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Articles 1 - 5 of 5
Full-Text Articles in Engineering
High Temperature Oxidation Kinetics Of Alumina Forming Steels For Petrochemical Processes, Kao Zoua Yang
High Temperature Oxidation Kinetics Of Alumina Forming Steels For Petrochemical Processes, Kao Zoua Yang
Theses and Dissertations
Petrochemical industries produce 14.33 million barrels of petroleum products a day and by 2023, are expected to produce over a trillion dollars in sales annually. Petroleum is the number one used fuel source and is the raw material used to produce a wide range of petrochemical products including ethylene which is the raw chemical precursors that is crucial to the polymer market. Ethylene is created by the process of cracking ethane and other hydrocarbons in steel reactors at high temperature and potentially oxidizing conditions. The cracking process produces a range of byproducts including a detrimental solid carbon, called coke, which …
Uncertainty Quantification And Constraint Of Chemical Kinetic Mechanisms Based On Flow Reactor Experiments, Ana Victoria Kock
Uncertainty Quantification And Constraint Of Chemical Kinetic Mechanisms Based On Flow Reactor Experiments, Ana Victoria Kock
Theses and Dissertations
The chemical kinetic model is one of key sub-models for computational fluid dynamics (CFD) simulation for optimizing and designing various combustors/engines. Detailed chemical kinetic models can consist of hundreds of species and thousands of elementary reaction steps. Considering the complexity in these detailed chemical kinetic models, it is important to quantify and minimize the uncertainties in the kinetic parameters. The uncertainties in the kinetic models can then be compared to uncertainties tied to experimental measurements. This approach has been frequently applied for relatively simple combustion parameters (e.g., laminar flame speed, ignition delay time), however it has not been well utilized …
Oxidation Of Hafnium Diboride—Silicon Carbide At 1500 °C In Air; Effect Of Compressive Stress, Anthony J. Degregoria, Marina B. Ruggles-Wrenn, Glen E. Pry
Oxidation Of Hafnium Diboride—Silicon Carbide At 1500 °C In Air; Effect Of Compressive Stress, Anthony J. Degregoria, Marina B. Ruggles-Wrenn, Glen E. Pry
Faculty Publications
The long-term oxidation behavior of HfB2 and of HfB2-20 vol.% SiC was studied. Test samples of each material were oxidized at 1500 °C in air using a box furnace. The exposure times were 0, 0.5, 1, 2, 3, 6, 9, 12, 15, 30, 45 and 90 h. Weight gain, oxide scale composition and oxide scale thickness were characterized for both materials. Crystal structure of the surface scales was analyzed using x-ray diffraction. Oxide scales were further characterized via scanning electron microscopy with energy dispersive spectroscopy analysis. For HfB2 the oxide scale consists predominantly of porous HfO …
Novel Investigation Of Catalytic Hydrogenation And Oxidation Of 1,3-Butadiene, Ali M. Alabedkhalil
Novel Investigation Of Catalytic Hydrogenation And Oxidation Of 1,3-Butadiene, Ali M. Alabedkhalil
Theses
The hydrogenation of 1,3 Butadiene (BD) is an important industrial process that is generally used to generate butene, which is a key feedstock to produce a variety of chemicals such as polymers, plastic, and synthetic rubber. This process involves reacting BD with hydrogen using different metallic Ni-based catalysts. In this study, Ni/Al2O3 and Ni/Nb2O5 catalysts were used and investigated to perform the hydrogenation reaction because of their commercial availability, effective hydrogenation activity, and affordability compared to Platinum Group Metal (PGM) catalysts.
The catalytic reactions were conducted using a quartz tube reactor between a temperature range …
Effect Of Cr And Ni Concentrations On Resilience Of Cast Nb-Alloyed Heat Resistant Austenitic Steels At Extreme High Temperatures, Simon N. Lekakh, Mario F. Buchely, Mei Li, Larry Godlewski
Effect Of Cr And Ni Concentrations On Resilience Of Cast Nb-Alloyed Heat Resistant Austenitic Steels At Extreme High Temperatures, Simon N. Lekakh, Mario F. Buchely, Mei Li, Larry Godlewski
Materials Science and Engineering Faculty Research & Creative Works
Austenitic Cr–Ni Alloyed Heat Resistant Steels with Nb Additions Are Used for Intensively Thermo-Mechanically Loaded Cast Components Working in Extreme High Temperature Oxidizing Environment. their Performance during Static Oxidation and Transient Thermo-Mechanical Loading Was Investigated to Recommend an Optimal Cost-Effective Cr/Ni Composition of Nb-Alloyed Austenitic Class Steels. the Static Oxidation and Transient Thermo-Mechanical Behavior of Three Austenitic Steels with Different Cr/Ni Alloying Levels Were Investigated and Compared for Variety of Working Conditions. Static Oxidation Was Performed between 900 °C and 1000 °C in Air for 400 H. the Critical Temperature Which Increases Spallation during Static Oxidation Was Determined for Each …