Open Access. Powered by Scholars. Published by Universities.®

Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 2 of 2

Full-Text Articles in Engineering

The Development Of Cesium Calcium Bromo-Iodide Scintillator For X-Ray And Gamma Ray Detection, Matthew Starr Loyd Dec 2017

The Development Of Cesium Calcium Bromo-Iodide Scintillator For X-Ray And Gamma Ray Detection, Matthew Starr Loyd

Masters Theses

CsCaI3:Eu [cesium calcium iodide doped with europium] is a promising scintillator material that can be grown from the melt, but undergoes a tetragonal to orthorhombic phase transition upon cooling at 255 °C [degrees Celsius], causing twinning and cloudiness. The purpose of this work is to suppress this solid to solid phase transition in the CsCaI3:Eu scintillator, which has a light yield of ~40000 ph/Mev and energy resolution at 662keV of ~4%, by halide replacement to form the compound CsCaBrxI3-x:Eu [cesium calcium bromo-iodide doped with europium]. Crystals 8 cm3 [cubic centimeters] in …


Surface Energy In Bond-Counting Models On Bravais And Non-Bravais Lattices, Tim Ryan Krumwiede May 2017

Surface Energy In Bond-Counting Models On Bravais And Non-Bravais Lattices, Tim Ryan Krumwiede

Doctoral Dissertations

Continuum models in computational material science require the choice of a surface energy function, based on properties of the material of interest. This work shows how to use atomistic bond-counting models and crystal geometry to inform this choice. We will examine some of the difficulties that arise in the comparison between these models due to differing types of truncation. New crystal geometry methods are required when considering materials with non-Bravais lattice structure, resulting in a multi-valued surface energy. These methods will then be presented in the context of the two-dimensional material graphene in a way that correctly predicts its equilibrium …