Engineering Commons^™

Dispersion Of Spherical Silicon Dioxide Nanoparticles In Poly(Styrene-B-Methyl Methacrylate) Diblock Copolymer Domains, Joshua C. Obinwa

Master's Theses

Polymer-nanoparticle hybrids are nanomaterials in which the unique properties of the nanosized structures can be precisely tuned by choosing an appropriate combination of the polymer and the nanoparticle. However, nanoparticle dispersion in a polymer is challenging due to the aggregation tendency of nanoparticles. To improve nanoparticle dispersion and control the location of nanoparticles in block copolymer assemblies, the nanoparticle surface is modified with surface ligands compatible with the block copolymer. In this thesis, hydroxyl-terminated poly(styrene-b-methyl methacrylate) (PS-b-PMMA) was utilized to functionalize the nanoparticle surface, covalently anchoring the hydroxylterminated end of the polymer onto the silicon dioxide nanoparticles. The silicon dioxide …

Electrochemical Detection Of Reactive Oxygen Species Via A Platinum Microelectrode Array, Victor M. Carriere Jr.

Master's Theses

Oxidative stress, an excess of endogenous or exogenous reactive oxygen species (ROS) in the body, is closely aligned with inflammatory responses. ROS such as hydrogen peroxide, superoxide, and radical hydroxyl ion serve essential functions in fighting infection, but chronic elevation of these species irreversibly damages cellular components. Given the central role of inflammation in a variety of diseases, including Alzheimer’s Disease, atherosclerosis, and rheumatoid arthritis, a low-cost, extracellular, non-invasive assay of ROS is needed.

This work reports the use of a platinum microelectrode array (Pt MEA)-based ceramic probe to detect time- and concentration-dependent variations in hydrogen peroxide (H2O2) production by …

Pretreatment Of Loblolly Pine Tree Toppings (Needled) Using Dess, Prathima Gujjula

Master's Theses

Contemporary industrial development and swift urbanization require environmentally sustainable energy sources. Ethanol made from biomass provides unique environmental and economic strategic benefits and can be considered a safe and clean liquid fuel alternative to fossil fuels. Ethanol’s significant advantages, such as low cost, biodegradability, and abundance, make the application of biomass for production of biorenewable energy favorable. However, biomass must be subjected to pretreatment processes to liberate the components needed for effective enzymatic hydrolysis that converts cellulose to sugars prior to fermentation to create biofuel. Production of valueadded co-products besides biofuels, through coordinated bio refinery processes, requires selectivity during pretreatment. …

Molecular Weight And Heating Value Of Lignin Extracted Using Deep Eutectic Solvent., Ekugbere Owen Owhe

Master's Theses

The molecular weight of lignin helps us to determine how lignin can be applied accurately in industry. The molecular weight can predict the behavior of lignin, and how it will function when combined with other materials. This thesis discusses how the molecular weight of lignin can be found with gel permeation chromatography (GPC) after acetylation with acetic anhydride and pyridine. Different lignins gave different number average molecular weight and weight average molecular weight values, which were likely due to the biomass source, type of extraction and solubility in the solvent of choice. How the structure of lignin changed after derivatization …