Engineering Commons^™

Adsorption Of Cu(Ii) Ions In Aqueous Solution Onto Limonia Acidissima Shellbased Activated Carbon: Kinetic And Isotherm Studies, Abrar Muslim, Syahiddin Dahlan Said, Gita Suci Hariati, Siti Fajar Karina, Fauzi Muhammad Djuned, Rizka Mulyawan

Makara Journal of Technology

Adsorption of Cu(II) ions from aqueous solution using activated carbon prepared from Limonia acidissima fruit shell (LAFS-AC) was conducted in batch mode experiments at pH 5 (±0.15), 100 rpm and 1 atm. The effects of contact time, initial Cu(II) ions concentration, KOH concentration, and adsorption temperature on Cu(II) ions adsorption capacity were investigated. Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy analyses were performed to investigate the active site and surface morphology of the LAFS-AC, respectively. The Cu(II) ions adsorption was fitted very well (R2 = 0.94 on average) to the pseudo second-order adsorption kinetic with the adsorption capacity and …

How To Produce A Potential High Value Bio-Char From The Worst Invasive Plant In Canada, Chiara Barbiero, Franco Berruti, Cedric Briens

Biochar: Production, Characterization and Applications

Phragmites Australis is a perennial plant, native to Eurasia, which is spreading worldwide, increasing fire hazards, and causing damage to wildlife and its surrounding habitat. Phragmites is classified as Canada’s worst invasive plant due to the difficulty of achieving its full eradication. Phragmites plants are fast growing and can spread quickly through seeds or rhizomes. They must be processed locally to destroy seeds and rhizomes. For these reasons, mobile pyrolysis was selected as a destruction method that provides valuable bio-char. The aim of this work is to study the effect of different pre-treatment and post-treatment strategies on bio-char characteristics, such …

Production Of Activated Carbon From Barley Biochar Precursor, Javier Pallarés, Ana González-Cencerrado, Inmaculada Ramos

Biochar: Production, Characterization and Applications

Agricultural production must be directed towards "sustainable agriculture", which preserves natural resources, reduces GHG emissions and maintains biodiversity. In this context, biochar is considered a product of great interest in agriculture since several studies have demonstrated its effectiveness in increasing agricultural yields, increasing the water retention capacity and nutrients in the soil, increasing the development of arbuscular mycorrhizal fungus (AMF), and ultimately improving the efficiency of fertilizers, thus reducing their use and reducing enviromental pollution.

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Regeneration Potential Of Activated Petroleum Coke For Application In Oil Sands Process-Affected Water, Sreejon Das

Electronic Thesis and Dissertation Repository

Cost effective regeneration of spent adsorbent is crucial for large scale application of adsorption as a viable separation process. While adsorption studies are abundant in literature, systematic and comprehensive regeneration studies are seldom reported in open literature. A proprietary activated carbon from petroleum coke was used for the removal of model naphthenic acids (NAs) and organic compounds from oil sands process-affected water (OSPW). A systematic and comprehensive study was conducted to regenerate the adsorbents. Methanol with aqueous NaOH (pH adjusted to around 12) was applied to regenerate the spent commercially available granular activated carbon (GAC) and activated petroleum-coke (APC). Optimization …

Influence Of Activated Carbon Surface Oxygen Functionality On Elemental Mercury Adsorption From Aqueous Solution, Emily K. Faulconer, David W. Mazyck

Publications

Mercury (Hg), though naturally occurring, is a toxic element. Exposure to various forms of mercury can be harmful for humans and ecosystems. Mercury-contaminated wastewater can be treated using activated carbon to adsorb the mercury, allowing for safe discharge. Wet chemical oxidation of activated carbon was performed to enhanced surface oxygen functionality, with the objective of enhancing aqueous ionic (Hg(II)) and elemental (Hg(0)) mercury adsorption. Characterization of the modified carbons included nitrogen adsorption-desorption, elemental analysis, point of zero charge, and total acidity titration. The concentration and identity of the modifying reagent influenced the characteristics of the carbons, including the surface oxygen …

Life Cycle Environmental And Economic Performance Of Biochar Compared With Activated Carbon: A Meta-Analysis, Hashim A. Alhashimi, Can B. Aktas

Civil Engineering Faculty Publications

As the commercial production and distribution of biochar continues to grow internationally, and its applications diversifying from its early uses as soil amendment, it is important to study the environmental impacts and economic performance of biochar in comparison to activated carbon in order to assess its value. The goal of the study was to assess, through a meta-analysis, the environmental and economic performance of biochar in comparison to activated carbon under an equivalent functional unit to adsorb heavy metals. More than 80 data points on adsorption capacity of biochar and activated carbon were identified through literature, which were statistically analyzed …

Activated Carbon Preparation And Modification For Adsorption, Yuhe Cao

Electronic Theses and Dissertations

Butanol is considered a promising, infrastructure-compatible biofuel. Butanol has a higher energy content than ethanol and can be used in conventional gas engines without modifications. Unfortunately, the fermentation pathway for butanol production is restricted by its toxicity to the microbial strains used in the process. Butanol is toxic to the microbes, and this can slow fermentation rates and reduce butanol yields. Gas stripping technology can efficiently remove butanol from the fermentation broth as it is produced, thereby decreasing its inhibitory effects. Traditional butanol separation heavily depends on the energy intensive distillation method. One of the main issues in acetone-butanol-ethanol fermentation …