Engineering Commons^™

Cu/Bnx Catalysts For Electrocatalytic Reduction Of Nitrogen And Nitrate Waste, Siming Huo

Dissertations

Ammonia (NH₃) is one of the most important chemicals to the whole human society. The invention of the Haber-Bosch process enabled the industrial production of NH₃. However, owing to the high capital costs of the centralized plant and the equipment and the negative environmental impact, it is no longer suitable for today's needs of human development. As a result, there is an urgent need to investigate sustainable approaches for ammonia production. Among those reported studies, nitrogen reduction (NRR) and nitrate reduction reaction (NO₃RR) are considered applicable in the future. However, after decades of studying …

Generation Of Plasma With A Rotating Electric Field, Franklin Price Mosely

Electrical & Computer Engineering Theses & Dissertations

Nonthermal plasma generation is an important area of research that has many applications ranging from semiconductor production to medical applications including the treatment of cancers and sterilization of surfaces. Specific radicals and excited species and discharge powers are critical for the successful completion of these processes. It is important that these excited species are shown to be achievable for a given discharge system without leading to instabilities such as arcing.

The present thesis details the design, fabrication, testing, and analysis of a novel plasma generation system based on multiphase excitation. As predicted by theory, the experimental results demonstrate that a …

Application Of Direct Simulation Monte Carlo Method To Computation Of Rf Signal Degradation During Hypersonic Flight, Andrew Derubertis

McKelvey School of Engineering Theses & Dissertations

In order to further understand the hypersonic blackout problem, the first step is to investigate models to quantify signal degradation and begin implementing these models to representative plasma sheath and flow data. This research is the first attempt at implementing a model to predict RF signal degradation through the plasma sheath surrounding the hypersonic air vehicle. The investigation is performed using a Direct Simulation Monte Carlo (DSMC) based flow solver. The dsmcFoam solver in the OpenFoam library is used to simulate the flow around hypersonic bodies to obtain flow field properties, most importantly the electron number density profile, to aid …

Ambient Ammonia Synthesis Via Microwave-Catalytic Materials And Plasma Chemistry, Siobhan Brown

Graduate Theses, Dissertations, and Problem Reports

Ammonia is critical to supporting human life on earth because of its use as fertilizer. The Haber-Bosch process to produce ammonia has been practiced for over 100 years. This process operates at high pressure and temperature to overcome the thermodynamic and kinetic limitations of the ammonia synthesis reaction thus researchers have tried to overcome it for decades. At present this process represents 1% of global energy usage and 2.5% of global CO₂ emissions. The proposed chemical looping ammonia synthesis approach seeks to reduce the environmental impact of this critical process and to elucidate microwave-catalytic principles.

This research aims to …

On The Chronological Understanding Of The Homogeneous Dielectric Barrier Discharge, Xinpei Lu, Zhi Fang, Dong Dai, Tao Shao, Feng Liu, Cheng Zhang, Dawei Liu, Chunqi Jiang

Electrical & Computer Engineering Faculty Publications

Dielectric barrier discharges (DBD) are widely utilised non-equilibrium atmospheric pressure plasmas with a diverse range of applications, such as material processing, surface treatment, light sources, pollution control, and medicine. Over the course of several decades, extensive research has been dedicated to the generation of homogeneous DBD (H-DBD), focussing on understanding the transition from H-DBD to filamentary DBD and exploring strategies to create and sustain H-DBD. This paper first discusses the influence of various parameters on DBD, including gas flow, dielectric material, surface conductivity, and mesh electrode. Secondly, a chronological literature review is presented, highlighting the development of H-DBD and the …

On The Chronological Understanding Of The Homogeneous Dielectric Barrier Discharge, Xinpei Lu, Zhi Fang, Dong Dai, Tao Shao, Feng Liu, Cheng Zhang, Dawei Liu, Lanlan Nie, Chunqi Jiang

Bioelectrics Publications

Dielectric barrier discharges (DBD) are widely utilised non-equilibrium atmospheric pressure plasmas with a diverse range of applications, such as material processing, surface treatment, light sources, pollution control, and medicine. Over the course of several decades, extensive research has been dedicated to the generation of homogeneous DBD (H-DBD), focussing on understanding the transition from H-DBD to filamentary DBD and exploring strategies to create and sustain H-DBD. This paper first discusses the influence of various parameters on DBD, including gas flow, dielectric material, surface conductivity, and mesh electrode. Secondly, a chronological literature review is presented, highlighting the development of H-DBD and the …

Surface Volatilization Investigation Of Graphite, Mitchell Stern

Graduate College Dissertations and Theses

The re-entry vehicle posseses enough kinetic energy that it becomes hypersonic while passing throughthe upper atmosphere. This kinetic energy is quickly transferred into thermal energy as the quiescent atmosphere turned hypersonics with reference to the vehicle suddenly stagnates. Furthermore, the high energy process of generating plasma also ablates the leading edge surfaces, causing reactions between the charged gasses and the solid material composing the thermal protection system (TPS) of the aircraft. These reactions can be exothermic an d pose an additional mode of heat transfer into the body of the aircraft. Learning more about the interactions within the boundary layer …