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Tests And Refinements Of A General Structure-Activity Model For Avian Repellents, Larry Clark, Pankaj Shah
Tests And Refinements Of A General Structure-Activity Model For Avian Repellents, Larry Clark, Pankaj Shah
Larry Clark
We tested the robustness of a structure-activity model for avian trigeminal chemoirritants. Fourteen benzoates and acetophenones were tested using European starlings Sturn us vulgaris as a bioassay. In general. the pre viously proposed model was a reasonable predictor of repellency (i.e., irritant potency). We found that the presence of a phenyl ring was critical to repel lency. Basicity of the molecule is the next most critical feature influencing repellency. The presence of an acidic function within the electron-withdrawing functionality seriously detracts from repellency. The presence or absence of an electron-withdrawing or -donating group may potentiate repellent effects, but its presence …
Chemical Repellency In Birds: Relationship Between Chemical Structure And Avoidance Response, Larry Clark, Pankaj Shah, Russell Mason
Chemical Repellency In Birds: Relationship Between Chemical Structure And Avoidance Response, Larry Clark, Pankaj Shah, Russell Mason
Larry Clark
We examined how molecular structure of24 anthranilate and benzoic acid deriva tives correlated with drinking behavior in European starlings Sturnus vulgaris.The effectiveness of bird repellents was &?SOciated with basicity, the presence of an electron onating group in resonance with an electron-withdrawing carboxylic group on a phenyl ring, and a heterocyclic ring in the same pi cloud plane as the phenyl ring. Of the benzoic acid derivatives tested in this study, methyl, ethyl, dimethyl, and linalylanthranilate as well as anthranilic acid and 4-ketobenztriazine were repellent to birds. Water consumption was significantly reduced relative to control levels at concentrations as low as …