Engineering Commons^™

Controls On Phosphorus Export From An Agricultural Watershed: Amsden Brook, Fort Fairfield, Maine Usa., Gregory J. Mcdonald

Electronic Theses and Dissertations

This study explores the sources and mechanisms of phosphorus (P) mobilization during base flow within the Amsden Brook watershed, Fort Fairfield, Maine, USA. Amsden Brook is an agriculturally dominated watershed drained by a spring-fed and perennial first- to second-order stream. We characterized the P concentrations within the watershed to investigate connections between soils, stream sediment, surface water, and groundwater. Waters were monitored monthly during the 2017 snow-free period for temperature, pH, dissolved oxygen, conductivity, soluble reactive P (SRP), total P, strong acid anions, strong base cations, dissolved organic carbon (DOC), Al, Fe, and Mn. Phosphorus speciation within soils and sediment …

Application Of Silicon Nanohair Textured P-N Junctions In A Photovoltaic Device, Michael Small

Electronic Theses and Dissertations

The goal of this project is to design and develop a fabrication process for a silicon photovoltaic device which incorporates a nanohair textured p-n junction. The silicon nanowires are etched into a silicon wafer, comprising an epitaxial p-layer on n-substrate, via metal-assisted chemical etching (MACE). The resulting nanowires contain p-n junctions that lie along the length of the vertical nanowires. This construct has the potential to increase the optical bandwidth of a silicon photovoltaic device by allowing a greater amount of short wavelength light to reach the junction. In addition, the MACE method of nanofabrication has the potential for decreasing …

Three-Dimensional Bedrock Channel Evolution With Smoothed Particle Hydrodynamics, Nick Richmond

Electronic Theses and Dissertations

Bedrock channels are responsible for balancing and communicating tectonic and climatic signals across landscapes, but it is difficult and dangerous to observe and measure the flows responsible for removing weakly-attached blocks of bedrock from the channel boundary. Consequently, quantitative descriptions of the dynamics of bedrock removal are scarce. Detailed numerical simulation of violent flows in three dimensions has been historically challenging due to technological limitations, but advances in computational fluid dynamics aided by high-performance computing have made it practical to generate approximate solutions to the governing equations of fluid dynamics. From these numerical solutions we gain detailed knowledge of the …

A Transfer Learning Approach For Sentiment Classification., Omar Abdelwahab

Electronic Theses and Dissertations

The idea of developing machine learning systems or Artificial Intelligence agents that would learn from different tasks and be able to accumulate that knowledge with time so that it functions successfully on a new task that it has not seen before is an idea and a research area that is still being explored. In this work, we will lay out an algorithm that allows a machine learning system or an AI agent to learn from k different domains then uses some or no data from the new task for the system to perform strongly on that new task. In order …

Mechanistic Studies Of Reducible Metal Oxides As Hydrodeoxygenation Catalysts, Akbar Mahdavi Shakib

Electronic Theses and Dissertations

Hydrodeoxygenation of phenol to benzene using ruthenium supported titania catalysts strongly varies depending on the support crystal structure and preparation conditions. Here, we performed spectroscopic characterization of titania supports to identify the surface impurities common to commercial and synthesized titania samples using a variety of spectroscopic methods. Sulfate impurities were detected for the commercial anatase samples and a procedure for their elimination was proposed so that inactive catalysts gained reactivity. Surface hydroxyls of different TiO2 samples (anatase, rutile, and pyrogenic) were identified using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments performed on vigorously cleaned surfaces and a facet-specific assignment …

The Hilbert-Huang Transform: A Theoretical Framework And Applications To Leak Identification In Pressurized Space Modules, Kenneth R. Bundy

Electronic Theses and Dissertations

Any manned space mission must provide breathable air to its crew. For this reason, air leaks in spacecraft pose a danger to the mission and any astronauts on board. The purpose of this work is twofold: the first is to address the issue of air pressure loss from leaks in spacecraft. Air leaks present a danger to spacecraft crew, and so a method of finding air leaks when they occur is needed. Most leak detection systems localize the leak in some way. Instead, we address the identification of air leaks in a pressurized space module, we aim to determine the …

Comparison Of A Modified And Traditional Rapid Infiltration Basin For Treatment And Control Of Nutrients In Wastewater Effluent, Jessica Cormier

Electronic Theses and Dissertations

Rapid infiltration basins (RIB) have been historically used in Florida for groundwater recharge, effluent disposal, or a combination of both. However, this technique has proven ineffective in providing nitrogen control unless the RIB is modified in some manner. In this study, a traditional RIB was compared to a modified RIB constructed with manufactured biosorption activated media (BAM) to evaluate nitrate removal from reclaimed water. The RIBs are used for reclaimed and excess storm water disposal. Few, if any, studies have been published where BAM-modified RIBs have been used for this purpose. In this work, a mixture of clay, tire crumb, …

Room Temperature Operation Of Quantum Cascade Lasers Monolithically Integrated Onto A Lattice-Mismatched Substrate, Rowel Go

Electronic Theses and Dissertations

Quantum Cascade Lasers (QCLs) are semiconductor devices that, currently, have been observed to emit radiation from ~ 2.6 μm to 250 μm (1 to 100 terahertz range of frequencies.) They have established themselves as the laser of choice for spectroscopic gas sensing in the mid-wavelength infrared (3-8 μm) and long-wavelength infrared (8-15 μm) region. In the 4-12 μm wavelength region, the highest performing QCL devices, in terms of wall-plug efficiency and continuous wave operation, are indium phosphide (InP) based. The ultimate goal is to incorporate this InP-based QCL technology to silicon (Si) substrate since most opto-electronics are Si-based. The main …

Developing Optimization Techniques For Logistical Tendering Using Reverse Combinatorial Auctions, Jennifer Kiser

Electronic Theses and Dissertations

In business-to-business logistical sourcing events, companies regularly use a bidding process known as tendering in the procurement of transportation services from third-party providers. Usually in the form of an auction involving a single buyer and one or more sellers, the buyer must make decisions regarding with which suppliers to partner and how to distribute the transportation lanes and volume among its suppliers; this is equivalent to solving the optimization problem commonly referred to as the Winner Determination Problem. In order to take into account the complexities inherent to the procurement problem, such as considering a supplier’s network, economies of scope, …

High Dynamic Range Optical Devices And Applications., Elijah Robert Jensen

Electronic Theses and Dissertations

Much of what we know about fundamental physical law and the universe derives from observations and measurements using optical methods. The passive use of the electromagnetic spectrum can be the best way of studying physical phenomenon in general with minimal disturbance of the system in the process. While for many applications ambient visible light is sufficient, light outside of the visible range may convey more information. The signals of interest are also often a small fraction of the background, and their changes occur on time scales so quickly that they are visually imperceptible. This thesis reports techniques and technologies developed …

Evaluation Of Drug-Loaded Gold Nanoparticle Cytotoxicity As A Function Of Tumor Tissue Heterogeneity., Hunter Allan Miller

Electronic Theses and Dissertations

The inherent heterogeneity of tumor tissue presents a major challenge to nanoparticle-medicated drug delivery. This heterogeneity spans from the molecular to the cellular (cell types) and to the tissue (vasculature, extra-cellular matrix) scales. Here we employ computational modeling to evaluate therapeutic response as a function of vascular-induced tumor tissue heterogeneity. Using data with three-layered gold nanoparticles loaded with cisplatin, nanotherapy is simulated with different levels of tissue heterogeneity, and the treatment response is measured in terms of tumor regression. The results show that tumor vascular density non-trivially influences the nanoparticle uptake and washout, and the associated tissue response. The drug …

Developing A Risk Assessment Protocol To Quantify Distribution And Uptake Of Persistent Organic Pollutants In Glacial Outflows, Kimberley Rain Miner

Electronic Theses and Dissertations

Pollutants released by industrialized nations between 1960 and 2004 have been transported northward through atmospheric processes and deposited into glaciated alpine ecosystems. Many of these chemicals retain their original structure and are absorbed into the biota thousands of miles away from where they were originally utilized. With a warming climate increasing the melt of alpine glaciers, these glaciers may be introducing growing amounts of toxins into the watershed. While studies have demonstrated the existence of resident pollutants within glaciated ecosystems, no one has developed a risk assessment to identify sources and quantity of risk posed by these compounds when released …

Re-Evaluating Performance Measurement: New Mathematical Methods To Address Common Performance Measurement Challenges, Jordan David Benis

Electronic Theses and Dissertations

Performance Measurement is an essential discipline for any business. Robust and reliable performance metrics for people, processes, and technologies enable a business to identify and address deficiencies to improve performance and profitability. The complexity of modern operating environments presents real challenges to developing equitable and accurate performance metrics. This thesis explores and develops two new methods to address common challenges encountered in businesses across the world. The first method addresses the challenge of estimating the relative complexity of various tasks by utilizing the Pearson Correlation Coefficient to identify potentially over weighted and under weighted tasks. The second method addresses the …

Microwave Acoustic Saw Resonators For Stable High-Temperature Harsh-Environment Static And Dynamic Strain Sensing Applications, Anin K. Maskay

Electronic Theses and Dissertations

High-temperature, harsh-environment static and dynamic strain sensors are needed for industrial process monitoring and control, fault detection, structural health monitoring in power plant environments, steel and refractory material manufacturing, aerospace, and defense applications. Sensor operation in the aforementioned extreme environments require robust devices capable of sustaining the targeted high temperatures, while maintaining a stable sensor response. Current technologies face challenges regarding device or system size, complexity, operational temperature, or stability.

Surface acoustic wave (SAW) sensor technology using high temperature capable piezoelectric substrates and thin film technology has favorable properties such as robustness; miniature size; capability of mass production; reduced installation …

Multi Self-Adapting Particle Swarm Optimization Algorithm (Msapso)., Gerhard Koch

Electronic Theses and Dissertations

The performance and stability of the Particle Swarm Optimization algorithm depends on parameters that are typically tuned manually or adapted based on knowledge from empirical parameter studies. Such parameter selection is ineffectual when faced with a broad range of problem types, which often hinders the adoption of PSO to real world problems. This dissertation develops a dynamic self-optimization approach for the respective parameters (inertia weight, social and cognition). The effects of self-adaption for the optimal balance between superior performance (convergence) and the robustness (divergence) of the algorithm with regard to both simple and complex benchmark functions is investigated. This work …

Surface Reaction And Diffusion Kinetics In Semiconducting Metal Oxide Film Gas Sensors, Aravind Reghu

Electronic Theses and Dissertations

Chemiresistive metal oxide gas sensors based on materials such as SnO₂, ZnO, and TiO₂, have been investigated extensively by many researchers for a wide range of applications. The band bending model, based on the surface chemistry of highly reactive ionosorbed species (O₂^- or O^-) and the semiconducting material properties of SnO₂, TiO₂ and ZnO, adequately predicts the dependence of the change in sensor conductivity (Δσ) as a function of target gas pressure and temperature. However, the band bending model is not applicable to gas sensors based on reducible oxides …

Longitudinal Tracking Of Physiological State With Electromyographic Signals., Robert Warren Stallard

Electronic Theses and Dissertations

Electrophysiological measurements have been used in recent history to classify instantaneous physiological configurations, e.g., hand gestures. This work investigates the feasibility of working with changes in physiological configurations over time (i.e., longitudinally) using a variety of algorithms from the machine learning domain. We demonstrate a high degree of classification accuracy for a binary classification problem derived from electromyography measurements before and after a 35-day bedrest. The problem difficulty is increased with a more dynamic experiment testing for changes in astronaut sensorimotor performance by taking electromyography and force plate measurements before, during, and after a jump from a small platform. A …

Network Science Algorithms For Mobile Networks., Heba Mohamed Elgazzar

Electronic Theses and Dissertations

Network Science is one of the important and emerging fields in computer science and engineering that focuses on the study and analysis of different types of networks. The goal of this dissertation is to design and develop network science algorithms that can be used to study and analyze mobile networks. This can provide essential information and knowledge that can help mobile networks service providers to enhance the quality of the mobile services. We focus in this dissertation on the design and analysis of different network science techniques that can be used to analyze the dynamics of mobile networks. These techniques …

Development Of A Tabletop Coherent Soft X-Ray Source, Hanfu Kong

Electronic Theses and Dissertations

The goal of this thesis is to design a tabletop coherent soft X-ray source for attosecond high resolution imaging. We collect signals from gas cells with different length and lens with different focal length. A spectrometer with a grating and a CCD camera is applied to observe and measure the spectrum of the X-ray attosecond pulses. This thesis first introduces the theory background of ultrafast lasers, then mainly explains high harmonic generation, which is the key method for attosecond pulses generation, subsequently presents the experiment system and analyzes the results from the experiment, also compares different combinations of parameters of …

Non-Hermitian Optics, Absar Ulhassan

Electronic Theses and Dissertations

From the viewpoint of quantum mechanics, a system must always be Hermitian since all its corresponding eigenvalues must be real. In contrast, the eigenvalues of open systems-unrestrained because of either decay or amplification-can be in general complex. Not so long ago, a certain class of non-Hermitian Hamiltonians was discovered that could have a completely real eigenvalue spectrum. This special class of Hamiltonians was found to respect the property of commutation with the parity-time (PT) operator. Translated into optics, this implies a balance between regions exhibiting gain and loss. Traditionally, loss has been perceived as a foe in optics and something …

Power Scaling Of High Power Solid State Lasers., Bumjin Oh

Electronic Theses and Dissertations

The solid-state laser is one of the most widely used lasers in scientific research and industrial applications. This thesis describes detailed investigations of two modern architectures of high power cw solid-state lasers, a 20 W diode-pumped Yb:YAG thin disc laser and 300 W diode-pumped Nd:YAG rod laser. With the thin disc laser architecture, the signal beam must fit to the pump area on the disc defined by the multi-pass diode pump configuration. The beam propagation, beam diameter, phase and thermal effects for various cavity configurations are investigated theoretically and experimentally. In addition, the internal loss, small signal gain, and thermal …

Fiber Optimization For Operation Beyond Transverse Mode Instability Limitations, Joshua Bradford

Electronic Theses and Dissertations

Transverse Mode Instabilities (TMIs) stand as a fundamental limitation to power and brightness scaling in laser systems based upon optical fiber technologies. This work comprises experimental and theoretical investigations into fiber laser design that should minimize the effects of Stimulated Thermal Rayleigh Scattering. Theoretical discussions and simulations focus on how fiber parameters affect transverse mode coupling. These include core geometry optimization, pump geometry optimization, in addition to the effects of HOM content and losses on the TMI threshold. Experimentally, a high-power laser facility is commissioned with beam quality diagnostics to quantify the thresholds of the onset of modal interferences and …

Generation And Characterization Of Isolated Attosecond Pulse In The Soft X-Ray Regime, Jie Li

Electronic Theses and Dissertations

The observation of any atomic and molecular dynamics requires a probe that has a timescale comparable to the dynamics itself. Ever since the invention of laser, the temporal duration of the laser pulse has been incrementally reduced from several nanoseconds to just attoseconds. Picosecond and femtosecond laser pulses have been widely used to study molecular rotation and vibration. In 2001, the first single isolated attosecond pulse (1 attosecond = 10^-18 seconds.) was demonstrated. Since this breakthrough, "attoscience" has become a hot topic in ultrafast physics. Attosecond pulses typically have span between EUV to X-ray photon energies and sub-femtosecond pulse duration. …

2 Micron Fiber Lasers: Power Scaling Concepts And Limitations, Alex Sincore

Electronic Theses and Dissertations

Thulium- and holmium-doped fiber lasers (TDF and HDF) emitting at 2 micron offer unique benefits and applications compared to common ytterbium-doped 1 micron lasers. This dissertation details the concepts, limitations, design, and performance of four 2 micron fiber laser systems. While these lasers were developed for various end-uses, they also provide further insight into two major power scaling limitations. The first limitation is optical nonlinearities: specifically stimulated Brillouin scattering (SBS) and modulation instability (MI). The second limitation is thermal failure due to inefficient pump conversion. First, a 21.5 W single-frequency, single-mode laser with adjustable output from continuous-wave to nanosecond pulses …

Single Mode Wavelength-Tunable Thulium Fiber, Dong Jin Shin

Electronic Theses and Dissertations

Thulium fiber lasers have the broadest emission wavelength bandwidth out of any rare-earth doped fiber lasers. The emission wavelength starts from 1.75μm and ends at around 2.15μm, covering a vast swath of the eye safe wavelength region and intersecting with a large portion of mid-infrared atmospheric transmission window. Also, thulium fiber lasers provide the highest average output power of any other rare-earth doped fiber lasers in these wavelength regimes, making them uniquely suited for applications such as remote sensing. At the moment, high power beam propagation of continuous wave laser through the atmosphere in the mid-infrared range is yet to …

Cavity-Coupled Plasmonic Systems For Enhanced Light-Matter Interactions, Abraham Vazquez-Guardado

Electronic Theses and Dissertations

Light-matter interaction is a pivotal effect that involves the synergetic interplay of electromag- netic fields with fundamental particles. In this regard localized surface plasmons (LSP) arise from coherent interaction of the electromagnetic field with the collective oscillation of free electrons in confined sub-wavelength environments. Their most attractive properties are strong field en- hancements at the near field, highly inhomogeneous, peculiar temporal and spatial distributions and unique polarization properties. LSP systems also offer a unique playground for fundamental electromagnetic physics where micro-scale systemic properties can be studied in the macro-scale. These important properties and opportunities are brought up in this work …

Application Of Drainage Water Management And Saturated Buffers For Conservation Drainage In South Dakota, Abhinav Sharma

Electronic Theses and Dissertations

Edge of field practices such as drainage water management (DWM) and saturated buffers can reduce nutrient transport from croplands to surface waterbodies. DWM uses stackable weir boards in a control structure to manipulate the water table depth throughout the cropping season and reduce the amount of nutrient rich water draining out from the field. Saturated buffers, on the other hand, use a control structure to divert water draining out from the cropland to a vegetative strip via a subsurface tile installed parallel to a waterway. For the saturated buffer systems, a combination of natural denitrification, nitrogen mineralization, and plant uptake …

A Development Of Travel Time Equation For Overland Flow As Affected By Vegetation, Naga Vara Prasad Ganti

Electronic Theses and Dissertations

In overland flow water research, travel time is a significant parameter used in estimating peak discharge in channels or rivers. Overland flow is assumed to be in turbulent condition to estimate travel time using Manning’s Velocity Equation (MVE). When the flow is in a laminar condition, Grismer’s Laminar Mean Velocity Equation (GLMVE) is applied but fails to consider the roughness parameter. A review of the literature shows numerous equations for overland travel time, but there is no known equation that determines the mean velocity of overland flow under laminar condition with a roughness coefficient or other coefficient related to the …

Comparison Of Historical Precipitation For Aberdeen, Ipswich, And Eureka, South Dakota, Uday Singh Kshatriya

Electronic Theses and Dissertations

The availability of water resources varies from time to time with the climate conditions. Keeping track of climate conditions would eventually benefit for the future predictions. The objective of this research was to compare and contrast the climate especially for Aberdeen, Ipswich and Eureka, South Dakota utilizing the historical monthly precipitation records and to develop the techniques that are reliable to estimate the missing data. For these necessary statistical analyses were performed using the monthly precipitation data from High Plains Regional Climate Center (HPRCC) for the annual and 8-Year periods for Aberdeen, Ipswich and Eureka, South Dakota. 63 water years …

Evaluating E. Coli Particle Attachment And The Impact On Transport During High Flows, Louis Amegbletor

Electronic Theses and Dissertations

Fecal indicator bacteria, including E. coli, are the leading cause of water quality impairments within assessed waters in the United States. The source of E. coli includes WWTP, leaking sewers, animal manure, wildlife, livestock, and stream bed sediment. Storm events contribute to bacteria loading within waters through wash-in of land sources of bacteria and resuspension of bacteria within sediments. Bacteria introduced into the water column are either attached to particles or are unattached (or free-living). The goal of this study was to examine the attachment of E. coli to different particle sizes, including their impact on contributing to water …