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Ortho-Aminoacetophenone Repellency To Birds: Similiarities To Methyl Antrhanilate, Russell Mason, Larry Clark, Pankaj Shah
Ortho-Aminoacetophenone Repellency To Birds: Similiarities To Methyl Antrhanilate, Russell Mason, Larry Clark, Pankaj Shah
Larry Clark
Methyl anthranilate is an effective bird repellent at concentrations 2:1.0% (g/g). Ortho-ami noacetophenone (OAP) has an odor similar to that of methyl anthranilate and is chemically (structurally) similar. Coincidentally, OAP is present in the scent gland secretions of mustelid species that prey on birds. For these reasons, we chose to test the bird repellency of this material and 3 isomers to European starlings (Stumus vulgaris). Ortho-aminoacetophenone was repellent at concentrations :50.01% in both choice and no-choice feeding tests. The other structural isomers (meta-, para-, alpha-) were less effective. Chemically, the results suggest that hydrogen-bonded ring structure formation and basicity predict …
Prediction Of Avian Repellency From Chemical Structure: The Aversiveness Of Vanillin, Vanillyl Alcohol, And Veratryl Alcohol, Pankaj Shah, Larry Clark, Russel Mason
Prediction Of Avian Repellency From Chemical Structure: The Aversiveness Of Vanillin, Vanillyl Alcohol, And Veratryl Alcohol, Pankaj Shah, Larry Clark, Russel Mason
Larry Clark
The effectiveness of bird repellents is associated with the presence of an electron-withdrawing group (carbonyl or carboxyl) and an electron-donating group in resonance on a phenyl ring. The present experiments were designed to examine the relative importance of these structural features. European starlings (Sturnus vulgaris) were presented with vanillin, vanillyl alcohol, and veratryl alcohol in two-cup and one-cup feeding trials and in one-bottle drinking tests. In feeding trials, veratryl alcohol was significantly more aversive than the other two chemicals. In drinking tests. veratryl alcohol was repellent only at the highest concentration (0.5% ml/ml), and was lethal at that concentration and …