Engineering Commons^™

Anodic Catalysts For Anion Exchange Membrane Fuel Cells, Aaron Joseph Roy

Chemical and Biological Engineering ETDs

With a limited availability of energy resources from petroleum and other fossil fuels, as well as growing concerns relating to the environmental implications of fossil fuel emissions, non-carbon fuels which can be utilized in proton and anion exchange membrane fuel cells (PEMFC’s/AEMFC’s), such as hydrogen and hydrazine hydrate (HH), are becoming more attractive as alternative fuels. Historically, platinum and platinum group metal catalysts (PGM) have been used as cathode and anode catalyst materials for both PEMFC’s and AEMFC’s. Although these catalysts are the highest performing catalysts available for the conversion of hydrogen energy in fuel cells, the limited availability and …

Graphite And Graphene-Oxide Based Pgm-Free Model Catalysts For The Oxygen Reduction Reaction, Joseph Henry Dumont

Nanoscience and Microsystems ETDs

The world currently relies heavily on fossil fuels such as coal, oil, and natural gas for its energy. Fossil fuels are non-renewable, that is, they draw on finite resources that will eventually dwindle, becoming too expensive or too environmentally damaging to retrieve. One alternative source of energy are fuel cells, electrochemical devices that convert chemical energy to cleanly and efficiently produce electricity. They can be used in a wide range of applications, including transportation, stationary, portable and emergency power sources. Their development has been slowed by the high cost of PGM electrocatalysts needed at both electrodes as well as sluggish …

Synthesis And Characterization Of Molybdenum Sulfide And For Hydrogen Evolution Reaction And Supercapacitor Applications, Zhuo Wang

Electronic Theses & Dissertations

To meet the constantly rising requirement of energy other than traditional fossil fuel and environment protection, it is a perfect time to development low cost, and efficient materials for clean energy production. Hydrogen generation by water splitting is one of the cleanest ways to produce cheaper energy. Hydrogen evolution reaction (HER) is one of the key steps in water splitting process. Ideally, the thermodynamic potential for HER should be at 0 V (vs. SHE). However, without an efficient catalyst, this reaction occurred at higher potential, called overpotential. A good HER catalyst is needed to lower the overpotential and hence to …

A Study Of Iron-Nitrogen-Carbon Fuel Cell Catalysts: Chemistry – Nanostructure – Performance, Michael J. Workman

Nanoscience and Microsystems ETDs

Fuel cells have the potential to be a pollution-free, low-cost, and energy efficient alternative to the internal combustion engine for transportation and small-scale stationary power applications. The current state of fuel cell technology has already achieved two of these three lofty goals. The remaining barrier to wide-scale deployment is the high cost, which is primarily caused by dependence on large amounts of platinum to catalyze the energy conversion reactions. To overcome this barrier and facilitate the integration of fuel cells into mainstream applications, research into a new class of catalyst materials that do not require platinum is needed.

There has …

Renewable Carbon From Lignin Biomass And Its Electrode And Catalyst Applications In Batteries, Supercapacitors, And Fuel Cells, Muslum Demir

Theses and Dissertations

Over the last century, almost all of the carbon materials developed for the energy industry are derived from fossil fuels. The growing global concerns about energy needs, fossil fuels consumption, and the related environmental issues have motived scientists to find new, green and sustainable energy resources such as the wind, solar and biomass energy. Essentially, biomass-derived materials can be utilized in energy storage and conversion devices such as Li-ion batteries, fuel cells, and supercapacitors. Among the biomass resources, lignin is a high volume byproduct from the pulp and paper industry and is currently burned to generate electricity and steam. The …

Platinum-Rhodium Alloy Electrocatalyst Activities In The Methanol Oxidation Reaction, William R. Sandorf

Williams Honors College, Honors Research Projects

This study evaluates the electrochemical activity of several compositions of platinum-rhodium alloys on carbon support to identify potential replacements for the expensive platinum electrocatalysts currently used in direct methanol fuel cells (DMFCs). The electrochemical active surface areas (ECSAs) of each sample were determined using cyclic voltammetry (CV) in a 0.5 M H₂SO₄ solution to normalize CV currents generated in the methanol oxidation reaction (MOR). The activity of five compositions was tested; Pt₃Rh, Pt₂Rh, PtRh, Pt₂Rh, and Pt₃Rh. 100 mg of each catalyst was synthesized at 10% by weight platinum …