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Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

2019

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University of Texas at El Paso

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Pressureless Sintering Of Zirconium Diboride Obtained By Combustion Synthesis, Gabriel Llausas Jan 2019

Pressureless Sintering Of Zirconium Diboride Obtained By Combustion Synthesis, Gabriel Llausas

Open Access Theses & Dissertations

Magnetohydrodynamic (MHD) direct power generation has the potential to significantly increase the thermal efficiency of coal fired power plants. Materials for MHD electrodes should have high melting points, high electrical and thermal conductivities, and excellent thermal shock and corrosion resistance. Zirconium diboride (ZrB2), which belongs to the class of ultra-high temperature ceramics (UHTC), is a promising material for this application. Mechanically activated self-propagating high-temperature synThesis (MASHS) is an attractive method for its fabrication. Previous studies have shown that zirconium diboride can be fabricated from inexpensive oxides of zirconium and boron (ZrO2 and B2O3) using magnesium as a reducing agent and …