Engineering Commons^™

Effects Of So2 In Air On Performance Of Direct Methanol Fuel Cell, Bin Qin, Fen-Ning Jing, Xue-Jing Sun, Gong-Quan Sun, Hai Sun

Journal of Electrochemistry

Direct methanol fuel cells (DMFC) generally use oxygen as an oxidant. Contaminants such as sulfides and nitrides in the air can affect the performance of the DMFC. In this work, the effects of SO₂ on the performance of DMFC were investigated and the mechanism of poisoning was analyzed, by means of constant current discharge curve, polarization performance curve, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). In the CV scan, the permeated methanol was oxidized at a low potential to eliminate its effect on the SO₂ poisoning behavior test. The results showed that the SO₂ poisoning resulted …

Graphene Oxides In Water: Characterization, Reactivity, And Application, Siyuan An

McKelvey School of Engineering Theses & Dissertations

Recently discovered, graphene and graphene oxide materials have drawn considerable research attention due to outstanding and novel properties, which underpin wide material potential for a number of advanced applications including supercapacitors, solar cells, sensors, catalysts, semiconductors, sorbents, and membranes, among others. Graphene oxides (GO), which are considered as a family of oxidized graphene materials (derivatives), is a key precursor to the synthesis of free-standing graphene via oxidation-exfoliation-reduction pathways. GO properties depend on the synthesis routes/conditions (i.e. derivatization), including partially maintaining graphene (i.e. sp2) properties. Further, oxygen-containing functionalities (epoxy, hydroxyl, carbonyl, and carboxyl groups) render GO hydrophilic – and correspondingly stability …

A Comprehensive Study Of Arsenic Removal From Aqueous Solution Using Low-Cost Adsorbents, Mrinmoyee Mondal

Electronic Thesis and Dissertation Repository

Arsenic poisoning in water is a global concern for many years due to its high carcinogenic and toxic effect on the human body. Adsorption is one of the promising technology to treat arsenic-contaminant water. Recently, natural adsorbent modified with metal oxide/hydroxide is being studied widely, because of its great removal efficiency, inexpensive and eco-friendly properties.

In the present study, two low-cost adsorbents namely Aerocrete and Vermiculite (modified with iron oxy-hydroxide) were assessed for arsenic (both As(III) and As(V)) removal. The maximum removal of As(V) was ~99% at pH 6 for both adsorbents (3g/L). Optimum removal of As(III) was observed at …

Activated Carbon Fixed-Bed Adsorber Design For Treating Chromium Hexavalent Wastewater, Tedi Hudaya, Velicia Rachmat

Makara Journal of Technology

Pollution caused by industrial wastewater containing heavy metals is a major issue, primarily due to its toxic nature. A cheap yet effective method to deal with such wastewater is activated carbon adsorption. The purpose of this research is to evaluate and design a fixed bed adsorber with granular activated carbon as an adsorbent to process wastewater-containing chromium hexavalent (Cr 6+). Experiments show that the Langmuir isotherm fits the equilibrium data as effectively as the Freundlich isotherm. Activated carbon used in this research is Jacobi 2000® derived from bituminous coal. The lab scale inlet volumetric flow is 100 mL/h with different …

Graphene-Based Materials Coated On Zeolite For The Removal Of Persistent Organic Pollutants From Water, Yan Zhang

Theses and Dissertations

Adsorption is a fast, low-cost and the most commonly implemented water treatment technology for the removal of multiple contaminations from ground water, drinking water or wastewater. Difficulties in removing persistent organic pollutants (POPs) to improve quality and safety of treated water sources require the exploration of novel and multifunctional materials. Graphene-based materials having unique structures, high specific surface areas and tailorable functional groups are promising candidates as adsorbents.

The main goal of this work is to fabricate a novel adsorbent made of GO/rGO attached on natural zeolite substrates for the removal of variably charged organic model compounds and POPs in …

Growth And Behaviors Of Inn/Gan Multiple Quantum Wells By Plasma-Assisted Molecular Beam Epitaxy, Chen Li

Graduate Theses and Dissertations

Fully realizing the potential of InGaN semiconductors requires high quality materials with arbitrary In-content. To this date the growth of In-rich InGaN films is still challenging since it suffers from the low growth temperatures and many detrimental alloying problems. InN/GaN multiple quantum wells (MQWs) and super lattices (SLs) are expected to be promising alternatives to random InGaN alloys since in principle they can achieve the equivalent band gap of InGaN random alloys with arbitrarily high In-content and at the same time bypass many growth difficulties.

This dissertation focuses on studying the growth mechanisms, structural properties and energy structures of InN/GaN …

Removal Of Carbamazepine From Drinking Water, Adam Johnson, Thomas Krumpolc, Jordan Gadberry, Juan Rodriguez, Paolo Marrero-Rivera, Zachary Wiese

Chemical Engineering Undergraduate Honors Theses

Due to the increasing prevalence of prescription medication over the past few

decades, pharmaceuticals have accumulated in various water sources. This has become a

public health concern because many pharmaceuticals have limited research on the effects

of chronic low-level exposure. According to the World’s Health Organization (WHO),

traces of pharmaceuticals products have been reported in different water sources such as

surface waters, wastewater, groundwater, and drinking water.[1] One pharmaceutical of

interest that has been detected in water sources is carbamazepine. Carbamazepine is a

common pharmaceutical prescribed for the treatment of seizure disorders, neuropathic

pain, and various psychological disorders. It’s mechanism …

Thallium Removal From Drinking Water Using Pyrolusite Filter Media, Erin R. Andersen

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Thallium (Tl) is a rare heavy metal in drinking water, but its extreme toxicity makes its removal crucial to consumer health. Traditional treatment methods do not work for Tl in sources with high concentrations of ions like calcium (Ca⁺²) and potassium (K⁺), as they are removed preferentially to Tl. A treatment method that specifically targets Tl must be applied. Pilot studies conducted in Park City Utah found that pyrolusite, a manganese oxide ore, will remove Tl to very low concentrations in the presence of competing ions but because this method is not common, further study was …

Novel Engineered Porous Materials For The Removal Of Lead From Water, Mohsen Hajipour Hajipour Manjili

Theses and Dissertations

The estimated average blood lead level for the population younger than 5 years in the United States is approximately 100 times higher than ancient background levels, indicating that substantial sources of lead exposure exist in the environment. This research is focused on the removal of lead from water with a functionalized zeolite. Functionalization improves adsorption behavior to achieve adsorbent materials with high capacity and stability with potential multiple re-uses.

The lead sorption from water onto an Australian zeolitic mineral (clinoptilolite) unmodified and modified with sulfide-based reagents is investigated with batch and fixed bed column experiments. The effect of solution pH, …

Ion Exchange For Nutrient Recovery Coupled With Biosolids-Derived Biochar Pretreatment To Remove Micropollutants, Yiran Tong, Lee K. Kimbell, Anna Avila, Patrick J. Mcnamara, Brooke K. Mayer

Civil and Environmental Engineering Faculty Research and Publications

Wastewater, especially anaerobic treatment effluent, contains high ammonia nitrogen (NH₄-N) and inorganic orthophosphate (PO₄-P), which necessitate additional treatment to meet stringent discharge regulations. Ion exchange regeneration is a process that can be adopted for not only removing but also recovering nutrients. However, recovering nutrients by ion exchange from nutrient-rich effluents that also contain micropollutants (which typically pass through anaerobic treatment as well) may result in subsequent problems, since micropollutants could end up in ion exchange effluent, regenerant, or recovered fertilizer products. Micropollutant removal by a nonselective adsorbent, such as biosolids-derived biochar, before nutrient recovery processes would …

Surface Chemistry And Modelling Of Salicyl Hydroxamic Acid Adsorption At The Surface Of Rare Earth Oxides, Carbonates And Phosphates, Marc F. Sime

Graduate Theses & Non-Theses

The adsorption mechanism of salicyl hydroxamic acid (SHA, C7H7O3N) on rare earth minerals was investigated using two complementary methods: precipitation studies and modelling. Precipitation studies showed that SHA adsorption occurs through a displacement of the hydroxide ion at the surface in an ion exchange mechanism, leading to surface precipitation and/or chemisorption. Surface precipitation predominates in the light rare earth oxides (LREOs), while chemisorption predominates in the heavier REOs. Modelling revealed that adsorption of SHA on the REM surface is dependent upon the orientation of SHA on the surface as well as the distance between rare earth elements sites on the …

Comparison Of Salicyl Hydroxamate Adsorption On Rare Earth Phosphates To Oxides And Carbonates, Stephanie Trant

Graduate Theses & Non-Theses

Adsorption behavior of the anionic collector salicyl hydroxamic acid (SHA) on a group of selected rare earth phosphates (REPs) was studied by means of experimental methods and modeling software. These REPs were then compared to rare earth carbonates (RECs) and rare earth oxides (REOs) to develop a trend. A suite of rare earth elements (REE) were studied that included light (LREE) and middle (MREE). Results for heavy (HREE) were inferred. Synthetic phosphate, oxide and carbonate powders of the rare earth elements Lanthanum (La), Cerium (Ce), Europium (Eu) and Dysprosium (Dy) were tested for these studies. Dysprosium phosphate was the only …

Continuous Flow Process For Recovery Of Metal Contaminants From Industrial Wastewaters With Magnetic Nanocomposites, David Hutchins

Graduate Theses & Non-Theses

Remediation of metal-containing industrial effluents presents both a technical challenge and an economic opportunity. Many industrial waste streams contain low levels of metal ions requiring treatment prior to discharge. Existing treatment technologies are frustrated by disparate compositions and low metal concentrations. Chemical precipitation is effective; however, it requires excessive reagents and discourages selective recovery. Ion-exchange enables recovery, but requires a batch process with extensive operational and maintenance demands, and is rarely implemented in large-scale applications. A continuous flow process capable of selective recovery would present many advantages over existing technologies.

This research examines and develops a continuous flow process for …

Biosolids-Derived Biochar For Triclosan Removal From Wastewater, Lee K. Kimbell, Yiran Tong, Brooke K. Mayer, Patrick J. Mcnamara

Civil and Environmental Engineering Faculty Research and Publications

Micropollutants, including antibiotics, hormones, pharmaceuticals, and personal care products, are discharged into the environment with liquid and solid effluent streams from water resource recovery facilities (WRRFs). The objective of this research was to determine whether biosolids-derived biochar (BS-biochar) could be used as a sorbent in continuous flow-through columns to remove micropollutants as a polishing step for wastewater treatment. Triclosan (TCS) was selected as a representative micropollutant due to frequent detection in liquid effluents, residual biosolids, and surface waters. Bench-scale column experiments were conducted to determine the effect of flow rate and competition due to the presence of other organic micropollutants …

Removal Of Carbamazepine From Drinking Water, Zachary Wiese

Chemical Engineering Undergraduate Honors Theses

Due to the increasing prevalence of prescription medication over the past few

decades, pharmaceuticals have accumulated in various water sources. This has become a

public health concern because many pharmaceuticals have limited research on the effects

of chronic low-level exposure. According to the World’s Health Organization (WHO),

traces of pharmaceuticals products have been reported in different water sources such as

surface waters, wastewater, groundwater, and drinking water.[1] One pharmaceutical of

interest that has been detected in water sources is carbamazepine. Carbamazepine is a

common pharmaceutical prescribed for the treatment of seizure disorders, neuropathic

pain, and various psychological disorders. It’s mechanism …

Removal Of Carbamazepine From Drinking Water, Paola Marrero-Rivera, Adam Johnson, Jordan Alex Gadberry, Juan Rodriguez, Thomas Krumpolc, Zach Wiese

Chemical Engineering Undergraduate Honors Theses

Due to the increasing prevalence of prescription medication over the past few decades, pharmaceuticals have accumulated in various water sources. This has become a public health concern because many pharmaceuticals have limited research on the effects of chronic low-level exposure.One pharmaceutical of interest that has been detected in water sources is carbamazepine. Carbamazepine (CBZ) is a common pharmaceutical prescribed for the treatment of seizure disorders, neuropathic pain, and various psychological disorders. It’s mechanism of action is “sodium channel blocking,” which is the impairment of conduction of sodium ions in sodium channels. This, in effect, reduces nervous-system conductivity in key areas …

Receiving Import-Substituting Adsorbents On The Basis Of Charcoal, R.A Paygamov, D.J Jumayeva, Sh.A Kuldasheva, I.D Eshmetov

Chemical Technology, Control and Management

In this article, the issues of obtaining import-substituting carbonaceous adsorbents based on wood for cleaning oil-processing industrial wastewater from oil products are considered. The experiments obtaining adsorbents, out at different temperatures and times were carried. It was shown that new, highly adsorptive carbonaceous adsorbents based on wood were obtained by pyrolysis with thermal activation at the optimum temperature (350-400° C during 90 minutes). Physical and chemical properties of adsorbents and the dependence of the porosity of coal on the pyrolysis temperature and the degree of grinding is studied.

Color Removal From Combined Dye And Fruit Nectar Wastewater Using Adsorption And Microfiltration, Oluwatobiloba A. Akinwande

ETD Archive

Pollution of the waterways is a great challenge of the 21st century. Textile effluents contain compounds which have the capacity to cause more harm when ingested. There are many dye removal technologies like coagulation, photo oxidation which help to remove color from dye wastewater. The use of adsorption to remove color from dye wastewater has been used for many centuries. Activated carbon can efficiently remove color from dye wastewater but it is very expensive and so different researches have been conducted to get the adsorption capacity of different forms of adsorbents. These adsorbents can be gotten from agricultural waste, biomass, …

Color Removal And Treatment Of Dye And Sugar Waste Water Using Low Cost Adsorbents, Saisantosh Vamshi Harsha Madiraju

ETD Archive

This study was undertaken to determine the treatment of wastewater from dye and sugar industry for removal of color. This specific treatment consists of adsorption using low cost adsorbents and micro filtration using whatman-41 micro filters. Considerations of this treatment process is to take the samples using batch adsorption and avoid coagulation with further dilution. Numerous runs were made with the ideal waste samples prepared in the laboratory. As a first step in the study different dyes were considered using different concentrations of sugar wastewater. Samples were treated with three different low-cost adsorbents. These treated samples using low cost adsorbents …

Color Removal Of Dye And Milk Wastewater Using Peanut Hull By The Process Of Adsorption, Venkatesh Kummarakuntla

ETD Archive

Dairy industry is one of the major industries from which organic wastewater is produced and released into the water bodies. Textile industries also generate considerable amount of dye wastewater that effect the water quality standards. Various treatment techniques are adopted to treat the wastewater. Adsorption is one of the low-cost treatment processes to treat the textile and milk wastewater. This thesis focuses on the treatment of combined dye and milk wastewater using the process of adsorption. The treatment process is carried out by using three different types of low cost adsorbents Peanut-hull, Banana peel and Activated carbon. The effectiveness of …

Treatment Of Dye Wastewater Using Dehydrated Peanut Hull, Nikitha Shamirpet

ETD Archive

The release of dye waste water into environment causes harm to aquatic life when they reach drains or other water sources. They pollute the soil and causes change in cycles of plant and animal life through bio-accumulation and nutrient cycle. Dyes which form residue or precipitate causes mutations or changes in the DNA of living organisms in and around the area of release of the dye into atmosphere. In this thesis, several runs were attempted to treat the synthetically prepared dye waste water using dehydrated peanut hull. The initial dye waste water samples were all collected and checked for absorbance, …

Effect Of History On The Binary Adsorption Equilibria Of Aluminium Terephthalate (Mil-53(Al)), Ufuoma Israel Kara

ETD Archive

Metal organic frameworks (MOFs) are highly porous solids with potential applications in a wide range of fields including gas separations and catalysis. Most of porous solids used in these applications such as zeolites and activated carbon usually have rigid structures. In contrast, a number of metal-organic frameworks (MOFs) exhibit structural transformation in response to external stimuli. Such materials show promise for applications such as sensors, actuators and adsorptive separations. Several thermodynamic formalisms were proposed in literature to explain this phenomenon, often known as gate-opening or “breathing” of the MOF material. In this study, the adsorptive behavior of MIL-53(Al), a MOF …

Adsorption And Microfiltration Processes To Treat Dye And Coffee Wastewater., Abhiram Siva Prasad Pamula

ETD Archive

Wastewater from coffee processing industry creates high biological and chemical oxygen demand in the surface water. In addition to coffee wastewater from coffee industry, dyes from textile industry enter surface water affecting water quality in terms of transmissivity of light. Adsorption is an economical wastewater treatment process to remove color from dye and coffee wastewater. In the current thesis, adsorption using low-cost adsorbents like peanut hull and onion peel are used to treat combined dye and coffee wastewater. Three representative dyes including acid black 48, disperse yellow 3, crystal violet certified with processed coffee is used in preparing batch adsorption …

Study Of Gas Production From Shale Reservoirs With Multi-Stage Hydraulic Fracturing Horizontal Well Considering Multiple Transport Mechanisms, Chaohua Guo, Mingzhen Wei, Hong Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Development of unconventional shale gas reservoirs (SGRs) has been boosted by the advancements in two key technologies: horizontal drilling and multi-stage hydraulic fracturing. A large number of multi-stage fractured horizontal wells (MsFHW) have been drilled to enhance reservoir production performance. Gas flow in SGRs is a multi-mechanism process, including: desorption, diffusion, and non-Darcy flow. The productivity of the SGRs with MsFHW is influenced by both reservoir conditions and hydraulic fracture properties. However, rare simulation work has been conducted for multi-stage hydraulic fractured SGRs. Most of them use well testing methods, which have too many unrealistic simplifications and assumptions. Also, no …

Characteristics Of Activated Carbons Produced From Herbaceous Biomass Feedstock, Oluwatosin Jerry Oginni

Graduate Theses, Dissertations, and Problem Reports

Energy security and environmental protection are at the forefront of research due to the forecasted depletion of fossil fuel reserves and the growing concern of its adverse environmental impacts. The use of renewable sources for energy applications has centered on the use of biomass feedstocks and this include from herbaceous, woody, agricultural waste, forest residues and municipal wastes. The thermochemical conversion (pyrolysis) of these biomass feedstocks has potential to produce liquid fuel, a solid residue (biochar) and non-condensable gas. The biochar is primarily composed of renewable porous carbon and other inorganic compounds. The biochar is used for soil amendment, adsorption …

Quantum Many - Body Interaction Effects In Two - Dimensional Materials, Sanghita Sengupta

Graduate College Dissertations and Theses

In this talk, I will discuss three problems related to the novel physics of two-dimensional quantum materials such as graphene, group-VI dichalcogenides family (TMDCs viz. MoS2 , WS2, MoSe2 , etc) and Silicene-Germanene class of materials.

The first problem poses a simple question - how do the quantum excitations in a graphene membrane affect adsorption? Using the tools of diagrammatic perturbation theory, I will derive the scattering rates of a neutral atom on a graphene membrane. I will show how this seemingly naive model can serve as a non-relativistic condensed matter analogue of the infamous infrared problem in Quantum Electrodynamics. …

Experimental Evaluation Of Uranyl Transport Into Mesoporous Silica Gel Using Fluorescence, Brandon M. Dodd

Theses and Dissertations

This research investigated parameters that can affect the use of nanoporous silica gel as a media for accumulating a detectable amount of uranium. The unique fluorescence of the Uranyl (UO₂²⁺) ion was used to evaluate the transport kinetics and accumulation within silica gel in a static fluid and under pressure driven flow. The addition of fluid flow decreased the time constant from on the order of an hour to approximately 2s with a very low fluid velocity of 0.36cm/s. The 0.36cm/s fluid velocity was found to be the critical velocity above which there was no gain in …

Synthesis And Comprehensive Studies Of Nanogels For Enhanced Oil Recovery, Jiaming Geng

Doctoral Dissertations

“Nanomaterials have been developed and applied for enhanced oil recovery (EOR) in oil industry. Among the developed nanomaterials, nano-sized crosslinked polymeric gel particles (nanogels) have shown the potential in improving both the macro- and micro-displacing efficiency. This dissertation focuses on the synthesis and the potential EOR mechanisms of nanogels. Nanogels with positive, negative, and neutral charges were synthesized through suspension polymerization. The morphology, size distribution, and zeta potential of nanogels were elucidated by corresponding technologies, such as scanning electron microscopy and dynamic light scattering. The ability of nanogels in oil-water interfacial tension (IFT) reduction and oil-in-water (o/w) emulsion stabilization was …

Atomic Layer Deposition Prepared Nanostructured Materials For Various Catalytic Reactions, Xiaofeng Wang

Doctoral Dissertations

"Atomic layer deposition (ALD) has been widely used for thin film coating and metal nanoparticles (NPs) preparation. In this report, the applications of ALD prepared nanostructured materials in catalysis were examined.

Highly dispersed Pt monometallic catalysts with different substrates and multi-walled carbon nanotubes (MWCNTs) supported Pt-Co bimetallic catalysts were synthesized by ALD for selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols (UA). Pt/MWCNTs showed the highest selectivity of UA in selective hydrogenation of citral, as compared to Pt/SiO₂, Pt/ALD-Al₂O₃, and Pt/γ-Al₂O₃. After adding Co, the highest selectivity was achieved …