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Full-Text Articles in Life Sciences

Sorption-Desorption Of Imidacloprid And Its Metabolites In Soil And Vadose Zone Materials, Sharon V. Papiernik, William C. Koskinen, Lucia Cox, Pamela J. Rice, Sharon A. Clay, Nancy R. Werdin-Pfisterer, Kristen A. Norberg Jan 2006

Sorption-Desorption Of Imidacloprid And Its Metabolites In Soil And Vadose Zone Materials, Sharon V. Papiernik, William C. Koskinen, Lucia Cox, Pamela J. Rice, Sharon A. Clay, Nancy R. Werdin-Pfisterer, Kristen A. Norberg

Agronomy, Horticulture and Plant Science Faculty Publications

Sorption-desorption is one of the most important processes affecting the leaching of pesticides through soil because it controls the amount of pesticide available for transport. Subsurface soil properties can significantly affect pesticide transport and the potential for groundwater contamination. This research characterized the sorption-desorption of imidacloprid (1-[(6-chloro-3-pyridinyl)-methyl]-Nnitro-2-imidazolidinimine) and three of its metabolites, 1-[(6-chloro-3-pyridinyl)methyl]-2-imidazolidinone (imidacloprid-urea), 1-[(6-chloro-3-pyridinyl)methyl]-4,5-dihydro-1H-imidazol-2-amine (imidaclopridguanidine), and 1-[(6-chloro-3-pyridinyl)methyl]-1H-imidazol-2-amine (imidacloprid-guanidine-olefin), as a function of changing soil properties with depth in two profiles extending from the surface to a depth of 1.8 or 8 m. Sorption of each compound was highly variable and hysteretic in all cases. Normalizing the sorption coefficients (Kf) …


Atrazine And Alachlor Dissipation Rates From Field Experiments, Stephen R. Workman, Andrew D. Ward, Norman R. Fausey, Sue E. Nokes Jan 1995

Atrazine And Alachlor Dissipation Rates From Field Experiments, Stephen R. Workman, Andrew D. Ward, Norman R. Fausey, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

Chemical transport is being monitored in the root zone of three agricultural management systems at the Ohio Management Systems Evaluation Area (OMSEA). Atrazine and alachlor concentration data from soil cores taken to a depth of 0.9 m and partitioned into the increments of 0.0 to 0.15, 0.15 to 0.3, 0.45 to 0.6, and 0.75 to 0.9 m show the herbicides remained in the top 0.15 m of the profile during the 1991 and 1992 growing seasons. The slow movement of herbicides was partly due to below normal rainfall during the period. Since the herbicides have not been transported out of …