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2019

University of Massachusetts Amherst

Polymer and Organic Materials

Capillary Force Induced Wrinkling

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Capillary Wrinkling And Mechanical Properties: Single Layers, Bilayers, And Composites, Jooyoung Chang Oct 2019

Capillary Wrinkling And Mechanical Properties: Single Layers, Bilayers, And Composites, Jooyoung Chang

Doctoral Dissertations

In this dissertation, we aim to understand the mechanical properties of thin films and classes of wrinkle patterns of polymer films using capillary wrinkling. We discuss four independent research subjects. In the first project, we measure the thickness (t) dependence of Young’s modulus (E) of polymer thin films. Thin films were measured from bulk thicknesses down to thickness less than the radius of gyration (6 nm). E does not show any systematic change with t, although an increase in modulus was found for the thinnest poly(styrene) (PS) film. The second topic is stretching (Y) and bending (B) moduli of PS/poly(methyl …