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Full-Text Articles in Life Sciences
Detection Of Al(Iii) And Ga(Iii) Complexes With Morin By Electrospray Ionization Mass Spectrometry, John B. Bremner, Larry A. Hick, Jody Morgan, Saowanee Rattanaphani, Vichitr Rattanaphani, C Septhum
Detection Of Al(Iii) And Ga(Iii) Complexes With Morin By Electrospray Ionization Mass Spectrometry, John B. Bremner, Larry A. Hick, Jody Morgan, Saowanee Rattanaphani, Vichitr Rattanaphani, C Septhum
Faculty of Science - Papers (Archive)
The Al(III) and Ga(III) complexes formed by morin (M) in aqueous solution were investigated by means of electrospray ionization mass spectrometry (ESI-MS). In the full scan mass spectra, Al:M showed 1:2 and 2:3 stoichiometric ratios. When (S)-N-acetylserine methyl ester (Ser), as a partial mimic of the serine residue in silk, was added to Al:M and Ga:M complexes in aqueous solution, the mass spectra of Ser:Al:M showed 1:1:1 and 1:1:2 stoichiometric ratios. The patterns of the mass spectra of Ga:M and Ser:Ga:M complexes were similar to those for the corresponding Al(III) complexes. Calculated heats of formation of potential structures of the …
Annual Variation Of Strato-Mesospheric Carbon Monoxide Measured By Ground-Based Fourier Transform Infrared Spectrometry, Voltaire A. Velazco, S.J. Wood, M Sinnhuber, I Kramer, Nicholas B. Jones, Y Kasai, Justus Notholt, Thorsten Warneke, T Blumenstock, F Hase, F Murcray, O Schrems
Annual Variation Of Strato-Mesospheric Carbon Monoxide Measured By Ground-Based Fourier Transform Infrared Spectrometry, Voltaire A. Velazco, S.J. Wood, M Sinnhuber, I Kramer, Nicholas B. Jones, Y Kasai, Justus Notholt, Thorsten Warneke, T Blumenstock, F Hase, F Murcray, O Schrems
Faculty of Science - Papers (Archive)
We present long-term time-series of strato-mesospheric CO vertical columns measured from stations located in Antarctica, mid-latitudes and the Arctic, covering the period from 19972005. The instrument and the measurement technique allows the separation of tropospheric and strato-mesospheric contributions to the CO column, therefore providing information on the chemistry and dynamics both at low and high altitudes. Data from polar stations show a similar annual variability of strato-mesospheric CO with a strong maximum in late winter and spring. A small enhancement in late summer for some stations, which we call the "summer bulge", can be seen occasionally. Generally, the mid-latitude stations …