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Chemical Engineering

Jason R. Hattrick-Simpers

Materials Science and Engineering

Articles 1 - 30 of 30

Full-Text Articles in Engineering

Magnetic Properties Of Crystals Of La5Mo4-XTXO16, S. Lofland, Jason Hattrick-Simpers, K. Ramanujachary, W. Mccarroll Mar 2015

Magnetic Properties Of Crystals Of La5Mo4-XTXO16, S. Lofland, Jason Hattrick-Simpers, K. Ramanujachary, W. Mccarroll

Jason R. Hattrick-Simpers

No abstract provided.


Development Of A High-Throughput Methodology For Screening Coking Resistance Of Modified Thin-Film Catalysts, Kaijian Yang, John Bedenbaugh, Hang Li, Michael Peralta, Johnathan Bunn, Jochen Lauterbach, Jason Hattrick-Simpers Mar 2015

Development Of A High-Throughput Methodology For Screening Coking Resistance Of Modified Thin-Film Catalysts, Kaijian Yang, John Bedenbaugh, Hang Li, Michael Peralta, Johnathan Bunn, Jochen Lauterbach, Jason Hattrick-Simpers

Jason R. Hattrick-Simpers

No abstract provided.


Applications Of High Throughput Screening Tools For Thermoelectric Materials, W. Wong-Ng, H. Joress, J. Martin, Y. Yan, M. Otani, E. Thomas, M. Green, Jason Hattrick-Simpers Mar 2015

Applications Of High Throughput Screening Tools For Thermoelectric Materials, W. Wong-Ng, H. Joress, J. Martin, Y. Yan, M. Otani, E. Thomas, M. Green, Jason Hattrick-Simpers

Jason R. Hattrick-Simpers

No abstract provided.


Data Management And Visualization Of X-Ray Diffraction Spectra From Thin Film Ternary Composition Spreads, I. Takeuchi, C. Long, O. Famodu, M. Murakami, Jason Hattrick-Simpers, G. Rubloff, M. Stukowski, K. Rajan Mar 2015

Data Management And Visualization Of X-Ray Diffraction Spectra From Thin Film Ternary Composition Spreads, I. Takeuchi, C. Long, O. Famodu, M. Murakami, Jason Hattrick-Simpers, G. Rubloff, M. Stukowski, K. Rajan

Jason R. Hattrick-Simpers

We discuss techniques for managing and visualizing x-ray diffraction spectrum data for thin film composition spreads which map large fractions of ternary compositional phase diagrams. An in-house x-ray microdiffractometer is used to obtain spectra from over 500 different compositions on an individual spread. The MATLAB software is used to quickly organize the data and create various plots from which one can quickly grasp different information regarding structural and phase changes across the composition spreads. Such exercises are valuable in rapidly assessing the “overall” picture of the structural evolution across phase diagrams before focusing in on specific composition regions for detailed …


High-Throughput Screening Of Magnetic Properties Of Quench Metallic-Alloy Thin-Film Composition Spreads, Jason Hattrick-Simpers, Cui Jun, Makoto Murakami, Antonio Orozco, Lee Knauss, Robert Booth, Edward Greve, Samuel Lofland, Manfred Wuttig, Ichiro Takeuchi Mar 2015

High-Throughput Screening Of Magnetic Properties Of Quench Metallic-Alloy Thin-Film Composition Spreads, Jason Hattrick-Simpers, Cui Jun, Makoto Murakami, Antonio Orozco, Lee Knauss, Robert Booth, Edward Greve, Samuel Lofland, Manfred Wuttig, Ichiro Takeuchi

Jason R. Hattrick-Simpers

No abstract provided.


Data Analysis In Combinatorial Experiments: Applying Supervised Principal Component Technique To Investigate The Relationship Between Tof-Sims Spectra And The Composition Distribution Of Ternary Metallic Alloy Thin Films, Rossana Dell'anna, Palo Lazzeri, Roberto Canteri, Christian Long, Jason Hattrick-Simpers, Ichiro Takeuchi, Mariano Anderle Mar 2015

Data Analysis In Combinatorial Experiments: Applying Supervised Principal Component Technique To Investigate The Relationship Between Tof-Sims Spectra And The Composition Distribution Of Ternary Metallic Alloy Thin Films, Rossana Dell'anna, Palo Lazzeri, Roberto Canteri, Christian Long, Jason Hattrick-Simpers, Ichiro Takeuchi, Mariano Anderle

Jason R. Hattrick-Simpers

No abstract provided.


Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers Mar 2015

Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers

Jason R. Hattrick-Simpers

High throughput (combinatorial) materials science methodology is a relatively new research paradigm that offers the promise of rapid and efficient materials screening, optimization, and discovery. The paradigm started in the pharmaceutical industry but was rapidly adopted to accelerate materials research in a wide variety of areas. High throughput experiments are characterized by synthesis of a “library” sample that contains the materials variation of interest (typically composition), and rapid and localized measurement schemes that result in massive data sets. Because the data are collected at the same time on the same “library” sample, they can be highly uniform with respect to …


Phase Transformation In An Yttrium-Hydrogen System Studied By Tem, K. Wang, Jason Hattrick-Simpers, L. Bendersky Mar 2015

Phase Transformation In An Yttrium-Hydrogen System Studied By Tem, K. Wang, Jason Hattrick-Simpers, L. Bendersky

Jason R. Hattrick-Simpers

No abstract provided.


Fabrication And Characterization Of In-Situ Grown Epitaxial Ba1-XSrXTio3 Composition Spreads, K. Chang, M. Aronova, O. Famodu, Jason Hattrick-Simpers, S. Lofland, I. Takeuchi, C. Lu, L. Bendersky, H. Chang Mar 2015

Fabrication And Characterization Of In-Situ Grown Epitaxial Ba1-XSrXTio3 Composition Spreads, K. Chang, M. Aronova, O. Famodu, Jason Hattrick-Simpers, S. Lofland, I. Takeuchi, C. Lu, L. Bendersky, H. Chang

Jason R. Hattrick-Simpers

No abstract provided.


Raman Spectroscopic Observation Of Dehydration In Ball-Milled Linh2-Libh4-Mgh2 Nanoparticles, Jason Hattrick-Simpers, James Maslar, Michael Niemann, Chun Chiu, Sesha Srinivasan, Elias Stefanakos, Leonid Bendersky Mar 2015

Raman Spectroscopic Observation Of Dehydration In Ball-Milled Linh2-Libh4-Mgh2 Nanoparticles, Jason Hattrick-Simpers, James Maslar, Michael Niemann, Chun Chiu, Sesha Srinivasan, Elias Stefanakos, Leonid Bendersky

Jason R. Hattrick-Simpers

No abstract provided.


Synthesis And Characterization Of Sr3Femoo6.88: An Oxygen-Deficient 2d Analogue Of The Double Perobskite Sr2Femoo6, Gabriel Veith, Martha Greenblatt, Mark Croft, K. Ramanujachary, Jason Hattrick-Simpers, Samuel Lofland, Israel Nowik Mar 2015

Synthesis And Characterization Of Sr3Femoo6.88: An Oxygen-Deficient 2d Analogue Of The Double Perobskite Sr2Femoo6, Gabriel Veith, Martha Greenblatt, Mark Croft, K. Ramanujachary, Jason Hattrick-Simpers, Samuel Lofland, Israel Nowik

Jason R. Hattrick-Simpers

No abstract provided.


Determination Of Work Functions In The Ta1-XAlXNY/Hfo2 Advanced Gate Stack Using Combinatorial Methodology, Kao-Shuo Chang, Martin Green, Jason Hattrick-Simpers, Ichiro Takeuchi, J. Suehle, O. Celik, S. De Gendt Mar 2015

Determination Of Work Functions In The Ta1-XAlXNY/Hfo2 Advanced Gate Stack Using Combinatorial Methodology, Kao-Shuo Chang, Martin Green, Jason Hattrick-Simpers, Ichiro Takeuchi, J. Suehle, O. Celik, S. De Gendt

Jason R. Hattrick-Simpers

No abstract provided.


Phase Formation And Hydrogen Ordering In Yttrium-Hydrogen System, Ke Wang, Jason Hattrick-Simpers, Leonid Bendersky Mar 2015

Phase Formation And Hydrogen Ordering In Yttrium-Hydrogen System, Ke Wang, Jason Hattrick-Simpers, Leonid Bendersky

Jason R. Hattrick-Simpers

No abstract provided.


Combinatorial Study Of Ni-Ti-Pt Ternary Metal Gate Electrodes On Hfo2 For The Advanced Gate Stack, K.-S. Chang, M. Green, J. Suehle, E. Vogel, H. Xiong, Jason Hattrick-Simpers, I. Takeuchi, O. Famodu, K. Ohmori, P. Ahmet, T. Chikyow, P. Majhi, B.-H. Lee, M. Gardner Mar 2015

Combinatorial Study Of Ni-Ti-Pt Ternary Metal Gate Electrodes On Hfo2 For The Advanced Gate Stack, K.-S. Chang, M. Green, J. Suehle, E. Vogel, H. Xiong, Jason Hattrick-Simpers, I. Takeuchi, O. Famodu, K. Ohmori, P. Ahmet, T. Chikyow, P. Majhi, B.-H. Lee, M. Gardner

Jason R. Hattrick-Simpers

The authors have fabricated combinatorial Ni–Ti–Pt ternary metal gate thin film libraries on HfO2 using magnetron co-sputtering to investigate flatband voltage shift (ΔVfb) , work function (Φm) , and leakage current density (JL) variations. A more negative ΔVfb is observed close to the Ti-rich corner than at the Ni- and Pt-rich corners, implying smaller Φm near the Ti-rich corners and higher Φm near the Ni- and Pt-rich corners. In addition, measured JL values can be explained consistently with the observed Φm variations. Combinatorial methodologies prove to be useful in surveying the large compositional space of ternary alloymetal gate electrode systems.


High-Throughput Characterization Of Shape Memory Thin Films Using Automated Temperature-Dependent Resistance Measurements, Sigurd Thienhaus, Christiane Zamponi, Holger Rumpf, Jason Hattrick-Simpers, Ichiro Takeuchi, Alfred Ludwig Mar 2015

High-Throughput Characterization Of Shape Memory Thin Films Using Automated Temperature-Dependent Resistance Measurements, Sigurd Thienhaus, Christiane Zamponi, Holger Rumpf, Jason Hattrick-Simpers, Ichiro Takeuchi, Alfred Ludwig

Jason R. Hattrick-Simpers

No abstract provided.


The Materials Super Highway: Integrating High-Throughput Experimentation Into Mapping The Catalysis Materials Genome, Jason Hattrick-Simpers, Cun Wen, Jochen Lauterbach Mar 2015

The Materials Super Highway: Integrating High-Throughput Experimentation Into Mapping The Catalysis Materials Genome, Jason Hattrick-Simpers, Cun Wen, Jochen Lauterbach

Jason R. Hattrick-Simpers

No abstract provided.


A Semi-Empirical Model For Tilted-Gun Planar Magnetron Sputtering Accounting For Chimney Shadowing, Johnathan Bunn, C. Metting, Jason Hattrick-Simpers Mar 2015

A Semi-Empirical Model For Tilted-Gun Planar Magnetron Sputtering Accounting For Chimney Shadowing, Johnathan Bunn, C. Metting, Jason Hattrick-Simpers

Jason R. Hattrick-Simpers

No abstract provided.


Combinatorial Approach To Turbine Bond Coat Discovery, Christopher Metting, Johnathan Bunn, Ellen Underwood, Stephen Smoak, Jason Hattrick-Simpers Mar 2015

Combinatorial Approach To Turbine Bond Coat Discovery, Christopher Metting, Johnathan Bunn, Ellen Underwood, Stephen Smoak, Jason Hattrick-Simpers

Jason R. Hattrick-Simpers

No abstract provided.


Recent Developments In Thermoelectric Metrology At Nist, W. Wong-Ng, J. Martin, E. Thomas, M. Otani, N. Lowhorn, M. Green, G. Liu, Y. Yan, Jason Hattrick-Simpers, T. Tran Mar 2015

Recent Developments In Thermoelectric Metrology At Nist, W. Wong-Ng, J. Martin, E. Thomas, M. Otani, N. Lowhorn, M. Green, G. Liu, Y. Yan, Jason Hattrick-Simpers, T. Tran

Jason R. Hattrick-Simpers

No abstract provided.


Giant Magnetostriction In Annealed Co1-XFeX Thin-Films, Dwight Hunter, Will Osborn, Ke Wang, Nataliya Kazantseva, Jason R. Hattrick-Simpers, Richard Suchoski, Ryota Takahashi, Marcus L. Young, Apurva Mehta, Leonid A. Bendersky, Same E. Lofland, Manfred Wuttig, Ichiro Takeuchi Mar 2015

Giant Magnetostriction In Annealed Co1-XFeX Thin-Films, Dwight Hunter, Will Osborn, Ke Wang, Nataliya Kazantseva, Jason R. Hattrick-Simpers, Richard Suchoski, Ryota Takahashi, Marcus L. Young, Apurva Mehta, Leonid A. Bendersky, Same E. Lofland, Manfred Wuttig, Ichiro Takeuchi

Jason R. Hattrick-Simpers

Chemical and structural heterogeneity and the resulting interaction of coexisting phases can lead to extraordinary behaviours in oxides, as observed in piezoelectric materials at morphotropic phase boundaries and relaxor ferroelectrics. However, such phenomena are rare in metallic alloys. Here we show that, by tuning the presence of structural heterogeneity in textured Co1−xFex thin films, effective magnetostriction λeff as large as 260 p.p.m. can be achieved at low-saturation field of ~10 mT. Assuming λ100 is the dominant component, this number translates to an upper limit of magnetostriction ofλ100≈5λeff >1,000 p.p.m. Microstructural analyses …


Combinatorial Investigation Of Ferromagnetic Shape-Memory Alloys In The Ni-Mn-Al Ternary System Using A Composition Spread Technique, Olugbenga Famodu, Jason Hattrick-Simpers, Maria Aronova, Kao-Shou Chang, Makoto Murakami, Manfred Wuttig, Teiko Okazaki, Yasubumi Furuya, Lee Knauss, Leonid Bendersky, Frank Biaricaniello, Ichiro Takeuchi Mar 2015

Combinatorial Investigation Of Ferromagnetic Shape-Memory Alloys In The Ni-Mn-Al Ternary System Using A Composition Spread Technique, Olugbenga Famodu, Jason Hattrick-Simpers, Maria Aronova, Kao-Shou Chang, Makoto Murakami, Manfred Wuttig, Teiko Okazaki, Yasubumi Furuya, Lee Knauss, Leonid Bendersky, Frank Biaricaniello, Ichiro Takeuchi

Jason R. Hattrick-Simpers

No abstract provided.


Observation Of Phase Transitions In Hydrogenated Yttrium Films Via Normalized Infrared Emissivity, Jason Hattrick-Simpers, Ke Wang, Lei Cao, Chun Chiu, Edwin Heilweil, Robert Downing, Leonid Bendersky Mar 2015

Observation Of Phase Transitions In Hydrogenated Yttrium Films Via Normalized Infrared Emissivity, Jason Hattrick-Simpers, Ke Wang, Lei Cao, Chun Chiu, Edwin Heilweil, Robert Downing, Leonid Bendersky

Jason R. Hattrick-Simpers

No abstract provided.


Combinatorial Study Of Thin Film Metal Hydride By Prompt Gamma Activation Analysis, L. Cao, Jason Hattrick-Simpers, R. Bindel, R. Bindel, B. Tomlin, R. Zeisler, R. Paul, L. Bendersky, R. Downing Mar 2015

Combinatorial Study Of Thin Film Metal Hydride By Prompt Gamma Activation Analysis, L. Cao, Jason Hattrick-Simpers, R. Bindel, R. Bindel, B. Tomlin, R. Zeisler, R. Paul, L. Bendersky, R. Downing

Jason R. Hattrick-Simpers

No abstract provided.


Combinatorial Search Of Thermoelastic Shape-Memory Alloys With Extremely Small Hysteresis Width, Jun Cui, Yong Chu, Olugbenga Famodu, Yasubumi Furuya, Jason Hattrick-Simpers, Richard James, Alfred Ludwig, Sigurd Thienhaus, Manfred Wuttig, Zhiyong Zhang, Ichiro Takeuchi Mar 2015

Combinatorial Search Of Thermoelastic Shape-Memory Alloys With Extremely Small Hysteresis Width, Jun Cui, Yong Chu, Olugbenga Famodu, Yasubumi Furuya, Jason Hattrick-Simpers, Richard James, Alfred Ludwig, Sigurd Thienhaus, Manfred Wuttig, Zhiyong Zhang, Ichiro Takeuchi

Jason R. Hattrick-Simpers

No abstract provided.


Enhanced Dielectric Properties In Single Crystal-Like Bifeo3 Thin Films Grown By Flux-Mediated Epitaxy, S.-H. Lim, M. Murakami, J. Yang, S.-Y. Young, Jason Hattrick-Simpers, M. Wuttig, L. Salamanca-Riba, I. Takeuchi Mar 2015

Enhanced Dielectric Properties In Single Crystal-Like Bifeo3 Thin Films Grown By Flux-Mediated Epitaxy, S.-H. Lim, M. Murakami, J. Yang, S.-Y. Young, Jason Hattrick-Simpers, M. Wuttig, L. Salamanca-Riba, I. Takeuchi

Jason R. Hattrick-Simpers

We have fabricated single crystal-like BiFeO3 (BFO) thin films by flux-mediated epitaxy using pulsed laser deposition(PLD). The Bi–Cu–O flux composition and its thickness were optimized using composition spread, thickness gradient, and temperature gradient libraries. The optimized BFO thin films grown with this technique showed larger grain size of ∼2μm and higher dielectric constant in the range of 260–340 than those for standard PLD grown films. In addition, the leakage current density of the films was reduced by two orders of magnitude compared to that of standard PLD grown films.


Tunable Multiferroic Properties In Nanocomposite Pbtio3-Cofe2O4 Epitaxial Thin Films, M. Murakami, K.-S. Chang, M. Aronova, C.-L. Lin, Ming Yu, Jason Hattrick-Simpers, M. Wuttig, I. Takeuchi, C. Gao, B. Hu, S. Lofland, L. Knauss, L. Bendersky Mar 2015

Tunable Multiferroic Properties In Nanocomposite Pbtio3-Cofe2O4 Epitaxial Thin Films, M. Murakami, K.-S. Chang, M. Aronova, C.-L. Lin, Ming Yu, Jason Hattrick-Simpers, M. Wuttig, I. Takeuchi, C. Gao, B. Hu, S. Lofland, L. Knauss, L. Bendersky

Jason R. Hattrick-Simpers

We report on the synthesis of PbTiO3–CoFe2O4 multiferroic nanocomposites and continuous tuning of their ferroelectric and magnetic properties as a function of the average composition on thin-film composition spreads. The highest dielectric constant and nonlinear dielectric signal was observed at (PbTiO3)85–(CoFe2O4)15, where robust magnetism was also observed. Transmission electron microscopy revealed a pancake-shaped epitaxial nanostructure of PbTiO3 on the order of 30 nm embedded in the matrix of CoFe2O4 at this composition. Composition dependent ferroics properties observed here indicate that there is considerable interdiffusion of cations into each other.


Synthesis Of Mono-Disperse Cofe Alloy Nanoparticles With High Activity Toward Nabh4 Hydrolysis, Cun Wen, Xin Zhang, Samuel Lofland, Jochen Lauterbach, Jason Hattrick-Simpers Mar 2015

Synthesis Of Mono-Disperse Cofe Alloy Nanoparticles With High Activity Toward Nabh4 Hydrolysis, Cun Wen, Xin Zhang, Samuel Lofland, Jochen Lauterbach, Jason Hattrick-Simpers

Jason R. Hattrick-Simpers

No abstract provided.


Demonstration Of Magnetoelectric Scanning Probe Microscopy, Jason R. Hattrick-Simpers, Liyang Dai, Manfred Wuttig, Ichiro Takeuchi, Eckhard Quandt Mar 2015

Demonstration Of Magnetoelectric Scanning Probe Microscopy, Jason R. Hattrick-Simpers, Liyang Dai, Manfred Wuttig, Ichiro Takeuchi, Eckhard Quandt

Jason R. Hattrick-Simpers

A near-field room temperature scanning magnetic probe microscope has been developed using a laminated magnetoelectric sensor. The simple trilayer longitudinal-transverse mode sensor, fabricated using Metglas as the magnetostrictive layer and polyvinylidene fluoride as the piezoelectric layer, shows an ac field sensitivity of 467±3μV∕Oe in the measured frequency range of 200Hz–8kHz. The microscope was used to image a 2mm diameter ring carrying an ac current as low as 10−5A. ac fields as small as 3×10−10T have been detected.


Exploration Of Artificial Multiferroic Thin-Film Heterostructures Using Composition Spreads, K.-S. Chang, M. A. Aronova, C.-L. Lin, M. Murakami, M.-H. Yu, Jason R. Hattrick-Simpers, O. O. Famodu, S. Y. Lee, R. Ramesh, M. Wuttig, I. Takeuchi, C. Gao, L. A. Bendersky Mar 2015

Exploration Of Artificial Multiferroic Thin-Film Heterostructures Using Composition Spreads, K.-S. Chang, M. A. Aronova, C.-L. Lin, M. Murakami, M.-H. Yu, Jason R. Hattrick-Simpers, O. O. Famodu, S. Y. Lee, R. Ramesh, M. Wuttig, I. Takeuchi, C. Gao, L. A. Bendersky

Jason R. Hattrick-Simpers

We have fabricated a series of composition spreads consisting of ferroelectric BaTiO3 and piezomagnetic CoFe2O4 layers of varying thicknesses modulated at nanometer level in order to explore artificial magnetoelectricthin-film heterostructures. Scanning microwavemicroscopy and scanning superconducting quantum interference device microscopy were used to map the dielectric and magnetic properties as a function of continuously changing average composition across the spreads, respectively. Compositions in the middle of the spreads were found to exhibit ferromagnetism while displaying a dielectric constant as high as ≈120.


Multimode Quantitative Scanning Microwave Microscopy Of In Situ Grown Epitaxial Ba1-XSrXTio3 Composition Spreads, K. Chang, M. Aronova, O. Famodu, I. Takeuchi, S. Lofland, Jason Hattrick-Simpers, H. Chang Mar 2015

Multimode Quantitative Scanning Microwave Microscopy Of In Situ Grown Epitaxial Ba1-XSrXTio3 Composition Spreads, K. Chang, M. Aronova, O. Famodu, I. Takeuchi, S. Lofland, Jason Hattrick-Simpers, H. Chang

Jason R. Hattrick-Simpers

We have performed variable-temperature multimode quantitative microwavemicroscopy of in situepitaxial Ba1−xSrxTiO3 thin-film composition spreads fabricated on (100) LaA1O3 substrates. Dielectric properties were mapped as a function of continuously varying composition from BaTiO3 to SrTiO3. We have demonstrated nondestructive temperature-dependent dielectric characterization of local thin-film regions. Measurements are simultaneously taken at multiple resonant frequencies of the microscope cavity. The multimode measurements allow frequency dispersion studies. We observe strong composition-dependent dielectric relaxation in Ba1−xSrxTiO3 at microwave frequencies.