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Net Ecosystem Metabolism; Global Oceans; Wet Deposition; Chesapeake Bay; Gas-Exchange; Water; Pollutants; Atlantic; Hydrocarbons; Respiration
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Full-Text Articles in Life Sciences
Improved Method For Quantifying The Air-Sea Flux Of Volatile And Semi-Volatile Organic Carbon, Ej Hauser, Rm Dickhut, R Falconer, As Wozniak
Improved Method For Quantifying The Air-Sea Flux Of Volatile And Semi-Volatile Organic Carbon, Ej Hauser, Rm Dickhut, R Falconer, As Wozniak
VIMS Articles
A method for quantifying the diffusive air-sea exchange of gaseous organic carbon (OC) was developed. OC compounds were separated into two operational pools-those that were kinetically air limited in diffusion across the air-sea interface and those that were water limited-during simultaneous air/water sampling. The method separates OC compounds into low Henry's law constant (low-H) semivolatile OC (SOC) and high Henry's law constant (high-H) volatile OC (VOC) pools that can be categorized by relating diffusion kinetic parameters to Henry's Law constant. Air limited (low-H; H << similar to 0.1 L atm mol(-1)) compounds were collected in pure water traps and were quantified as dissolved OC, whereas water limited (high-H; H >> similar to 0.1 L atm mol-1) compounds were collected on solid sorbent tubes downstream from the …