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Faculty of Science - Papers (Archive)

2010

Modeling

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Equilibrium And Kinetic Modeling Of The Adsorption Of Indigo Carmine Onto Silk, Naparat Jiwalak, Saowanee Rattanaphani, John B. Bremner, Vichitr Rattanaphani Jan 2010

Equilibrium And Kinetic Modeling Of The Adsorption Of Indigo Carmine Onto Silk, Naparat Jiwalak, Saowanee Rattanaphani, John B. Bremner, Vichitr Rattanaphani

Faculty of Science - Papers (Archive)

Quantitative adsorption kinetic and equilibrium parameters for indigo carmine dyeing of silk were studied using UV-visible absorption spectroscopy. The effect of initial dye concentration, contact time, pH, material to liquor ratio (MLR), and temperature were determined to find the optimal conditions for adsorption. The mechanism of adsorption of indigo carmine dyeing onto silk was investigated using the pseudo first-order and pseudo second-order kinetic models. The adsorption kinetics was found to follow a pseudo-second-order kinetic model with an activation energy (E-a) of 51.06 kJ/mol. The equilibrium adsorption data of indigo carmine dye on silk were analyzed by the Langmuir and Freundlich …