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Engineering Commons

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2019

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Chemical Engineering

Technological University Dublin

Photoreactive organic

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Development And Characterisation Of High Surface Energy Microstructured Sol-Gel Coatings For Sensing Applications, Emma Machugh Nov 2019

Development And Characterisation Of High Surface Energy Microstructured Sol-Gel Coatings For Sensing Applications, Emma Machugh

Doctoral

This study investigates the development of high surface energy photoreactive organic inorganic hybrid sol-gel coatings for the microstructuration of high-resolution microfluidic platforms and optofluidic biosensor platforms by standard photolithography processes. To achieve this, the first step of our work consisted of identifying the fundamental physico chemical processes governing the structuration and surface properties of hybrid organic inorganic sol-gel coatings. For this purpose, a reference material based on the combination of an organosilane (3-Methacryloxypropytrimethoxysilane, MAPTMS) and a transition metal (zirconium propoxide, ZPO), was firstly developed and characterised. It was highlighted that chemical, physical and combined physical and chemical processes can be …