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Comparing Theory And Experiment For Analyte Transport In The First Vacuum Stage Of The Inductively Coupled Plasma Mass Spectrometer, Matthew R. Zachreson
Comparing Theory And Experiment For Analyte Transport In The First Vacuum Stage Of The Inductively Coupled Plasma Mass Spectrometer, Matthew R. Zachreson
Theses and Dissertations
The Direct Simulation Monte Carlo algorithm as coded in FENIX is used to model the transport of trace ions in the first vacuum stage of the inductively coupled plasma mass spectrometer. Haibin Ma of the Farnsworth group at Brigham Young University measured two radial trace density profiles: one 0.7 mm upstream of the sampling cone and the other 10 mm downstream. We compare simulation results from FENIX with the experimental results. We find that gas dynamic convection and diffusion are unable to account for the experimentally-measured profile changes from upstream to downstream. Including discharge quenching and ambipolar electric fields, however, …