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VIMS Articles

2013

Animal Sciences

Physical Sciences Peer-Reviewed Articles

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Full-Text Articles in Life Sciences

Using Timescales To Interpret Dissolved Oxygen Distributions In The Bottom Waters Of Chesapeake Bay, Jian Shen, B Hong, Ay Kuo Jan 2013

Using Timescales To Interpret Dissolved Oxygen Distributions In The Bottom Waters Of Chesapeake Bay, Jian Shen, B Hong, Ay Kuo

VIMS Articles

A simplified conceptual model based on timescales of gravitational circulation, vertical exchange, and total oxygen consumption rate of the biochemical processes is presented to provide insight into the relationships between estuarine dynamics and bottom water dissolved oxygen (DO). Two dimensionless parameters are introduced to diagnose the relationship between the vertical exchange process and the biochemical DO consumption and the influence of gravitational circulation on replenishment of bottom DO. The relative magnitudes of these timescales provide a linkage between the physical and biochemical processes. The hypoxic and anoxic conditions in deep waters of Chesapeake Bay are successfully interpreted with these three …


Improved Method For Quantifying The Air-Sea Flux Of Volatile And Semi-Volatile Organic Carbon, Ej Hauser, Rm Dickhut, R Falconer, As Wozniak Jan 2013

Improved Method For Quantifying The Air-Sea Flux Of Volatile And Semi-Volatile Organic Carbon, Ej Hauser, Rm Dickhut, R Falconer, As Wozniak

VIMS Articles

A method for quantifying the diffusive air-sea exchange of gaseous organic carbon (OC) was developed. OC compounds were separated into two operational pools-those that were kinetically air limited in diffusion across the air-sea interface and those that were water limited-during simultaneous air/water sampling. The method separates OC compounds into low Henry's law constant (low-H) semivolatile OC (SOC) and high Henry's law constant (high-H) volatile OC (VOC) pools that can be categorized by relating diffusion kinetic parameters to Henry's Law constant. Air limited (low-H; H << similar to 0.1 L atm mol(-1)) compounds were collected in pure water traps and were quantified as dissolved OC, whereas water limited (high-H; H >> similar to 0.1 L atm mol-1) compounds were collected on solid sorbent tubes downstream from the …