Engineering Commons^™

Compositional Changes For Reduction Of Polymerisation-Induced Shrinkage In Holo, Dervil Cody, Mohesh Moothanchery, Emilia Mihaylova, Vincent Toal, Svetlana Mintova, Izabela Naydenova

Doctoral

Polymerisation-induced shrinkage is one of the main reasons why many photopolymer materials are not used for certain applications including holographic optical elements and holographic data storage. Here, two compositional changes for the reduction of shrinkage in an acrylamide-based photopolymer are reported. A holographic interferometric technique was used to study changes in the dynamics of the shrinkage processes occurring in the modified photopolymer during holographic recording in real time. Firstly, the effect of the replacement of the acrylamide monomer in the photopolymer composition with a larger monomer molecule, diacetone acrylamide, on polymerisation-induced shrinkage has been studied. A reduction in relative shrinkage …