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Comparative Study Of Various Pretreatment Reagents On Rice Husk And Structural Changes Assessment Of The Optimised Pretreated Rice Husk, Teck Nam Ang Dr., Gek Cheng Ngoh Dr, Adeline Seak May Chua Dr Jan 2013

Comparative Study Of Various Pretreatment Reagents On Rice Husk And Structural Changes Assessment Of The Optimised Pretreated Rice Husk, Teck Nam Ang Dr., Gek Cheng Ngoh Dr, Adeline Seak May Chua Dr

Teck Nam Ang Dr.

The performance of alkalis (NaOH and Ca(OH)2) and acids (H2SO4, HCl, H3PO4, CH3COOH, and HNO3) in the pretreatment of rice husk was screened, and a suitable reagent was assessed for subsequent optimisation using response surface methodology. From the assessment, HCl that hydrolysed rice husk well was optimised with three parameters (HCl loading, pretreatment duration, and temperature) using Box-Behnken Design. The optimised condition (0.5% (w/v) HCl loading, 125oC, 1.5 hours) is relatively mild, and resulted in ~22.3 mg TRS/ml hydrolysate. The reduced model developed has good predictability, where the predicted and experimental results differ by only 2%. The comprehensive structural characterization …


Sustainable Approach To Produce Bioethanol From Karanja (Pongamia Pinnata) Oilseed Residue, Pooja Doshi, Gopal Srivastava Jan 2013

Sustainable Approach To Produce Bioethanol From Karanja (Pongamia Pinnata) Oilseed Residue, Pooja Doshi, Gopal Srivastava

Turkish Journal of Agriculture and Forestry

Agricultural biomass is the world's largest, most sustainable, and most promising renewable energy source. This study investigated the potential of Karanja (Pongamia pinnata) oilseed residual waste (defatted kernel, hull, and their mixture) as a source of ethanol. The pretreatment of the finely ground samples was carried out using dilute sulfuric acid (0.5%) hydrolysis at a higher temperature of 121 °C and 15 psi pressure for 90 min. The pretreatment usually removes the lignin and facilitates the hydrolysis of cellulose and hemicelluloses. They were further hydrolyzed using 5% H_2SO_4 at 50 °C for 70 h. The analyses of hydrolyzed products have …