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Analytical Chemistry

UNLV Theses, Dissertations, Professional Papers, and Capstones

Theses/Dissertations

Thulium

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Full-Text Articles in Physical Sciences and Mathematics

Separation Of Neighboring Trivalent Lanthanides For Neutron Capture Cross Section Measurements, Balazs Jozsef Bene May 2018

Separation Of Neighboring Trivalent Lanthanides For Neutron Capture Cross Section Measurements, Balazs Jozsef Bene

UNLV Theses, Dissertations, Professional Papers, and Capstones

The determination of the low-energy neutron capture cross-section of 171Tm with greater accuracy is important for both astrophysics and Stockpile Stewardship. Thulium-171 is a branching point in the s-process of stellar nucleosynthesis. Branching point nuclei, with half-lives in the order of 1 – 100 years are places where neutron capture and beta decay competes. This isotope is also the second order (n, γ) reaction product of 169Tm, which was used as a radiochemical detector in nuclear weapon experiments. It was placed at strategic locations in nuclear devices. Following the test, samples were analyzed in the collected samples for products of …


Intragroup Separation Of Trivalent Lanthanides And Actinides For Neutron Capture Experiments In Stockpile Stewardship Sciences, Narek Gharibyan Dec 2011

Intragroup Separation Of Trivalent Lanthanides And Actinides For Neutron Capture Experiments In Stockpile Stewardship Sciences, Narek Gharibyan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Knowledge of low-energy cross sections for stable and unstable nuclei in neutron-, γ- and ion induced reactions is important in both the simulation and radiochemistry diagnosis of nuclear device performance. This dissertation explores extraction chromatography and ion chromatography methods for the intragroup separation of trivalent actinides and lanthanides in support of cross section measurements for isotopes of interest. For trivalent actinides, americium (Am(III)) and curium (Cm(III)), separation is necessary to assist in experiments related to the measurement of neutron capture cross section for 241 Am and the production of 242 m Am/242g Am isomeric ratio. Extraction chromatography resins …