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Crystallization Of Polyamide 66 Copolymers At High Supercoolings, Xiaoping Guan

Doctoral Dissertations

Crystallization kinetics and morphologies of a series of random copolymers of PA 66 (or Nylon 66) have been investigated at high supercoolings. Optical microscopy with rapid cooling apparatus was employed to observe spherulitic morphologies and measure growth rates. Final spherulitic morphologies of PA 66 and copolymers could be changed with increasing supercoolings from impinged spherulites to isolated spherulites with decreasing size until total amorphous.

Spherulite growth results indicated that the rates of crystallization of PA 66 copolymers were reduced with increasing content of comonomer, and crystallization was moved to lower temperatures. The melting temperature, crystallinity, crystal structure and lamellar thickness …