Engineering Commons^™

Measuring The Double Layer Capacitance Of Electrolyte Solutions Using A Graphene Field Effect Transistor, Agatha Ulibarri

Senior Theses

When operating graphene field effect transistors (GFETs) in fluid, a double layer capacitance (C_dl) is formed at the surface. In the literature, the C_dl is estimated using values obtained using metal electrode experiments. Due to the distinctive electronic and surface properties of graphene, there is reason to believe these estimates are inadequate. This work seeks to directly characterize the double layer capacitance of a GFET. A unique method for determining the C_dl has been implemented, and data has been obtained for three electrolytes and one ionic fluid. The results yield dramatically lower C_dl values than …

The Incorporation Of Graphene To Lithium Cobalt Oxide As A Cathode To Improve The Performance Of Lithium Ion Batteries, Kenan Wang

Graduate Theses and Dissertations

One of the objectives of this thesis work was to investigate the cathode performance of lithium cobalt oxide (LiCoO2) incorporated with graphene powder in lithium ion batteries (LIBs). Graphene powder was incorporated into cathode materials to enhance the performance of LIBs. The other objective was to impede the construction of a solid electrolyte interphase (SEI) sheet using graphene sheet coating on its cathode.

The results of this work show that adding graphene powder improved the performance of LiCoO¬2 as a cathode material. With the incorporation of different weight percentages of graphene powder, the LiBs showed distinct changes in their charging …

Polymer Nanocomposites Containing High Aspect Ratio Particulates: Innovation In Co-Extruded Multilayer Barrier Films, Kevin Meyers

Dissertations

Delaminated montmorillonite (MMT) clay/ maleic anhydride grafted LLDPE nanocomposite multilayer films with alternating layers of LDPE were produced through multilayer co-extrusion. The MMT concentration within the nanocomposite layers was increased through annealing the films in the melt due to a mismatch in interdiffusion rates of the polymer layers. Analysis of the nanocomposite layers upon annealing revealed that the platelets impinged upon one another resulting in significant improvement in oxygen barrier in the multilayer system, exceeding the results of bulk nanocomposites.

Model analysis demonstrated that increasing the nanoplatelet aspect ratio or initial concentration in the filled layers would lead to even …

Photo-Induced Charge Transport In Graphene And Semiconducting Wse2 Integrated With Zero-Dimensional Materials For Enhancing Optoelectronic Device Characteristics, Srishti Chugh

Open Access Theses & Dissertations

Two-dimensional (2D) materials encompass a diverse array of properties from the metallic-like character of graphene to the semiconducting nature of many of the transition metal dichalcogenides (TMDCs) such as tungsten diselenide (WSe2). These materials exhibit intriguing interactions with incoming radiation which makes them interesting for electronics and optoelectronics, especially given the high electron mobility and the ballistic nature of the electronic transport under certain conditions. In particular, the semiconducting TMDCs, such as WSe2, express an indirect-to-direct optical transition with scaling from the bulk to monolayers. Despite the enhanced optical absorption characteristics of monolayer WSe2 stemming from its direct band gap, …

Surfactant Driven Assembly Of Freeze-Casted, Polymer-Derived Ceramic Nanoparticles On Grapehene Oxide Sheets For Lithium-Ion Battery Anodes, Ali Zein Khater

Honors Undergraduate Theses

Traditional Lithium-Ion Batteries (LIBs) are a reliable and cost-efficient choice for energy storage. LIBs offer high energy density and low self-discharge. Recent developments in electric-based technologies push for replacing historically used Lead-Acid batteries with LIBs. However, LIBs do not yet meet the demands of modern technology. Silicon and graphene oxide (GO) have been identified as promising replacements to improve anode materials. Graphene oxide has a unique sheet-like structure that provides a mechanically stable, light weight material for LIB anodes. Due to its structure, reduced graphene oxide (rGO) is efficiently conductive and resistive to environmental changes. On the other hand, silicon-based …