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Point Defects In Lithium Gallate And Gallium Oxide, Christopher A. Lenyk

Theses and Dissertations

Electron paramagnetic resonance (EPR), Fourier-Transform Infrared spectroscopy (FTIR), photoluminescence (PL), thermoluminescence (TL), and wavelength-dependent TL are used to identify and characterize point defects in lithium gallate and β-gallium oxide doped with Mg and Fe acceptor impurities single crystals. EPR investigations of LiGaO₂ identify fundamental intrinsic cation defects lithium (V⁻_Li) and gallium (V²⁻_Ga) vacancies. The defects’ principle g values are found through angular dependence studies and atomic-scale models for these new defects are proposed. Thermoluminescence measurements estimate the activation energy of lithium vacancies at Ea = 1.05 eV and gallium vacancies at Ea > 2 …