Engineering Commons^™

Degradation Of 3-Nitro-1, 2, 4-Trizole-5-One (Nto) In Wastewater With Uv/H2o2 Oxidation, Amalia Terracciano, Christos Christodoulatos, Agamemnon Koutsospyros, Zhaoyu Zheng, Tsan-Liang Su, Benjamin Smolinski, Per Arienti, Xiaoguang Meng

Civil Engineering Faculty Publications

Insensitive Munition (IM) formulations contain 3-nitro-1,2,4-trizole-5-one (NTO), an energetic compound with the highest aqueous solubility (16 g L⁻¹) among all IM explosives, including 2,4-dinitroanisole (DNAN) and 1-nitroguanidine (NQ); as a result wastewater streams from IM processing facilities can be highly contaminated and potentially toxic. The removal of energetic compounds from wastewater streams prior to their discharge in the environment is imperative, and new technology must be developed to efficiently treat high levels of NTO and other IM compounds in these streams. In this study, the treatment of NTO wastewater by a UV/H₂O₂ oxidation process under …

No2- And No3- Enhance Cold Atmospheric Plasma Induced Cancer Cell Death By Generation Of Onoo-, Dehui Xu, Qingjie Cui, Yujing Xu, Zhijie Liu, Zeyu Chen, Wenjie Xia, Hao Zhang, Dingxin Liu, Hailan Chen, Michael G. Kong

Bioelectrics Publications

Cold atmospheric plasma (CAP) is a rapidly developed technology that has been widely applied in biomedicine especially in cancer treatment. Due to the generation of various active species in plasma, CAP could induce various tumor cells death and showed a promising potential in cancer therapy. To enhance the biological effects of gas plasma, changing the discharging parameters is the most commonly used method, yet increasing discharging power will lead to a higher possibility of simultaneously damage surrounding tissues. In this study, by adding nontoxic concentration of additional nitrite and nitrate in the medium, we found that anti-tumor effect of CAP …

Mechanically Assisted Electrochemical Degradation Of Alumina-Tic Composites, Hetal Umesh Maharaja, Guigen Zhang

Publications

Alumina-TiC composite material is a tough ceramic composite with excellent hardness, wear resistance and oxidation resistance in dry and high-temperature conditions. In aqueous conditions, however, it is likely to be electrochemically active facilitating charge transfer processes due to the conductive nature of TiC. For application as an orthopedic biomaterial, it is crucial to assess the electrochemical behavior of this composite, especially under a combined mechanical and electrochemical environment. In this study, we examined the mechanically assisted electrochemical performance of alumina-TiC composite in an aqueous environment. The spontaneous electrochemical response to brushing abrasion was measured. Changes in the magnitude of electrochemical …

Thermal And Mechanical Response Of Inner Cone Sample Of Zrb₂-Sic Ceramic Under Arc-Jet Conditions, Jun Wei, Lokeswarappa R. Dharani, K. Chandrashekhara

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Under arc-jet test conditions, ZrB₂-SiC ceramic will undergo high temperature oxidation and develop an external glassy layer (SiO₂), zirconia sub-layer (ZrO₂) and SiC-depleted diboride layer (ZrB₂). This study relates to finite element modeling of the effects of oxidation on heat transfer and mechanical behavior of ZrB₂-SiC ceramic under arc-jet test conditions. A steady-state heat transfer FE method was employed to conduct the heat transfer analysis to obtain the temperature distribution in the inner body of the cone. The surface thermal conditions available in the literature were used in the heat …

Numerical Study Of Oxidation In Stainless Steel Alloy Ep-823 By Liquid Lead-Bismuth Eutectic, Rajyalakshmi Palaparty

UNLV Theses, Dissertations, Professional Papers, and Capstones

The oxidation of stainless steel is influenced by the presence of oxygen in the surrounding medium; the oxygen reacts with the alloy to form an oxide. In certain environments, such as nuclear reactor coolant systems, minimal oxidation of the stainless steel containment functions as a protective shield from corrosive coolants such as liquid lead-bismuth eutectic.

In the current study, this minimal oxidation is evaluated for a system in which corrosion-resistant stainless steel alloy EP-823 is subject to an environment of flowing oxygenated liquid lead-bismuth eutectic at a temperature of 743 K, whereby the thickness of the forming oxide layer is …

Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 1000°C In Air And In Silicic Acid-Saturated Steam, Brian G. Kroeger

Theses and Dissertations

Advanced SiC/SiC ceramic matrix composites (CMCs) are being considered for a variety of applications. Of interest is their ability to withstand exposure to high temperature in an aggressive oxidizing environment. The presence of steam creates such an environment. As steam traverses across a SiC/SiC composite and through cracks in the SiC matrix, it becomes saturated with silicic acid, Si(OH)₄. It is essential to understand the long-term impacts and durability of SiC/SiC CMCs that have been exposed to such a demanding environment. The present research investigated creep of Hi-Nicalon™ S SiC fibers at 1000°C in air and in silicic …

Evaluation And Prevention Of Spontaneous Combustion During Handling And Storage Of Coal, Amir E. Najarzadeh

Theses and Dissertations--Mining Engineering

Spontaneous combustion of coal has historically been a major problem for the coal industry, predominantly during storage and transportation. Various methods have been used in the laboratory for evaluating the propensity of different coal sources to self-heat. However, the heterogeneity of coal and the complexity of the system has resulted in inconsistencies and sometimes conflicting results as indicated by the findings reported in several publications.

The primary objective of the current study was to build a laboratory scale apparatus that simulates the condition of a coal stockpile to evaluate the events leading to spontaneous combustion and develop potential remedies. As …