Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Materials Science and Engineering (66)
- Chemical Engineering (57)
- Physical Sciences and Mathematics (36)
- Mechanical Engineering (28)
- Civil and Environmental Engineering (27)
-
- Engineering Science and Materials (26)
- Chemistry (19)
- Environmental Engineering (16)
- Electrical and Computer Engineering (15)
- Catalysis and Reaction Engineering (13)
- Biomedical Engineering and Bioengineering (12)
- Mechanics of Materials (12)
- Metallurgy (12)
- Aerospace Engineering (11)
- Materials Chemistry (10)
- Physical Chemistry (10)
- Environmental Sciences (9)
- Ceramic Materials (7)
- Oil, Gas, and Energy (7)
- Power and Energy (7)
- Civil Engineering (6)
- Science and Technology Studies (6)
- Social and Behavioral Sciences (6)
- Structural Materials (5)
- Nanoscience and Nanotechnology (4)
- Nuclear Engineering (4)
- Applied Mechanics (3)
- Bioresource and Agricultural Engineering (3)
- Computer Engineering (3)
- Institution
-
- University of South Carolina (18)
- University of Wollongong (16)
- Missouri University of Science and Technology (12)
- University of Texas at El Paso (12)
- Selected Works (9)
-
- University of Kentucky (9)
- Boise State University (8)
- Air Force Institute of Technology (7)
- Chinese Chemical Society | Xiamen University (7)
- Old Dominion University (7)
- University of Central Florida (6)
- University of Nevada, Las Vegas (6)
- SelectedWorks (5)
- Brigham Young University (4)
- Chulalongkorn University (4)
- Montana Tech Library (4)
- University of Tennessee, Knoxville (4)
- University of Vermont (4)
- California Polytechnic State University, San Luis Obispo (3)
- Cleveland State University (3)
- Louisiana State University (3)
- New Jersey Institute of Technology (3)
- Rochester Institute of Technology (3)
- Utah State University (3)
- Wright State University (3)
- American University in Cairo (2)
- Michigan Technological University (2)
- Purdue University (2)
- Syracuse University (2)
- Tashkent State Technical University (2)
- Publication Year
- Publication
-
- Faculty Publications (21)
- Open Access Theses & Dissertations (12)
- Theses and Dissertations (12)
- Australian Institute for Innovative Materials - Papers (8)
- Electronic Theses and Dissertations (8)
-
- Journal of Electrochemistry (7)
- Materials Science and Engineering Faculty Research & Creative Works (7)
- Faculty of Engineering and Information Sciences - Papers: Part A (5)
- Materials Science and Engineering Faculty Publications and Presentations (5)
- A.S. Md Abdul Haseeb (4)
- Doctoral Dissertations (4)
- Graduate College Dissertations and Theses (4)
- Journal of Metals, Materials and Minerals (4)
- Bachelors Theses and Reports, 1928 - 1970 (3)
- Bioelectrics Publications (3)
- Boise State University Theses and Dissertations (3)
- Chemical and Biochemical Engineering Faculty Research & Creative Works (3)
- Journal of the Microelectronic Engineering Conference (3)
- Materials Engineering (3)
- Theses (3)
- UNLV Theses, Dissertations, Professional Papers, and Capstones (3)
- Biomedical, Industrial & Human Factors Engineering Faculty Publications (2)
- Dissertations, Master's Theses and Master's Reports (2)
- ETD Archive (2)
- Faculty of Engineering - Papers (Archive) (2)
- John W Weidner (2)
- LSU Doctoral Dissertations (2)
- Makara Journal of Technology (2)
- Technical science and innovation (2)
- Transmutation Sciences Materials (TRP) (2)
- Publication Type
- File Type
Articles 1 - 30 of 205
Full-Text Articles in Engineering
Microstructural Characterization And Oxidation Behavior Of Al-Cu-Ni-Mn And Al-Cu-Ni-Mn-Si Non-Body Centered Cubic High Entropy Alloys, Mckenna Mae Lin Hitter
Microstructural Characterization And Oxidation Behavior Of Al-Cu-Ni-Mn And Al-Cu-Ni-Mn-Si Non-Body Centered Cubic High Entropy Alloys, Mckenna Mae Lin Hitter
Open Access Theses & Dissertations
High entropy alloys (HEA) differ from traditional alloying systems because five elements are mixed in equi-atomic proportions, as opposed to having one main principal element. As a result of exploring this new method of alloying, it was found that high entropy alloys demonstrate exceptional mechanical properties, an example being oxidation resistance, and are capable of enduring elevated temperatures. Seeing the potential that this new area of interest contains, studies involving a combination of elements to form various HEA have been performed. Most refractory metals are body-centered cubic and possess extremely high melting temperatures, so they are regularly considered when designing …
Selective Oxidation Of Iron In Chalcopyrite For Enhanced Copper Recovery, Khojiakbar Shuxrat O'G'Li Sultonov, Shokhrukh Toshpulatovich Khojiev, Gulnoza Berdiyor Qizi Beknazarova, Malika Sayfullayevna Saidova
Selective Oxidation Of Iron In Chalcopyrite For Enhanced Copper Recovery, Khojiakbar Shuxrat O'G'Li Sultonov, Shokhrukh Toshpulatovich Khojiev, Gulnoza Berdiyor Qizi Beknazarova, Malika Sayfullayevna Saidova
Technical science and innovation
This study explores the thermodynamic feasibility of selectively oxidizing iron contained in chalcopyrite mineral while preventing the oxidation of copper sulphide, with the ultimate goal of enhancing the copper concentration in the sulphide concentrate. A redox reaction in the solid phases between chalcopyrite and copper (I) oxide was constructed and subjected to thermodynamic analysis. The research identifies a crucial temperature range of 498-598 K (225-325 °C) as the most favourable for the redox reaction. The equilibrium constants at the selected optimal temperatures, 1.152 for chalcopyrite and 1.137 for copper (I) oxide, indicate that the redox reaction adheres to the expected …
Oxidation Of Additively Manufactured Zrb2–Sic In Air And In Co2 At 700–1000 °C, Marharyta Lakusta, Nicholas M. Timme, Abid H. Rafi, Jeremy Lee Watts, M. (Ming) C. (Chuan) Leu, Gregory E. Hilmas, William G. Fahrenholtz, David W. Lipke
Oxidation Of Additively Manufactured Zrb2–Sic In Air And In Co2 At 700–1000 °C, Marharyta Lakusta, Nicholas M. Timme, Abid H. Rafi, Jeremy Lee Watts, M. (Ming) C. (Chuan) Leu, Gregory E. Hilmas, William G. Fahrenholtz, David W. Lipke
Materials Science and Engineering Faculty Research & Creative Works
Oxidation behavior of additively manufactured zrb2–sic in air and in co2 is reported in the temperature range of 700–1000 °c. Observed scale morphologies in air and in co2 were similar, featuring an outer borosilicate layer and an inner porous zirconia layer containing partially oxidized silicon carbide particles and remnant borosilicate products. Oxide scale thicknesses and parabolic scaling constants in air were approximately twice those observed in co2 across all studied temperatures. Activation energies for oxidation of 140 ± 20 kj/mol in air and 110 ± 20 kj/mol in co2 were determined, indicating similar diffusion processes that appear to be rate-limiting. …
High Temperature Oxidation Kinetics Of Alumina Forming Steels For Petrochemical Processes, Kao Zoua Yang
High Temperature Oxidation Kinetics Of Alumina Forming Steels For Petrochemical Processes, Kao Zoua Yang
Theses and Dissertations
Petrochemical industries produce 14.33 million barrels of petroleum products a day and by 2023, are expected to produce over a trillion dollars in sales annually. Petroleum is the number one used fuel source and is the raw material used to produce a wide range of petrochemical products including ethylene which is the raw chemical precursors that is crucial to the polymer market. Ethylene is created by the process of cracking ethane and other hydrocarbons in steel reactors at high temperature and potentially oxidizing conditions. The cracking process produces a range of byproducts including a detrimental solid carbon, called coke, which …
Uncertainty Quantification And Constraint Of Chemical Kinetic Mechanisms Based On Flow Reactor Experiments, Ana Victoria Kock
Uncertainty Quantification And Constraint Of Chemical Kinetic Mechanisms Based On Flow Reactor Experiments, Ana Victoria Kock
Theses and Dissertations
The chemical kinetic model is one of key sub-models for computational fluid dynamics (CFD) simulation for optimizing and designing various combustors/engines. Detailed chemical kinetic models can consist of hundreds of species and thousands of elementary reaction steps. Considering the complexity in these detailed chemical kinetic models, it is important to quantify and minimize the uncertainties in the kinetic parameters. The uncertainties in the kinetic models can then be compared to uncertainties tied to experimental measurements. This approach has been frequently applied for relatively simple combustion parameters (e.g., laminar flame speed, ignition delay time), however it has not been well utilized …
Oxidation Of Hafnium Diboride—Silicon Carbide At 1500 °C In Air; Effect Of Compressive Stress, Anthony J. Degregoria, Marina B. Ruggles-Wrenn, Glen E. Pry
Oxidation Of Hafnium Diboride—Silicon Carbide At 1500 °C In Air; Effect Of Compressive Stress, Anthony J. Degregoria, Marina B. Ruggles-Wrenn, Glen E. Pry
Faculty Publications
The long-term oxidation behavior of HfB2 and of HfB2-20 vol.% SiC was studied. Test samples of each material were oxidized at 1500 °C in air using a box furnace. The exposure times were 0, 0.5, 1, 2, 3, 6, 9, 12, 15, 30, 45 and 90 h. Weight gain, oxide scale composition and oxide scale thickness were characterized for both materials. Crystal structure of the surface scales was analyzed using x-ray diffraction. Oxide scales were further characterized via scanning electron microscopy with energy dispersive spectroscopy analysis. For HfB2 the oxide scale consists predominantly of porous HfO …
Novel Investigation Of Catalytic Hydrogenation And Oxidation Of 1,3-Butadiene, Ali M. Alabedkhalil
Novel Investigation Of Catalytic Hydrogenation And Oxidation Of 1,3-Butadiene, Ali M. Alabedkhalil
Theses
The hydrogenation of 1,3 Butadiene (BD) is an important industrial process that is generally used to generate butene, which is a key feedstock to produce a variety of chemicals such as polymers, plastic, and synthetic rubber. This process involves reacting BD with hydrogen using different metallic Ni-based catalysts. In this study, Ni/Al2O3 and Ni/Nb2O5 catalysts were used and investigated to perform the hydrogenation reaction because of their commercial availability, effective hydrogenation activity, and affordability compared to Platinum Group Metal (PGM) catalysts.
The catalytic reactions were conducted using a quartz tube reactor between a temperature range …
Effect Of Cr And Ni Concentrations On Resilience Of Cast Nb-Alloyed Heat Resistant Austenitic Steels At Extreme High Temperatures, Simon N. Lekakh, Mario F. Buchely, Mei Li, Larry Godlewski
Effect Of Cr And Ni Concentrations On Resilience Of Cast Nb-Alloyed Heat Resistant Austenitic Steels At Extreme High Temperatures, Simon N. Lekakh, Mario F. Buchely, Mei Li, Larry Godlewski
Materials Science and Engineering Faculty Research & Creative Works
Austenitic Cr–Ni Alloyed Heat Resistant Steels with Nb Additions Are Used for Intensively Thermo-Mechanically Loaded Cast Components Working in Extreme High Temperature Oxidizing Environment. their Performance during Static Oxidation and Transient Thermo-Mechanical Loading Was Investigated to Recommend an Optimal Cost-Effective Cr/Ni Composition of Nb-Alloyed Austenitic Class Steels. the Static Oxidation and Transient Thermo-Mechanical Behavior of Three Austenitic Steels with Different Cr/Ni Alloying Levels Were Investigated and Compared for Variety of Working Conditions. Static Oxidation Was Performed between 900 °C and 1000 °C in Air for 400 H. the Critical Temperature Which Increases Spallation during Static Oxidation Was Determined for Each …
A Comparative Evaluation Of Oxidation And Combustion Phenomena In Ti-6al-4v Exposed To Earth Re-Entry And Arc-Jet Test Environments, Arlene Smith
Open Access Theses & Dissertations
The Ti-6Al-4V alloy is widely used in aerospace applications for its beneficial combination of properties. However, this alloy has high solubility for oxygen and thus a high reactivity. Recovered data contained within the Columbia artifacts suggests that this alloy underwent an accelerated degradation and combustion reaction when exposed to the high enthalpy, low-pressure surroundings experienced during reentry into Earth's atmosphere. Arc-jet testing has provided a simulated aerothermodynamic heating environment to mimic what the spacecraft endured. When the effect of thermal alteration on this alpha-beta phase alloy was investigated during previous studies, optical metallography and microhardness tests revealed inconsistencies between samples …
Infiltration-Controlled Combustion Of Lithium And Magnesium Powders And Reactions Of Lithium With Oxygen And Carbon Dioxide, Kevin Samuel Estala Rodriguez
Infiltration-Controlled Combustion Of Lithium And Magnesium Powders And Reactions Of Lithium With Oxygen And Carbon Dioxide, Kevin Samuel Estala Rodriguez
Open Access Theses & Dissertations
Chemical heat integrated power systems are of great interest for space missions where solar energy, nuclear energy, and batteries are not available or are not practical to use. A new concept of a power system is a metal combustor coupled with a chemical oxygen generator, where the generated oxygen infiltrates through the metal powder or combustion products. The combustion of lithium and magnesium powders under these conditions has not been studied yet. The present work investigates combustion of magnesium powder and stabilized lithium metal powder (SLMP) ignited by a laser inside a closed chamber filled with O2 or CO2. It …
Atomic Layer Deposited Pt/Tio2-Sio2 And Pt/Zro2-Sio2 For Sequential Adsorption And Oxidation Of Vocs, Busuyi O. Adebayo, Han Yu, Ali A. Rownaghi, Xinhua Liang, Fateme Rezaei
Atomic Layer Deposited Pt/Tio2-Sio2 And Pt/Zro2-Sio2 For Sequential Adsorption And Oxidation Of Vocs, Busuyi O. Adebayo, Han Yu, Ali A. Rownaghi, Xinhua Liang, Fateme Rezaei
Chemical and Biochemical Engineering Faculty Research & Creative Works
In this work, Pt nanoparticles were loaded on SiO2, TiO2-thin-film-modified SiO2 (TiO2-SiO2), or ZrO2-thin-film-modified SiO2 (ZrO2-SiO2) particles and the composites were investigated for sequential adsorption and desorption/catalytic oxidation of benzene. The SiO2 was prepared via sol–gel method, while TiO2-SiO2 and ZrO2-SiO2 were synthesized via atomic layer deposition (ALD) thin film coating of TiO2 or ZrO2 on SiO2 particles substrate. In the sequential capture-reaction tests, the materials were first exposed to ca. 500 ppmv benzene …
Degradation Mechanisms Of Zinc-Air Batteries Used In Hearing Aid, Kelly Hunt, Mallorty Bates, Gerard Klint Simon, Tarun Goswami
Degradation Mechanisms Of Zinc-Air Batteries Used In Hearing Aid, Kelly Hunt, Mallorty Bates, Gerard Klint Simon, Tarun Goswami
Biomedical, Industrial & Human Factors Engineering Faculty Publications
Hearing aid devices are powered by the oxidation of zinc that occurs within zinc-air batteries. Zinc-air batteries have an average discharge time of 7 days. Therefore, hearing-aid devices need frequent battery replacement. In this paper, degradation mechanisms of zinc-air batteries investigated where a competition mechanism between zinc passivation and dendritic formation dictates the battery life. This research included exposure time from none to 9 days and to document dendritic growth with time. Scanning electron microscope images were taken to quantify the damage growth as well energy dispersive X-ray tests were conducted to comment on the composition changes. The results confirmed …
Analyzing The Surface Chemistry Of Ni-Fe Hydroxide Alloy Nanoparticles As Catalysts For The Oxygen Evolution Reaction By X-Ray Photoelectron Spectroscopy Analysis, Lauren B. Shepard
Analyzing The Surface Chemistry Of Ni-Fe Hydroxide Alloy Nanoparticles As Catalysts For The Oxygen Evolution Reaction By X-Ray Photoelectron Spectroscopy Analysis, Lauren B. Shepard
Chemical Engineering Undergraduate Honors Theses
Water electrolysis has been proposed as a renewable source of hydrogen, a possible replacement to harmful fossil fuels. This process can be broken down into two half reactions, the hydrogen evolution reaction and the oxygen evolution reaction. Because the oxygen evolution reaction has slow kinetics and a high overpotential to overcome, a catalyst is needed to speed up the kinetics and ensure faster and more efficient production of molecular hydrogen. The use of Ni-Fe hydroxide alloy nanoparticles as a catalyst has been shown to significantly improve the efficiency of the reaction by decreasing the overpotential, making the process more energy …
Experimentation Of Abrasion Erosion At High Temperature For Concentrated Solar Power Systems, Tessa Mei-Lin Fong
Experimentation Of Abrasion Erosion At High Temperature For Concentrated Solar Power Systems, Tessa Mei-Lin Fong
Boise State University Theses and Dissertations
Concentrated solar power (CSP) is an alternative and sustainable way to produce energy. Studies have shown that running these plants at high temperatures above 700°C can increase the thermal efficiency in heat transfer. Molten salt is usually used as the heat transfer medium but cannot be used due to its low maximum temperature and high freezing point. Running these plants at high temperature brings up the concern of erosion and oxidation. Abrasion erosion occurs through the interaction of particles and material. The goal of this research is to understand material degradation due to abrasion erosion to understand the durability of …
The Oxidation Of The Hisimo Cast Irons Alloyed With Cr/Al At 800 °C, Wenhui Zhu, Bruce A. Pint, Yang Huo, Larry Godlewski, Bita Ghaffari, Simon Lekakh, Carlos Engler-Pinto, Mei Li
The Oxidation Of The Hisimo Cast Irons Alloyed With Cr/Al At 800 °C, Wenhui Zhu, Bruce A. Pint, Yang Huo, Larry Godlewski, Bita Ghaffari, Simon Lekakh, Carlos Engler-Pinto, Mei Li
Materials Science and Engineering Faculty Research & Creative Works
To improve the oxidation resistance of cast iron containing Si and Mo (HiSiMo), 1wt.% Cr and 3wt.% Al were added into the base alloy to improve high temperature oxidation resistance for exhaust manifold applications. Oxidation tests were performed in both dry and wet air (air + 10% H2O) at 800 °C for 1, 10, 24, and 50 h. The mass change and oxide thickness were measured to evaluate the oxidation resistance. Scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDS) and transmission electron microscopy (TEM) were employed to characterize the oxidized samples. The results showed that the additions of Al …
Cobalt Ferrite Nano-Composites For The Oxidation Of Phenols In Oil Refinery Wastewater, Amira Mohamed
Cobalt Ferrite Nano-Composites For The Oxidation Of Phenols In Oil Refinery Wastewater, Amira Mohamed
Theses and Dissertations
Phenolic compounds have the tendency to persist in the environment over a long period making them a main source of concern because of their toxic characteristics towards humans and animals (Bruce et al., 1987). Therefore, existence of phenolic compounds in aquatic environment is unfavourable and as a result, many treatment techniques have been implemented to treat the wastewater produced from petroleum refineries. Petroleum refineries are among the top industries that produces significant quantities of high phenol concentration wastewater. Photo-catalysis is a promising and effective method to treat phenol present in oil refineries effluent. In this study, the photo-catalyst used is …
Oxidative Aging And Fracture Behavior Of Polymers And Composites: Theory, Modeling And Experiments, Shabnam Konica
Oxidative Aging And Fracture Behavior Of Polymers And Composites: Theory, Modeling And Experiments, Shabnam Konica
Dissertations, Master's Theses and Master's Reports
Polymers and their composites (PMC) have emerged as effective alternative materials in structural, aerospace, and automotive industries due to their lightweight and tunable properties compared to metals. However, these materials tend to degrade during their operations in extreme environments. In this work, two extreme conditions are considered: - i) high-temperature oxidative degradation of polymers and polymer-based composites ii) Fracture and damage of polymer-based composites under thermo-mechanical loading.
Polymer oxidation starts when oxygen from the ambient diffuses into the bulk material and initiates chemical reactions to develop a coarse, brittle oxide layer on the exposed surface. The oxidative degradation process is …
The Role Of Microstructure On High-Temperature Oxidation Behavior Of Hafnium Carbide, Jonathan A. Scott, Xiaoqing He, David W. Lipke
The Role Of Microstructure On High-Temperature Oxidation Behavior Of Hafnium Carbide, Jonathan A. Scott, Xiaoqing He, David W. Lipke
Materials Science and Engineering Faculty Research & Creative Works
Microstructure development of the products formed upon oxidation of hafnium carbide (HfCx, x = 0.65, 0.81, or 0.94) at 1300°C and 0.8 mbar oxygen pressure was investigated using Raman spectroscopy, X-ray diffraction, electron microscopy, and electron energy-loss spectroscopy. For all specimens a multilayered oxide scale was observed featuring an outermost porous hafnia layer and an interlayer adjacent to the parent carbide containing hafnia interspersed with carbon. The outermost hafnia features coarse pores presumably formed during initial stages of oxidation to allow rapidly evolving gaseous products to escape from the oxidation front. As the oxidation scale thickens, diffusional resistance results in …
Minimizing Cr-Evaporation From Balance Of Plant Components By Utilizing Cost-Effective Alumina-Forming Austenitic Steels, Lingfeng Zhou
Minimizing Cr-Evaporation From Balance Of Plant Components By Utilizing Cost-Effective Alumina-Forming Austenitic Steels, Lingfeng Zhou
Graduate Theses, Dissertations, and Problem Reports
A solid oxide fuel cell (SOFC) is a clean and efficient energy conversion device. The development of intermediate-temperature SOFCs has made it preferable to use metallic interconnects (MICs) to greatly reduce the cost and significantly increase the efficiency compared to ceramic interconnect materials. However, gaseous chromium species will evaporate from the chromium-containing layer formed on the surface of commonly used MICs and balance of plant (BoP) components. Volatile chromium species have been shown to form solid deposits which poison the cathodes of SOFCs, causing drastic cell performance degradation and thereby limiting commercialization. In order to alleviate the Cr poisoning and …
Effect Of Spallation On Oxidation Kinetics Of Heat-Resistant Cr–Ni Austenitic Steels On Air And Combustion Atmosphere, Simon N. Lekakh, Oleg Neroslavsky, Mei Li, Larry Godlewski, Wenhui Zhu
Effect Of Spallation On Oxidation Kinetics Of Heat-Resistant Cr–Ni Austenitic Steels On Air And Combustion Atmosphere, Simon N. Lekakh, Oleg Neroslavsky, Mei Li, Larry Godlewski, Wenhui Zhu
Materials Science and Engineering Faculty Research & Creative Works
Thin-walled castings made from Cr–Ni austenitic steels offer a combination of light weight of a near-net component with significant high temperature corrosion protection by forming a surface oxide layer. However, above critical service conditions (temperature, atmosphere, thermal cycling), oxidized surface can result in intensive surface degradation due to scale spallation. Scale spallation can decrease the wall thickness which could be detrimental to the in-service life of thin-walled castings. Experiments and stochastic simulations of spallation assisted oxidation were performed with three cast austenitic heat-resistant steels having different Cr–Ni concentrations at temperatures between 900 and 1000 ℃ on air and water vapor …
Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli
Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli
USF Tampa Graduate Theses and Dissertations
Aquifer storage and recovery technology is used to sustain water resources and to prevent saltwater intrusion. The injected water can come from various resources, including treated wastewater. In pilot ASR studies in the Tampa Bay region, researchers found high As concentrations in the recovered water from the oxidation of the arsenopyrite that is embedded in the aquifers. The presence of dissolved O2 in the injected water is a major factor in the arsenopyrite oxidation during ASR, however the effects of NO3- on the arsenopyrite has not been studied yet. This is an important knowledge gap because injected water may contain …
Analysis Of The Possibility Of Increasing The Degree Of Zinc Waelz And Reducing Metal Losses During Waelz, Bakhriddin Tilovkabulovich Berdiyarov Dr.
Analysis Of The Possibility Of Increasing The Degree Of Zinc Waelz And Reducing Metal Losses During Waelz, Bakhriddin Tilovkabulovich Berdiyarov Dr.
Technical science and innovation
The article examines the flow process of zinc cakes, which is formed during the selective melting of zinc burns, and the factors influencing it. The effects of silica and calcium oxide on the combustion of coke added to the Welting process were analyzed. When the kinetic kinetics of zinc ferrites and silicates present in zinc cakes are studied, the addition of lime to the strategy promotes the thermodynamic recovery of zinc and reduces graphite consumption.The article also examines the temperature dependence of the rate of reduction reactions of zinc silicate and zinc oxides. Studies of the kinetics of coal-thermal reduction …
Steam Oxidation Of Ytterbium Disilicate Environmental Barrier Coatings With And Without A Silicon Bond Coat, Ken A. Kane, Eugenio Garcia, Sharon Uwanyuze, Michael Lance, Kinga A. Unocic, Sanjay Sampath, Bruce A. Pint
Steam Oxidation Of Ytterbium Disilicate Environmental Barrier Coatings With And Without A Silicon Bond Coat, Ken A. Kane, Eugenio Garcia, Sharon Uwanyuze, Michael Lance, Kinga A. Unocic, Sanjay Sampath, Bruce A. Pint
Materials Science and Engineering Faculty Research & Creative Works
The current generation of multilayer Si/Yb2Si2O7 environmental barrier coatings (EBCs) are temperature limited by the melting point of Si, 1414°C. To investigate higher temperature EBCs, the cyclic steam oxidation of EBCs comprised of a single layer of ytterbium disilicate (YbDS) was compared to multilayered Si/YbDS EBCs, both deposited on SiC substrates using atmospheric plasma spray. After 500 1-h cycles at 1300°C in 90 vol%H2O-10 vol%air with a gas velocity of 1.5 cm/s, both multilayer Si/YbDS and single layer YbDS grew thinner silica scales than bare SiC, with the single layer YbDS forming the …
Design And Implementation Of An Oxidation Catalyst For A Spark Ignited Two Stroke Snowmobile Engine, Noah Squires
Design And Implementation Of An Oxidation Catalyst For A Spark Ignited Two Stroke Snowmobile Engine, Noah Squires
Dissertations, Master's Theses and Master's Reports
Spark ignited two stroke engines are under increasing pressure as emissions standards become stricter, making them a perfect candidate for a catalytic aftertreatment system. Yet several significant challenges to catalysis exist. Namely two stroke exhaust systems are very sensitive to back pressure changes and high emissions concentrations can make controlling the temperature of the catalytic reaction difficult. Therefore, it is imperative that a two stroke specific catalyst design process be developed. This project focused on beginning to develop such a design process. Key results of this work include finding a location for the catalyst in the exhaust system that offers …
The Effects Of Oxidized Biodiesel Fuel On Fatty Acid Methyl Ester Composition And Particulate Matter Emissions From A Light-Duty Diesel Engine, Jack Elliot Reed
The Effects Of Oxidized Biodiesel Fuel On Fatty Acid Methyl Ester Composition And Particulate Matter Emissions From A Light-Duty Diesel Engine, Jack Elliot Reed
Graduate College Dissertations and Theses
Diesel particulate matter (PM) is classified by the EPA as carcinogenic, with the transportation sector largely responsible these emissions within the United States. Biodiesel (B100) is derived from renewable sources, providing similar chemical composition to diesel fuel and is in the current diesel supply up to 5% across the nation. However, biodiesel has an inherent oxidation issue due to the unique mixture of fatty acid methyl ester (FAME) molecules present in the biodiesel that are not in diesel. Biodiesel oxidation can only be delayed, and the inevitable process results in changes to the original fuel composition that may alter emissions …
Advanced Raman Spectroscopy Detection Of Oxidative Damage In Nucleic Acid Bases: Probing Chemical Changes And Intermolecular Interactions In Guanosine At Ultralow Concentration, Francesca Ripanti, Claudia Fasolato, Flavia Mazzarda, Simonetta Palleschi, Marina Ceccarini, Chunchun Li, Margherita Bignami, Enrico Bodo, Steven E.J. Bell, Filomena Mazzei, Paolo Postorino
Advanced Raman Spectroscopy Detection Of Oxidative Damage In Nucleic Acid Bases: Probing Chemical Changes And Intermolecular Interactions In Guanosine At Ultralow Concentration, Francesca Ripanti, Claudia Fasolato, Flavia Mazzarda, Simonetta Palleschi, Marina Ceccarini, Chunchun Li, Margherita Bignami, Enrico Bodo, Steven E.J. Bell, Filomena Mazzei, Paolo Postorino
Bioelectrics Publications
DNA/RNA synthesis precursors are especially vulnerable to damage induced by reactive oxygen species occurring following oxidative stress. Guanosine triphosphates are the prevalent oxidized nucleotides, which can be misincorporated during replication, leading to mutations and cell death. Here, we present a novel method based on micro-Raman spectroscopy, combined with ab initio calculations, for the identification, detection, and quantification of oxidized nucleotides at low concentration. We also show that the Raman signature in the terahertz spectral range (<100 >cm(-1)) contains information on the intermolecular assembly of guanine in tetrads, which allows us to further boost the oxidative damage detection limit. Eventually, we …100>
A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin
A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin
Faculty Publications
High entropy alloys (HEAs) are promising candidates for high-temperature structural material applications. Oxidation is a major factor that must be accounted for when designing such materials and it is thus important to study the oxidation behavior of HEAs to enable the optimum design of next generation materials. In this study, the thermodynamic behavior of interstitial oxygen in a Mo-Nb-Ta-W high entropy alloy was explored beyond the dilute limit. This was accomplished by sampling configurations of the HEA and HEA-oxygen systems from an isothermal–isobaric ensemble using a series of first-principle-based Monte Carlo simulations. It was found that the interstitial oxygen had …
Study Of Gold Ore Deposits Of Aristantau For Resilience And Search Technologies For Its Processing, Kuvandik Sanakulov, Omon Fuzaylov, J.A. Kenbaeva
Study Of Gold Ore Deposits Of Aristantau For Resilience And Search Technologies For Its Processing, Kuvandik Sanakulov, Omon Fuzaylov, J.A. Kenbaeva
Gorniy vestnik Uzbekistana
The article presents the results of research of chemical, material, mineralogical and rational analyses of persistent gold-bearing ore of The aristantau Deposit. The re- sults of experiments indicated the content of sulfide sulfur, organic carbon, arsenic and antimony. As a result, the technological scheme included operations for oxidative firing of the flotation concentrate. Various forms of fine-grained gold were found in pyrite, arsenopyrite, and sphalerite.
A Novel Method For Making Titanium Dioxide For Photocatalytic Applications, Gary Wilson
A Novel Method For Making Titanium Dioxide For Photocatalytic Applications, Gary Wilson
Graduate Theses & Non-Theses
Titanium dioxide possesses near-ideal properties for large-scale application as a photocatalyst. It is cheap and abundant, nontoxic, and environmentally safe. However, it still suffers from logistical problems preventing its application in industry: namely, rapid electron-hole recombination and inability to utilize visible light. For nearly five decades researchers in this booming field have made numerous attempts to address these problems, doping and combining titanium dioxide with a wide range of materials. A novel ambient-temperature approach to synthesis and doping/modification of anatase-form titanium dioxide was attempted using both oxygen-rich and oxygen deprived synthetic routes. Reactants were exposed to various wavelengths of ultraviolet …
Fluvial Sediment Organic Matter Degradation Identified With Elemental And Isotopic Fate During Laboratory Incubation, Brenden Riddle
Fluvial Sediment Organic Matter Degradation Identified With Elemental And Isotopic Fate During Laboratory Incubation, Brenden Riddle
Theses and Dissertations--Civil Engineering
Fluvial sediment is well recognized as a critical factor in both carbon and nutrient budgets within stream systems. However, we find very few studies of reactivity and isotope enrichment for stream water from agricultural and urban streams and the class of substrate known as fluvial sediment organic matter. This study investigated the hypothesis that fluvial sediment is subject to degradation even though many previous studies have considered this class of substrate generally inert. Therefore we qualify that elemental and isotopic signatures of fluvial sediment organic matter should be considered potentially non-conservative when used in tracer studies. Methods applied to this …