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Physical Sciences and Mathematics Commons

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Applied Mathematics

2012

Articles

Thermodynamic constraints

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Full-Text Articles in Physical Sciences and Mathematics

Second Gradient Viscoelastic Fluids: Dissipation Principle And Free Energies, G. Amendola, M. Fabrizio, John Murrough Golden Jan 2012

Second Gradient Viscoelastic Fluids: Dissipation Principle And Free Energies, G. Amendola, M. Fabrizio, John Murrough Golden

Articles

We consider a generalization of the constitutive equation for an incompressible second order fluid, by including thermal and viscoelastic effects in the expression for the stress tensor. The presence of the histories of the strain rate tensor and its gradient yields a non-simple material, for which the laws of thermodynamics assume a modified form. These laws are expressed in terms of the internal mechanical power which is evaluated, using the dynamical equation for the fluid. Generalized thermodynamic constraints on the constitutive equation are presented. The required properties of free energy functionals are discussed. In particular, it is shown that they …