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Articles 1 - 4 of 4
Full-Text Articles in Physical Sciences and Mathematics
Luminol/Sulfamic Acid Electrochemiluminescence And Its Application For Dopamine Detection, Hailemariam Barkae Tesfaye, Ibrahim Halawa Mohamed, Haile Fereja Tadesse, Addisu Kitte Shimeles, Ma Xian-Gui, Chen Ye-Quan, Xu Guo-Bao
Luminol/Sulfamic Acid Electrochemiluminescence And Its Application For Dopamine Detection, Hailemariam Barkae Tesfaye, Ibrahim Halawa Mohamed, Haile Fereja Tadesse, Addisu Kitte Shimeles, Ma Xian-Gui, Chen Ye-Quan, Xu Guo-Bao
Journal of Electrochemistry
Herein, sulfamic acid (SA) was utilized, for the first time, to enhance significantly the luminol electrochemiluminescence (ECL). With the SA concentration increased from 0.1 μmol·L-1 to 500 μmol·L-1 the ECL intensity increased proportionally. The developed luminol/SA ECL system was employed to detect dopamine (DA) based on its prominent quenching effect. The Stern-Volmer equation of Io/I= 1+Ksv[DA] could be applied to express well the quenching mechanism of DA in the luminol/SA ECL system. The calibration plot showed that the increase in the DA concentration from 0.5 to 20 μmol·L-1 decreased linearly the ECL intensity …
A Facile Strategy For Two-Step Fabrication Of Gold Nanoelectrode For In Vivo Dopamine Detection, Li-Hao Guan, Chao Wang, Wang Zhang, Yu-Lu Cai, Kai Li, Yu-Qing Lin
A Facile Strategy For Two-Step Fabrication Of Gold Nanoelectrode For In Vivo Dopamine Detection, Li-Hao Guan, Chao Wang, Wang Zhang, Yu-Lu Cai, Kai Li, Yu-Qing Lin
Journal of Electrochemistry
In vivo monitoring neurochemicals with microelectrode is invasive and the damage to brain tissue may inevitably cause disturbance signals physiologically to the measurement. It is of great importance to reduce the electrode size and to decrease the damage. This study demonstrates a novel nanoelectrode preparation methodology for in vivo monitoring dopamine (DA) fluctuation in the living brain of rats with high dependability. The fabrication process of the gold nanoelectrode involving a few minutes consists of only two steps: 1) growing gold nanoseeds on surface of tip of glassy capillary by ion sputtering; 2) wet depositing a continuous conductive gold film …
Synthesis Of Keggin Polyoxometalates Modified Carbon Paste Electrode As A Sensor For Dopamine Detection, Peng-Fei Dong, Na Li, Hai-Yan Zhao, Min Cui, Cong Zhang, Ju-Jie Ren, Xue-Ping Ji
Synthesis Of Keggin Polyoxometalates Modified Carbon Paste Electrode As A Sensor For Dopamine Detection, Peng-Fei Dong, Na Li, Hai-Yan Zhao, Min Cui, Cong Zhang, Ju-Jie Ren, Xue-Ping Ji
Journal of Electrochemistry
Polyoxometalates, a class of anionic clusters with structure diversity and size variability, make them very attractive in many fields such as electrochemistry, catalysis and medicine. The Co(C15N6H12)2[PW12O38]·5H2O(Co[PW12O38]) modified carbon paste electrode was prepared in this work, and its electrochemical performances as the sensor for dopamine detection were characterized with electrochemical impedance spectroscopy, cyclic voltammetry and differential pulse voltammetry. The preparation conditions and test conditions were optimized respectively. Under the optimized conditions, the POMs modified carbon paste electrode exhibited good selectivity and sensitivity …
Preparation Of Surface Molecularly Imprinted Magnetic Nanoparticles For Hemoglobin Sensing, Chun-Fang Huang, Gui-Hong Yao, Jian-Ding Qiu
Preparation Of Surface Molecularly Imprinted Magnetic Nanoparticles For Hemoglobin Sensing, Chun-Fang Huang, Gui-Hong Yao, Jian-Ding Qiu
Journal of Electrochemistry
Surface molecularly imprinted magnetic nanoparticles (NPs) were prepared by employing dopamine (DA) as a functional monomer, hemoglobin (Hb) as a template, H2PtCl6 as an oxidant triggered DA polymerization on the surface of the Fe3O4 NPs. The Hb and the formed platinum nanoparticles (PtNPs) were embedded into the polydopamine (PDA). After removal of the Hb, the surface molecularly imprinted magnetic nanoparticles (imprinted Fe3O4/PDA-PtNPs) were formed, and then simply immobilized on the magnetic glassy carbon electrode (imprinted Fe3O4/PDA-PtNPs/MGCE) for Hb sensing. The imprinted Fe3O4/PDA-PtNPs …