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Full-Text Articles in Engineering

Optimization Composition Of The Wood-Polymer Composition Based On Polyvinylchloride, Aliyev Sunnatulla, Ilkhamov Giyos, Jurayev Asror, Magrupov Farkhad Dec 2020

Optimization Composition Of The Wood-Polymer Composition Based On Polyvinylchloride, Aliyev Sunnatulla, Ilkhamov Giyos, Jurayev Asror, Magrupov Farkhad

CHEMISTRY AND CHEMICAL ENGINEERING

The objective of the reaserch is to elaboration the composition of a wood-polymer composition based on polyvinyl chloride with improved performance properties. The influence of the components of the composition - modifiers, lubricants, regulators and stabilizers - on the properties of the composition was researched. Optimization of the composition of wood-polymer composition based on PVC made it possible to obtain a material with higher strength and fire resistance.


Synthesis Of High-Strength Ceramics Based On Technogenic Waste Containing Aluminum Oxide, Shermatov Zhavokhir, Aripova Mastura, Paizyllakhanov Mukhammade-Sultankhan Dec 2020

Synthesis Of High-Strength Ceramics Based On Technogenic Waste Containing Aluminum Oxide, Shermatov Zhavokhir, Aripova Mastura, Paizyllakhanov Mukhammade-Sultankhan

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to synthesize wear-resistant and heat-resistant ceramics based on aluminum oxide. The man-made aluminum-containing waste of the Shurtan gas chemical complex was used as a source of aluminum oxide. In the work, the dependences «composition-structure», «composition-property» and «property-size of particles» were obtained, obtained by the method of heliomaterials science, namely by melting raw materials in a stream of concentrated solar radiation of high density (350 W/cm2) with subsequent quenching of the melt into water (103 deg/s). It is shown that the wear resistance and heat resistance of the material sharply increase when the content in …


High-Efficient And New Technology For Producing 5-Nitro-2-Acetylaminobenzimidazole, Saidov Sarvar, Abdurazakov Askar, Karimov Rikhsibay, Khvan Alla Dec 2020

High-Efficient And New Technology For Producing 5-Nitro-2-Acetylaminobenzimidazole, Saidov Sarvar, Abdurazakov Askar, Karimov Rikhsibay, Khvan Alla

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to create new veterinary products for agriculture based on local raw materials, to develop a highly efficient technology for their production. Waste from the production of medamine produced in the pilot production of the Institute of Plant Chemistry of the Academy of Sciences of the Republic of Uzbekistan. The process of synthesis of 5-nitro-2-acetylaminobenzimidazole was studied by one-factor experiments. The structure of the obtained product was investigated by IR, Mass, 1H, 13C NMR spectroscopy. The main factors influencing the process of obtaining 5-nitro-2-acetylaminobenzimidazole were revealed. On the basis of the obtained research results, a …


Low-Resistance Bi/Pb Ceramics Containing Ts = 295К-315k Phases Synthesized In A Solar Furnace (Parkent), Gulamova Dilbara, Gulamov Timur Dec 2020

Low-Resistance Bi/Pb Ceramics Containing Ts = 295К-315k Phases Synthesized In A Solar Furnace (Parkent), Gulamova Dilbara, Gulamov Timur

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of this work is to obtain bulk textured superconducting ceramics based on glass-crystalline precursors of the Bi1.7Pb0.3Sr2Ca(n-1)CunOy (n=5-9) series. Technologies for obtaining superconducting materials are presented. The advantages of melt methods and “Super Fast Aloys Quenching–T” technology is shown. Compositions, methods of synthesis and study of properties of precursors and ceramics obtained by solar energy are presented. The interrelation of the morphology of glass-crystalline precursors and superconducting ceramics based on them is revealed. It is shown that nano-sized nuclei are the basis on which superconducting phases with Ts = 295-315K are formed as a result of the peritectic …


Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part 2. Zn, Fe, Ni), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan Oct 2020

Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part 2. Zn, Fe, Ni), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate chelating ligands with aminobenzimidazoles carried out using quantum chemical methods. Using BIOVIA Materials Accelrys Studio 2017 software packages, the geometry, electron density distribution, and frontier orbitals calculated for the mixed ligand complexes Zn(II), Cu(II), Ni(II), Fe(III), which is necessary for understanding the electronic structure of coordination compounds with chelating ligands.


In Vitro Study Of Biodegradation Of Glass And Glass Crystals Of The R2o-Ro-Caf2-P2o5-Al2o3-Sio2 System, Aripova Mastura, Mkrtchyan Ripsime Oct 2020

In Vitro Study Of Biodegradation Of Glass And Glass Crystals Of The R2o-Ro-Caf2-P2o5-Al2o3-Sio2 System, Aripova Mastura, Mkrtchyan Ripsime

CHEMISTRY AND CHEMICAL ENGINEERING

For bioactive glasses and glass crystals, biodegradation is the most important parameter. The biodegradation process was studied for glasses and glass crystals synthesized in the R2O-RO-CaF2-P2O5-Al2O3-SiO2 system. Degradation analysis of samples was carried out on a Hitachi 902 biochemical analyzer in 0.9% NaCl, 3.8% sodium citrate solution and human serum. . The kinetics of leaching in various environments, the influence of the components of glasses and glass crystals on their biodegradation have been determined. The composition of glass that is most susceptible to degradation has been determined. IR spectroscopic analysis of glasses and crystallized glasses in vitro showed that all …


Research Of The Process Of Deformation Of Extractional Phosphoric Acid From Phosphorites Of Central Kyzylkum, Khodjamkulov Sakhomiddin, Mirzakulov Kholtura, Melikulova Gavkhar, Usmanov Ilkham Oct 2020

Research Of The Process Of Deformation Of Extractional Phosphoric Acid From Phosphorites Of Central Kyzylkum, Khodjamkulov Sakhomiddin, Mirzakulov Kholtura, Melikulova Gavkhar, Usmanov Ilkham

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this research was to determine the optimal technological parameters for the purification of extraction phosphoric acid based on phosphorites of Central Kyzylkum from fluorine by precipitation with sodium salts. The influence of the norm of sodium silicate and the total norm of sodium carbonate and sodium metasilicate salts on the chemical composition and degree of precipitation of sodium silicofluoride was research. It is shown that the optimal norm of sodium metasilicate is the stoichiometric norm for binding fluorine present in the extraction phosphoric acid to silicofluoride and the total norm of sodium salts is 120-140%, the temperature …


Modeling Of Craft Oil- Water Emulsion Under Laboratory Conditions, Arslanov Sharafutdin, Dengaev Aleksey, Getalov Andrey, Sarigin Boris Oct 2020

Modeling Of Craft Oil- Water Emulsion Under Laboratory Conditions, Arslanov Sharafutdin, Dengaev Aleksey, Getalov Andrey, Sarigin Boris

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this research is to study the possibilities of modeling oil-water emulsion in the laboratory. The study of the ratio of components and conditions of dispersion (formation) of oil-water emulsions on their stability at different settling temperatures using a laboratory model can optimize the separation of oil-water emulsions in field conditions. The possibility of modeling commercial oil and water emulsions in laboratory conditions is investigated, the average diameters of water globules in simulated oil and water emulsions at different times of their formation are determined, and the obtained average globule diameters are compared with the average diameter of …


The Possibilities Of Using Loess Clay Of Kattabog Deposit In The Production Of Ceramic Products, Ruzibaev Bahrom, Saloxidinova Salima Oct 2020

The Possibilities Of Using Loess Clay Of Kattabog Deposit In The Production Of Ceramic Products, Ruzibaev Bahrom, Saloxidinova Salima

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research was to determine the properties of loess clay in Kattabog deposit (Uzbekistan) to identify possible areas of use. Modern methods of physicochemical analysis are used: spectroscopic, x-ray phase, electron microscopic methods of analysis. The research results showed that the main phases of clay are hydromica, quartz, kaolinite, calcite and orthoclase. Based on the research, it can be stated that the clay of Kattabog deposit has good physical and technical properties and mineralogical composition, which is a valuable raw material for the production of various ceramics, bricks, tiles, majolica and other products.


Influence Of The Aluminum Oxide Additive On The Phase Composition Of Mullit-Forming Aluminosilicate Minerals, Mkrtchyan Ripsime, Aripova Mastura Oct 2020

Influence Of The Aluminum Oxide Additive On The Phase Composition Of Mullit-Forming Aluminosilicate Minerals, Mkrtchyan Ripsime, Aripova Mastura

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research is to determine the effect of alumina on the phase composition of shale of the Jerdanak deposit and the quartz-pyrophyllite rock of the Baynaksay deposit during high-temperature firing. X-ray phase analysis determined changes in the phase composition of rocks with additives from 5 to 20% aluminum oxide as a result of firing at 1300 and 1400 °C. A comparative analysis revealed the absence of cristobalite formation, a decrease in the quartz content, and an increase in the amount of mullite for shale samples. No positive effect of alumina additives on the phase composition of quartz-pyrophyllite …


Coordination Compounds Of Copper, Cobalt And Nickel Formates With Formamide And Carbamide, Jumaniyazova Mukaddas, Azizov Tohir Oct 2020

Coordination Compounds Of Copper, Cobalt And Nickel Formates With Formamide And Carbamide, Jumaniyazova Mukaddas, Azizov Tohir

CHEMISTRY AND CHEMICAL ENGINEERING

The synthesis of mixed ligand coordination compounds of copper, cobalt and nickel formates with formamide and urea in an aqueous solution was carried out. The metal content in the complexes was determined by complexometric titration. Using IR spectroscopy, it was proved that the coordination of formamide and urea with the complexing atom is carried out through the oxygen atom of the carbonyl group. The absorption spectrum of coordinated water is also present in the IR spectrum. The nature of the change in the frequency of stretching vibrations of the –OH group in the composition of water indicates its location in …


Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part I: Au, Pt, Ag), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan Oct 2020

Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part I: Au, Pt, Ag), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate chelating ligands with aminobenzimidazoles carried out using quantum chemical methods. Using BIOVIA Materials Accelrys Studio 2017 software packages, the geometry, electron density distribution, and frontier orbitals calculated for the mixed ligand complexes of Au(III), Pt(II), Ag(I), Cu(II), Ni(II), Fe(III), which are necessary for understanding the electronic structure of coordination compounds with chelating ligands.


Educational Cluster - Foundation Of The National Economy And Regional Innovation System, Usmonov Botir, Kushiev Khabibjon Oct 2020

Educational Cluster - Foundation Of The National Economy And Regional Innovation System, Usmonov Botir, Kushiev Khabibjon

CHEMISTRY AND CHEMICAL ENGINEERING

The paper analyzes the available resources for the creation of a cluster approach to the integration of education, science and industry in order to create a mechanism to bring the development of the economy to the level of modern requirements. The article describes the collaboration of science, education and industry through the clustering process. Ways to introduce clustering in the national innovation system are described. At the same time, the role of the integration of education, science and industry with the elements of the National Innovation System is analyzed. In conclusion, the role of the education cluster in the regional …


Obtaining Microcrystalline Cellulose From Melon Crops And Studying Its Structure, Umarova Vasila, Mardonov Asror, Khamdamova Dilnoza, Akmalova Guzal Oct 2020

Obtaining Microcrystalline Cellulose From Melon Crops And Studying Its Structure, Umarova Vasila, Mardonov Asror, Khamdamova Dilnoza, Akmalova Guzal

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the study was to obtain microcrystalline cellulose from gourds. Cellulose was isolated from the stems of watermelon and pumpkin by acid and alkaline heat treatment. Microcrystalline cellulose was obtained from cellulose by hydrolysis. Cellulose was hydrolyzed in a mixture of sulfuric acid and hydrogen peroxide. The optical parameters of the microcrystalline cellulose sample, ash content, bulk density, water swelling, and moisture sorption were determined. The structural features of the obtained microcrystalline cellulose were studied by IR spectroscopy. The functional groups present under various conditions for the production of microcrystalline cellulose were determined. The influence of the duration …


Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba Oct 2020

Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba

CHEMISTRY AND CHEMICAL ENGINEERING

Considering that many derivatives of bis carbamates have different biological activity, it was intuitive to produce a targeted synthesis of new derivatives of bis carbamates by the interaction of hexamethylene diisocyanate with 3,5-diode-4-hydroxybenzoic acid and 2,4,6-triiodophenol (1: 2 mol, respectively) in freshly distilled dry pyridine at 95-110 оC for 6 hours, the corresponding derivatives were obtained - methylene bis carbamates. Experimental studies have been conducted to identify the acute toxicity and radiopaque properties of the synthesized new N, -hexamethylene bis (2,6-diode-4-carboxyphenylcarbamate).


Modification Of Lithium Lubricants, Azimova Shodiyakhon, Arslanov Sharafutdin, Aripdjanov Oybek, Azimov Dilmurod Oct 2020

Modification Of Lithium Lubricants, Azimova Shodiyakhon, Arslanov Sharafutdin, Aripdjanov Oybek, Azimov Dilmurod

CHEMISTRY AND CHEMICAL ENGINEERING

The aim is to study the effect of the presence of free alkalis and acids on the properties of the complex lithium greases and the choice of the optimal dispersion medium, which provides the required physicochemical characteristics of the developed grease. The dispersed phase of lithium greases studied in the polyalphaolefin oils media. It was found that the use of a mixture of polyalphaolefin oil-4 and polyalphaolefin oil-40 as a percentage of 23/77 with a total content of 83.0% provides a relatively low effective viscosity of the lubricant at low temperatures and a relatively high tensile strength at high temperature.


Effective Oil Extraction From Bombyx Mori Silkworm Pupae And Its Structural Characteristics, Avazova Oynavod, Yugai Sveta, Rashidova Sayora Oct 2020

Effective Oil Extraction From Bombyx Mori Silkworm Pupae And Its Structural Characteristics, Avazova Oynavod, Yugai Sveta, Rashidova Sayora

CHEMISTRY AND CHEMICAL ENGINEERING

The conditions for the effective isolation of oil from the silkworm Bombyx mori pupae, based on the extraction of extracted oil with organic reagents, have been studied. The quantitative content of oil was determined in the samples. It is revealed that the oils extracted using gasoline have a high fat-wax composition compared with ethyl alcohol and hexane. When dried pupae processed with gasoline, it is possible to extract up to 16% of fatty substances as much as possible. Physical-chemical characteristics of the oil from silkworm pupae are characterized by high quality indicators. In particular, the presence of unsaturated fatty acids …


Composition Of Liquid Paraffins For Flotation Enrichment Of Potassium Chloride, Vaqqosov Sobir, Xolmuratov Shamsitdin, Buxarov Shuhrat, Kodirov Orifjon Oct 2020

Composition Of Liquid Paraffins For Flotation Enrichment Of Potassium Chloride, Vaqqosov Sobir, Xolmuratov Shamsitdin, Buxarov Shuhrat, Kodirov Orifjon

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this work is to determine the source of liquid paraffins from secondary products of the local chemical industry, compare the performance properties and use the resulting products as apolar co-reagents in silvinite flotation. The experiments were conducted with secondary used hexane and pyrocondensation. To improve the efficiency of flotation, the dependences of the order of reagent’s supply into the process and the time of action were studied. Experiments have shown that when adding tetradecane and pentadecane in an amount of 2.5 to 7.5% to hexane liquid paraffins, it is possible to reduce the tail of KCl to …


Influence Of Technological Parameters On The Chemical Composition Of Calcium Polyphosphates From Phosphorites Central Kyzylkum, Ulugberdieva Ziyada, Khujamberdiev Sherzod, Mirzakulov Kholtura, Usmanov Ilkham Oct 2020

Influence Of Technological Parameters On The Chemical Composition Of Calcium Polyphosphates From Phosphorites Central Kyzylkum, Ulugberdieva Ziyada, Khujamberdiev Sherzod, Mirzakulov Kholtura, Usmanov Ilkham

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research was to study the effect of temperature, the ratio of P2O5EPA:P2O5PRM and the duration of calcination on the content of various forms of P2O5 in calcium polyphosphate. The effect of calcination temperature from 150 to 300 °C, the ratio of P2O5EPA:P2O5FRM from 2,15 to 4,50 and the duration of the process from 20 to 120 minutes on the changes in various forms of P2O5 were studied. It was shown that with increasing temperature to 200-250 °C the content of the total (ortho + poly) assimilable form of Р2О5 increases and then decreases, passing through a …


Bases Of Development Of Technologies Of Synthesis Of Oxide Materials In Big Solar Furnace (Parkent), Gulamova Dilbara, Baxronov Khayot, Bobokhulov Sirojiddin, Eshonkulov Elyor Oct 2020

Bases Of Development Of Technologies Of Synthesis Of Oxide Materials In Big Solar Furnace (Parkent), Gulamova Dilbara, Baxronov Khayot, Bobokhulov Sirojiddin, Eshonkulov Elyor

CHEMISTRY AND CHEMICAL ENGINEERING

The advantages of synthesis of complex oxide compounds by solar energy, the possibility of obtaining highly textured nano materials are shown. The development of heliomaterial science, aimed at the synthesis of new materials, is inextricably linked with the use of effective optical energy systems. On the example of obtaining superconducting materials of nominal composition Bi1.7Pb0.3Sr2Ca(n-1)CunOy (n = 3-20), optimization of the parameters of the optical-energy system of the Big Solar Furnace (Parkent) is shown. The ideology of developing heliotechnology for the synthesis of inorganic materials in a solar furnace is presented. The properties of a superconducting material of nominal Bi1.7Pb0.3Sr2Ca(n1)CunOy …


Research Of The Process Of Deformation Of Extractional Phosphoric Acid From Phosphorites Of Central Kyzylkum, Khodjamkulov Sakhomiddin, Mirzakulov Kholtura, Melikulova Gavkhar, Usmanov Ilkham Jun 2020

Research Of The Process Of Deformation Of Extractional Phosphoric Acid From Phosphorites Of Central Kyzylkum, Khodjamkulov Sakhomiddin, Mirzakulov Kholtura, Melikulova Gavkhar, Usmanov Ilkham

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this research was to determine the optimal technological parameters for the purification of extraction phosphoric acid based on phosphorites of Central Kyzylkum from fluorine by precipitation with sodium salts. The influence of the norm of sodium silicate and the total norm of sodium carbonate and sodium metasilicate salts on the chemical composition and degree of precipitation of sodium silicofluoride was research. It is shown that the optimal norm of sodium metasilicate is the stoichiometric norm for binding fluorine present in the extraction phosphoric acid to silicofluoride and the total norm of sodium salts is 120-140%, the temperature …


Modeling Of Craft Oil- Water Emulsion Under Laboratory Conditions, Arslanov Sharafutdin, Dengaev Aleksey, Getalov Andrey, Sarigin Boris Jun 2020

Modeling Of Craft Oil- Water Emulsion Under Laboratory Conditions, Arslanov Sharafutdin, Dengaev Aleksey, Getalov Andrey, Sarigin Boris

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this research is to study the possibilities of modeling oil-water emulsion in the laboratory. The study of the ratio of components and conditions of dispersion (formation) of oil-water emulsions on their stability at different settling temperatures using a laboratory model can optimize the separation of oil-water emulsions in field conditions. The possibility of modeling commercial oil and water emulsions in laboratory conditions is investigated, the average diameters of water globules in simulated oil and water emulsions at different times of their formation are determined, and the obtained average globule diameters are compared with the average diameter of …


The Possibilities Of Using Loess Clay Of Kattabog Deposit In The Production Of Ceramic Products, Ruzibaev Bahrom, Saloxidinova Salima Jun 2020

The Possibilities Of Using Loess Clay Of Kattabog Deposit In The Production Of Ceramic Products, Ruzibaev Bahrom, Saloxidinova Salima

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research was to determine the properties of loess clay in Kattabog deposit (Uzbekistan) to identify possible areas of use. Modern methods of physicochemical analysis are used: spectroscopic, x-ray phase, electron microscopic methods of analysis. The research results showed that the main phases of clay are hydromica, quartz, kaolinite, calcite and orthoclase. Based on the research, it can be stated that the clay of Kattabog deposit has good physical and technical properties and mineralogical composition, which is a valuable raw material for the production of various ceramics, bricks, tiles, majolica and other products.


Influence Of The Aluminum Oxide Additive On The Phase Composition Of Mullit-Forming Aluminosilicate Minerals, Mkrtchyan Ripsime, Aripova Mastura Jun 2020

Influence Of The Aluminum Oxide Additive On The Phase Composition Of Mullit-Forming Aluminosilicate Minerals, Mkrtchyan Ripsime, Aripova Mastura

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the research is to determine the effect of alumina on the phase composition of shale of the Jerdanak deposit and the quartz-pyrophyllite rock of the Baynaksay deposit during high-temperature firing. X-ray phase analysis determined changes in the phase composition of rocks with additives from 5 to 20% aluminum oxide as a result of firing at 1300 and 1400 °C. A comparative analysis revealed the absence of cristobalite formation, a decrease in the quartz content, and an increase in the amount of mullite for shale samples. No positive effect of alumina additives on the phase composition of quartz-pyrophyllite …


Coordination Compounds Of Copper, Cobalt And Nickel Formates With Formamide And Carbamide, Jumaniyazova Mukaddas, Azizov Tohir Jun 2020

Coordination Compounds Of Copper, Cobalt And Nickel Formates With Formamide And Carbamide, Jumaniyazova Mukaddas, Azizov Tohir

CHEMISTRY AND CHEMICAL ENGINEERING

The synthesis of mixed ligand coordination compounds of copper, cobalt and nickel formates with formamide and urea in an aqueous solution was carried out. The metal content in the complexes was determined by complexometric titration. Using IR spectroscopy, it was proved that the coordination of formamide and urea with the complexing atom is carried out through the oxygen atom of the carbonyl group. The absorption spectrum of coordinated water is also present in the IR spectrum. The nature of the change in the frequency of stretching vibrations of the –OH group in the composition of water indicates its location in …


Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part I: Au, Pt, Ag), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan Jun 2020

Configuration And Competitive Reactivity Of Ligands In Mixed Ligand Complexes Of Dialkylditiophosphates And Aminobenbenzimidazole (Part I: Au, Pt, Ag), Esbergenova Botakoz, Daminova Shakhlo, Kadirova Zuhra, Sharipov Khasan

CHEMISTRY AND CHEMICAL ENGINEERING

With the aim of determination of electronic and geometrical structures of mixed-ligand complexes, theoretical modeling of the structures of coordination compounds of transition metals with dialkyldithiophosphate chelating ligands with aminobenzimidazoles carried out using quantum chemical methods. Using BIOVIA Materials Accelrys Studio 2017 software packages, the geometry, electron density distribution, and frontier orbitals calculated for the mixed ligand complexes of Au(III), Pt(II), Ag(I), Cu(II), Ni(II), Fe(III), which are necessary for understanding the electronic structure of coordination compounds with chelating ligands.


Educational Cluster - Foundation Of The National Economy And Regional Innovation System, Usmonov Botir, Kushiev Khabibjon Jun 2020

Educational Cluster - Foundation Of The National Economy And Regional Innovation System, Usmonov Botir, Kushiev Khabibjon

CHEMISTRY AND CHEMICAL ENGINEERING

The paper analyzes the available resources for the creation of a cluster approach to the integration of education, science and industry in order to create a mechanism to bring the development of the economy to the level of modern requirements. The article describes the collaboration of science, education and industry through the clustering process. Ways to introduce clustering in the national innovation system are described. At the same time, the role of the integration of education, science and industry with the elements of the National Innovation System is analyzed. In conclusion, the role of the education cluster in the regional …


Obtaining Microcrystalline Cellulose From Melon Crops And Studying Its Structure, Umarova Vasila, Mardonov Asror, Khamdamova Dilnoza, Akmalova Guzal Jun 2020

Obtaining Microcrystalline Cellulose From Melon Crops And Studying Its Structure, Umarova Vasila, Mardonov Asror, Khamdamova Dilnoza, Akmalova Guzal

CHEMISTRY AND CHEMICAL ENGINEERING

The aim of the study was to obtain microcrystalline cellulose from gourds. Cellulose was isolated from the stems of watermelon and pumpkin by acid and alkaline heat treatment. Microcrystalline cellulose was obtained from cellulose by hydrolysis. Cellulose was hydrolyzed in a mixture of sulfuric acid and hydrogen peroxide. The optical parameters of the microcrystalline cellulose sample, ash content, bulk density, water swelling, and moisture sorption were determined. The structural features of the obtained microcrystalline cellulose were studied by IR spectroscopy. The functional groups present under various conditions for the production of microcrystalline cellulose were determined. The influence of the duration …


Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba Jun 2020

Radiopaque Activity Of Iodine Containing Methylene-Bis-Carbamate, Baltabaev Ubaydulla, Djuraev Abdukahhor, Abduvakilov Jahongir, Abdullaeva Matluba

CHEMISTRY AND CHEMICAL ENGINEERING

Considering that many derivatives of bis carbamates have different biological activity, it was intuitive to produce a targeted synthesis of new derivatives of bis carbamates by the interaction of hexamethylene diisocyanate with 3,5-diode-4-hydroxybenzoic acid and 2,4,6-triiodophenol (1: 2 mol, respectively) in freshly distilled dry pyridine at 95-110 оC for 6 hours, the corresponding derivatives were obtained - methylene bis carbamates. Experimental studies have been conducted to identify the acute toxicity and radiopaque properties of the synthesized new N, -hexamethylene bis (2,6-diode-4-carboxyphenylcarbamate).


Modification Of Lithium Lubricants, Azimova Shodiyakhon, Arslanov Sharafutdin, Aripdjanov Oybek, Azimov Dilmurod Jun 2020

Modification Of Lithium Lubricants, Azimova Shodiyakhon, Arslanov Sharafutdin, Aripdjanov Oybek, Azimov Dilmurod

CHEMISTRY AND CHEMICAL ENGINEERING

The aim is to study the effect of the presence of free alkalis and acids on the properties of the complex lithium greases and the choice of the optimal dispersion medium, which provides the required physicochemical characteristics of the developed grease. The dispersed phase of lithium greases studied in the polyalphaolefin oils media. It was found that the use of a mixture of polyalphaolefin oil-4 and polyalphaolefin oil-40 as a percentage of 23/77 with a total content of 83.0% provides a relatively low effective viscosity of the lubricant at low temperatures and a relatively high tensile strength at high temperature.