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Assessing Challenges Associated With Sampling Hexavalent Chromium Under New Consensus Guidelilnes, Megan L. Steele
Assessing Challenges Associated With Sampling Hexavalent Chromium Under New Consensus Guidelilnes, Megan L. Steele
Theses and Dissertations
Hexavalent chromium is a corrosion inhibitor found in the primer of most aircraft platforms across the Department of Defense (DoD), from fighter jets to transports. It is also known to cause cancer in humans. Currently, the Occupational Safety and Health Administration (OSHA) legal exposure limit is 5 μg/m3 for workers exposed to hexavalent chromium. A non-regulatory scientific body has recently recommended lowering this exposure level over a factor of ten and sampling with a different sampler that collects particles with the same efficiency as the nose during inhalation. This inhalable sampler collects more particles than the one currently used …
Field Evaluation Of Solvent-Free Sampling With Di-N-Butylamine For The Determination Of Airborne Monomeric And Oligomeric 1,6-Hexamethylene Diisocyanate, Tiffany R. Heline
Field Evaluation Of Solvent-Free Sampling With Di-N-Butylamine For The Determination Of Airborne Monomeric And Oligomeric 1,6-Hexamethylene Diisocyanate, Tiffany R. Heline
Theses and Dissertations
During this study, a field evaluation of a new sampling method using di-n-butylamine for the determination of airborne monomeric and oligomeric 1,6-hexamethylene diisocyanate (HDI) was performed. The Supelco ASSET EZ4-NCO Dry Sampler was compared to the Omega Specialty Instrument Co. ISO-CHEK sampler. Three specific questions were addressed: 1) can HDI oligomers be quantified using HPLC-MS; 2) do ASSET and ISO-CHEK samplers collect equivalent HDI monomer & oligomer concentrations; and 3) what is the relative cost of ASSET samplers verse ISO-CHEK. Side-by-side HDI air sampling was conducted during polyurethane spray painting operations. ASSET samplers were analyzed by HPLC-MS for HDI monomer …