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Bacteriophage Inactivation As A Function Of Ferrous Iron Oxidation, Joe Heffron, Brad Mcdermid, Brooke K. Mayer
Bacteriophage Inactivation As A Function Of Ferrous Iron Oxidation, Joe Heffron, Brad Mcdermid, Brooke K. Mayer
Civil and Environmental Engineering Faculty Research and Publications
Iron-based disinfection has been promoted as a potential low-cost, low-byproduct means of virus mitigation. This research is the first to establish that virus inactivation due to ferrous iron is impacted both by the extent of iron oxidation (from ferrous to ferric iron) and the rate of iron oxidation. Log inactivation of bacteriophages increased linearly with ferrous iron concentration at low doses (< 3 mg/L Fe), but higher doses limited disinfection, likely due to floc formation. The rate of iron oxidation was controlled by independently varying pH and dissolved oxygen concentration. Bacteriophage inactivation increased with the inverse of ferrous oxidation rate, suggesting that slower iron oxidation rates allow better contact between viruses and reactive ferrous iron. Ferrous iron showed potential for disinfection in conditions of low pH and dissolved oxygen, though these conditions preclude effective iron coagulation/flocculation.
Analysis Of Operational Parameters, Reactor Kinetics, And Floc Characterization For The Removal Of Estrogens Via Electrocoagulation, Emily K. Maher, Kassidy N. O'Malley, Joe Heffron, Jingwan Huo, Brooke K. Mayer, Yin Wang, Patrick J. Mcnamara
Analysis Of Operational Parameters, Reactor Kinetics, And Floc Characterization For The Removal Of Estrogens Via Electrocoagulation, Emily K. Maher, Kassidy N. O'Malley, Joe Heffron, Jingwan Huo, Brooke K. Mayer, Yin Wang, Patrick J. Mcnamara
Civil and Environmental Engineering Faculty Research and Publications
Estrogenic compounds can cause human and ecological health issues and have been detected in surface and drinking water. In this research a reactor analysis determined the impact of operational parameters, the best fit kinetic model for the removal of estrone (E1), 17β-estradiol (E2), estriol (E3), and 17α-ethynylestradiol (EE2) using a bench-top iron electrocoagulation reactor, and characterized the floc generated in-situ. The parameters investigated were current density, conductivity, stir rate, and polarity reversal. Estrogen removal correlated well with an increase in current density, while conductivity did not impact removal but did reduce potentials. High stir rates and frequent polarity reversal …