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Full-Text Articles in Life Sciences

Chapter 7: The Chemical Senses In Birds, Larry Clark Jan 2014

Chapter 7: The Chemical Senses In Birds, Larry Clark

Larry Clark

No abstract provided.


Taxon-Specific Differences In Responsiveness To Capsaicin And Several Analogues: Correlates Between Chemical Structure And Behavioral Aversiveness, Russell Mason, Jay Bean, Pankaj Shah, Larry Clark Jan 1991

Taxon-Specific Differences In Responsiveness To Capsaicin And Several Analogues: Correlates Between Chemical Structure And Behavioral Aversiveness, Russell Mason, Jay Bean, Pankaj Shah, Larry Clark

Larry Clark

The present set of experiments was designed to explore avian insensitivity to capsaicin. Based upon a molecular model of avian chemosen­ sory repellency, we hypothesized that structural modifications of the basic capsaicin molecule, which is itself not aversive to birds, might produce aver­ sive analogues. To this end, European starlings (Sturnus vulgaris) and Nor­ way rats (Rattus norvegicus) were given varied concentrations of synthetic capsaicin and four analogues (methyl capsaicin, veratryl amine, veratryl acet­ amide, vanillyl acetamide) in feeding and drinking tests. The results agreed with a model that we are developing to describe the chemical nature of avian repellents. …


Nonlethal Bird Repellents: In Search Of A General Model Relating Repellency And Chemical Structure, Larry Clark, Pankaj Shah Jan 1991

Nonlethal Bird Repellents: In Search Of A General Model Relating Repellency And Chemical Structure, Larry Clark, Pankaj Shah

Larry Clark

Identification of potential repellents through molecular modeling has implications for the devel­ opment of commerciaUy viable, ecologically sound. nonlethal bird repellents. We tested isomers (ortho, meta, para) and moieties (amino, hydroxy, methoxy) of acetophenones for their effectiveness as bird repellents to better understand the nature of repellency in birds. ChemicaUy, basicity of a substituted phenyl ring, as de&ned by the electron-donating substituent, probably is an important feature infiuencing repellency; i.e., more basic substituents result in more potent repellents. Isomeric position of the electron-donating substituent, which leads to resonance of lone pairs of electrons.• is also an important feature of repellency; …


Prediction Of Avian Repellency From Chemical Structure: The Aversiveness Of Vanillin, Vanillyl Alcohol, And Veratryl Alcohol, Pankaj Shah, Larry Clark, Russel Mason Jan 1991

Prediction Of Avian Repellency From Chemical Structure: The Aversiveness Of Vanillin, Vanillyl Alcohol, And Veratryl Alcohol, Pankaj Shah, Larry Clark, Russel Mason

Larry Clark

The effectiveness of bird repellents is associated with the presence of an electron-withdrawing group (carbonyl or carboxyl) and an electron-donating group in resonance on a phenyl ring. The present experiments were designed to examine the relative importance of these structural features. European starlings (Sturnus vulgaris) were presented with vanillin, vanillyl alcohol, and veratryl alcohol in two-cup and one-cup feeding trials and in one-bottle drinking tests. In feeding trials, veratryl alcohol was significantly more aversive than the other two chemicals. In drinking tests. veratryl alcohol was repellent only at the highest concentration (0.5% ml/ml), and was lethal at that concentration and …