Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Analytical Chemistry

University of Massachusetts Amherst

2014

Raman spectroscopy

Articles 1 - 1 of 1

Full-Text Articles in Physical Sciences and Mathematics

Modification Of Gold Nanoparticles For Sers Application In Emulsion And Lipid Systems, Michael J. Driver Nov 2014

Modification Of Gold Nanoparticles For Sers Application In Emulsion And Lipid Systems, Michael J. Driver

Masters Theses

Gold nanoparticles produced using the Turkevich method were able to have their hydrophobicity modified using octanethiol in a novel method for SERS application. Both amphiliphic GNPs and hydrophobic GNPs were produced and differentiated by Raman signals. The amphiliphic GNPs were able to enhance the SERS signals of the protein emulsifier in the emulsion in situ and the hydrophobic GNPs were able to enhance the SERS signals from canola oil. Further purification of the hydrophobic GNPs proved to have higher enhancement and sensitivity, but still poor consistency which is typical of SERS. Monitoring lipid oxidation using Raman and SERS using alternative …