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Analytical Chemistry

University of Massachusetts Amherst

Flow models

Publication Year

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Full-Text Articles in Physical Sciences and Mathematics

Applications Of Controlled Dispersion Flow Injection Techniques, Julian Tyson Jan 1988

Applications Of Controlled Dispersion Flow Injection Techniques, Julian Tyson

Chemistry Department Faculty Publication Series

No abstract provided.


Models For Dispersion In Flow Injection Analysis Part 1. Basic Requirements And Study Of Factors Affecting Dispersion, David C. Stone, Julian Tyson Jan 1987

Models For Dispersion In Flow Injection Analysis Part 1. Basic Requirements And Study Of Factors Affecting Dispersion, David C. Stone, Julian Tyson

Chemistry Department Faculty Publication Series

The various approaches adopted for accounting for dispersion behaviour in flow injection analysis are examined and the advantages of a modelling approach are discussed. The variation of the dispersion coefficient as a function of (a) flow-rate, (b) tube length, (c) tube inner diameter and (d) method of injection obtained under typical flow injection conditions are studied and discussed. Explanations for some of the effects observed are presented in terms of molecular diffusion and convective flow patterns. The advantages of "time" injection over the more usual "slug" injection are clearly demonstrated and the use of the single well stirred tank model …