyα ratio as a function of continuum luminosity.

A …

Uv Observations Of The Cool Dbqa5 White Dwarf Lds 678a - Limits On The Atmospheric Composition, Pressure Shift, And Gravitational Redshift Derived From C I 2479, Terry D. Oswalt, Edward M. Sion, Gordon Hammond, Gerard Vauclair, James W. Liebert, Gary Wegner

Dartmouth Scholarship

A high-resolution ultraviolet spectrum of the helium-rich degenerate LDS 678A, obtained with the International Ultraviolet Explorer (IUE) satellite, is presented. LDS 678A is the coolest metallic line degenerate (DQ or DZ) yet observed with the IUE echelle. These observations provide a detailed line profile of the strong C I 2479 absorption line and equivalent width W2479 = 2.35 + or - 0.06 A from which theoretical profile fits yield a carbon abundance of log C/He = (-6.7 + or- 0.2). The presence of carbon in a He-rich atmosphere lends credence to the notion that LDS 678A is a transitional case …

Iue Observations Of Dq Herculis And Its Nebula, And The Nature Of The Cold Nova Shells, Gary J. Ferland, R. E. Williams, D. L. Lambert, G. A. Shields, M. Slovak, P. M. Gondhalekar, J. W. Truran

Physics and Astronomy Faculty Publications

The nebula ejected in the 1934 outburst of the classical nova DQ Her is remarkable for its unprecedentedly low temperature of T_e 500 K as measured by Williams et al. (1978). In this paper, IUE observations are combined with Steward optical spectra. It is confirmed that the gas is quite cold. It is further shown that the gas is ionized by the radiation field of the central object. X-ray, ultraviolet, optical and infrared observations of the underlying binary are combined with the extreme-ultraviolet continuum deduced from the level of ionization of the nebula to obtain a composite energy …

Physical Conditions In The Accretion Disk Of V603 Aquilae, Gary J. Ferland, D. L. Lambert, M. L. Mccall, G. A. Shields, M. Slovak

Physics and Astronomy Faculty Publications

Ultraviolet and optical spectra of the old nova V603 Aql are discussed. The UV-optical continuum is dominated by emission from the accretion disk. Emission lines from ions of H, He, C, N, and 0 are identified. These lines are probably formed in a circumstellar shell with radius comparable to the binary separation, density ~10¹⁰ cm^-3, and a roughly solar chemical composition. This corona is probably heated by radiation emitted by the underlying accretion disk. Photoionization calculations of the structure and emission-line spectrum of the corona are presented, and the effects of this gas on the X-ray continuum …

Preliminary Report On Iue Spectra Of Crab Nebula, K. Davidson, T. R. Gull, S. P. Maran, T. P. Stecher, Menas Kafatos, V. L. Trimble

Mathematics, Physics, and Computer Science Faculty Books and Book Chapters

The Crab Nebula is marginally observable with the IUE. Observations of the optically brightest filamentary regions, made with IUE in August 1979, show the C IV x1549, He II x1640, and C III] x1909 emission lines. The intensities of these lines have been compared with visual-wavelength data. It appears that carbon is not overabundant in the Crab; carbon/- oxygen is approximately "normal" oxygen is slightly scarcer than "normal" as a fraction of the total mass.

Β-Delayed Proton Decay Of 9c, David D. Allred, John E. Esterl, J. C. Hardy, R. G. Sextro, Joseph Cerny

Faculty Publications

The delayed-proton spectrum following the β decay of 9C (t1/2=126.5±1.0 msec) was found to consist primarily of a continuum extending from 13 to 1.5 MeV, the latter being the lowest energy observed. In addition to the previously observed peaks at 9.28 and 12.30 MeV (C.M.), possible peaks between 3 and 7 MeV have been tentatively identified.