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Chemistry

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Full-Text Articles in Life Sciences

Chemistry Of Hydrogen Oxide Radicals (Hox) In The Arctic Troposphere In Spring, J Mao, D J. Jacob, M J. Evans, J R. Olson, X Ren, W H. Brune, T M. St. Clair, J D. Crounse, K M. Spencer, M R. Beaver, P O. Wennberg, M J. Cubison, J L. Jimenez, A Fried, P Weibring, J G. Walega, S R. Hall, A J. Weinheimer, R C. Cohen, G Chen, J H. Crawford, C Mcnaughton, A D. Clarke, L Jaegle, Jenny A. Fisher, R M. Yantosca, P Le Sager, C C. Carouge Feb 2015

Chemistry Of Hydrogen Oxide Radicals (Hox) In The Arctic Troposphere In Spring, J Mao, D J. Jacob, M J. Evans, J R. Olson, X Ren, W H. Brune, T M. St. Clair, J D. Crounse, K M. Spencer, M R. Beaver, P O. Wennberg, M J. Cubison, J L. Jimenez, A Fried, P Weibring, J G. Walega, S R. Hall, A J. Weinheimer, R C. Cohen, G Chen, J H. Crawford, C Mcnaughton, A D. Clarke, L Jaegle, Jenny A. Fisher, R M. Yantosca, P Le Sager, C C. Carouge

Jenny A Fisher

We use observations from the April 2008 NASA ARCTAS aircraft campaign to the North American Arctic, interpreted with a global 3-D chemical transport model (GEOS-Chem), to better understand the sources and cycling of hydrogen oxide radicals (HOx≡H+OH+peroxy radicals) and their reservoirs (HOy≡HOx+peroxides) in the springtime Arctic atmosphere. We find that a standard gas-phase chemical mechanism overestimates the observed HO2 and H2O2 concentrations. Computation of HOx and HOy gas-phase chemical budgets on the basis of the aircraft observations also indicates a large missing sink for both. We hypothesize that this could reflect HO2 uptake by aerosols, favored by low temperatures and …


Detection Of Boronic Acids Through Excited-State Intramolecular Proton-Transfer Fluorescence, Matthew R. Aronoff, Brett Vanveller, Ronald T. Raines Oct 2013

Detection Of Boronic Acids Through Excited-State Intramolecular Proton-Transfer Fluorescence, Matthew R. Aronoff, Brett Vanveller, Ronald T. Raines

Brett VanVeller

Boronic acids are versatile reagents for the chemical synthesis of organic molecules. They and other boron-containing compounds can be detected readily by the interruption of the excited-state intramolecular proton transfer (ESIPT) of 10-hydroxybenzo[h]quinolone. This method is highly sensitive and selective, and useful for monitoring synthetic reactions and detecting boron-containing compounds on a solid support.


Biophyschem2011: A Joint Meeting Of The Australian Society For Biophysics And The Raci Physical Chemistry Division Foreword, Adam Trevitt, Jeffrey Reimers, Ronald Clarke, Jamie Vandenberg Jul 2013

Biophyschem2011: A Joint Meeting Of The Australian Society For Biophysics And The Raci Physical Chemistry Division Foreword, Adam Trevitt, Jeffrey Reimers, Ronald Clarke, Jamie Vandenberg

Adam Trevitt

[extract] This Research Front of the Australian Journal of Chemistry is aligned with the BIOPHYSCHEM2011 meeting, a joint conference of the Australian Society for Biophysics and the Physical Chemistry Division of the RACI, which was held at the University of Wollongong from 3 to 6 December 2011. Just shy of 200 delegates made the journey to the Illawarra as these two societies came together for the first time for a national meeting. The idea for this collaboration sprang from the inaugural Australian Biophysical Chemistry Workshop, coordinated by Dr Ron Clarke (U. Sydney) and Dr Tak Kee (U. Adelaide) in 2010. …


Soil Chemistry: Understanding Phosphorus In The Environment, Paul Milham, Warwick Dougherty, Robert Morrison, Robert Clark, Ronald Smernik, Ashlea Doolette, Lucy Burkitt, Damian Collins, Rebeca Alvarez, Andrew Thomas May 2013

Soil Chemistry: Understanding Phosphorus In The Environment, Paul Milham, Warwick Dougherty, Robert Morrison, Robert Clark, Ronald Smernik, Ashlea Doolette, Lucy Burkitt, Damian Collins, Rebeca Alvarez, Andrew Thomas

Robert Clark

It is an essential ingredient in food production, but poor management means bad news downstream. Understanding the way phosphorus behaves in the environment calls for soil and plant biology, and some new soil chemistry.