Engineering Commons^™

Design And Control Of Close Proximity Indirect Exposure For Nonthermal Atmospheric Pressure Plasma-Based Oxidation Of Carbon Fiber Precursor, Truman Andrew Bonds

Doctoral Dissertations

A new plasma-based method for the stabilization of polyacrylonitrile carbon fiber precursor utilizing reactive chemical species derived from a custom atmospheric pressure plasma generation system was developed and demonstrated. As opposed to the conventional stabilization method of convective heating in air, plasma-based stabilization efficiently introduces oxidative reactive species that both diffuse through and react faster with the precursor filaments, resulting in a faster and more efficient process. This method was successfully demonstrated with a variety of precursor chemistries, grades and sizes. The development effort was entirely experimental, with successive processing devices designed and constructed to examine various aspects of the …

The Stability Of Ferrate(Vi) In Water And Its Impacts On Disinfection Byproduct Precursors, Yanjun Jiang

Doctoral Dissertations

Ferrate has been proposed as an alternative pre-oxidant in drinking water treatment for many years. Despite extensive studies that examined ferrate oxidation of specific contaminants, little research has been done on the impacts of ferrate in raw waters that include natural organic matter (NOM) and bromide, and that are also treated with coagulants and chlorine. The future of ferrate as a potable water treatment chemical depends on its ability to achieve adequate disinfection while minimizing the formation of disinfection byproducts (DBPs) under these realistic scenarios. In this work, laboratory-scale treatment studies were conducted to (1) clarify the stability of ferrate …

High Temperature Oxidation Study Of Tantalum Carbide-Hafnium Carbide Solid Solutions Synthesized By Spark Plasma Sintering, Cheng Zhang

FIU Electronic Theses and Dissertations

Tantalum carbide (TaC) and hafnium carbide (HfC) possess extremely high melting points, around 3900 ^oC, which are the highest among the known materials. TaC and HfC exhibit superior oxidation resistance under oxygen deficient and rich environments, respectively. A versatile material can be expected by forming solid solutions of TaC and HfC. However, the synthesis of fully dense solid solution carbide is a challenge due to their intrinsic covalent bonding which makes sintering challenging.

The aim of the present work is to synthesize full dense TaC-HfC solid solutions by spark plasma sintering with five compositions: pure HfC, HfC-20 vol.% TaC …

Oxidation And Mechanical Properties Of In Situ Hybrid (Ticp+Tibw)/Ti6al4v Composites With Tailored Network Microstructure, L. J. Huang, X. P. Cui, Y. Jiao, T. B. Duan, X. T. Li, Y. N. Gao, L. Geng

The 8th International Conference on Physical and Numerical Simulation of Materials Processing

No abstract provided.

The Use Of Sodium Persulfate In Hydraulic Fracturing Fluids: A Degradation Study Based On Furfural, Katherine Elizabeth Manz

Masters Theses

Hydraulic fracturing has allowed natural gas to become a viable energy source via extraction of unconventional shale reserves, but this process requires an enormous amount of water. To ensure a productive fracture, a proprietary blend of chemical additives is added to the water. In this research, a hydraulic fracturing chemical additive – an enzyme breaking agent – is analyzed for organic components using gas chromatography mass spectrometry. The chemical changes that occur over the course of a fracture are also investigated using one model chemical found in the additive, furfural, in order to help assess the environmental risk that hydraulic …

Γ/Γ' Co-Base Superalloys – New High Temperature Materials Beyond Ni-Base Superalloys?, Steffen Neumeier, Christopher H. Zenk, Lisa P. Freund, Mathias Göken

Beyond Nickel-Based Superalloys II

In 2006 a new L1₂ phase, Co₃(Al,W), was discovered in the Co-Al-W system which has led to the development of novel Co-base superalloys with g/g¢ microstructures similar to those of the well-established Ni-base superalloys. First investigations on simple ternary alloys could show that these Co-Al-W based alloys exhibit higher solidus temperatures and show less segregations after casting compared to typical Ni-base superalloys. This leads to the question whether this g/g¢ Co-base superalloys can be regarded as new class of high temperature materials that can compete with or even supersede established Ni-base superalloys.

In the first part of …

Photoenhanced Oxidation Of C60 In Water: Exploring The Roles Of H2o2 And Hydroxyl Radical Based Reactions, Yining Ou

McKelvey School of Engineering Theses & Dissertations

Transformation of water-stable C₆₀ clusters (nC₆₀) to oxidized, soluble C₆₀ derivatives via photoreactions (i.e., reactions in UV irradiation) and ground-state reactions (i.e., reactions in dark) with various oxidants, such as oxygen, ozone, free chlorine, among others, have been described as critical processes in understanding the ultimate environmental fate of fullerene-based materials. However, few studies have explored the oxidation of aqueous based C₆₀ (as water stable nC₆₀) with hydrogen peroxide (H₂O₂) / hydroxyl radical (^.OH), which are common oxidants in both natural and engineered systems. Herein, the aqueous …

Chromium Oxidation By Disinfectants And Oxidants Used In Drinking Water Treatment, Nathan D. Rogers

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This project investigated the behavior of hexavalent chromium (Cr(VI), a potential carcinogen) in drinking water. While Cr(VI) can exist naturally, it can also be oxidized from Cr(III), a known trace nutrient. Recently, the State of California implemented a water regulation specifically for Cr(VI) at 10 parts per billion (ppb). This project completed a comprehensive evaluation of chromium behavior when in contact with common drinking water treatment chemicals including chlorine, monochloramine, chlorine dioxide, potassium permanganate, and ozone.

The results of these oxidation experiments are highly applicable to water treatment facilities. If a treatment plant is using monochloramine, there is no indication …

Materials Selection For Catalyst Supports, Connor G. Carr, Brianna L. Musicó, Andre Z. Shibata, Willie Kemp

Chancellor’s Honors Program Projects

No abstract provided.

Mechanically Activated Combustion Synthesis Of Molybdenum Borosilicides For Ultrahigh-Temperature Structural Applications, Alan Alberto Esparza Hernandez

Open Access Theses & Dissertations

The desire to improve the efficiency of power generation gas-turbines has led to a relentless quest for new, ultrahigh-temperature structural materials to replace the current nickel-based superalloys. These materials have reached the maximum allowable operating temperature determined by the melting temperature of these alloys, which is about 1150 °C. These materials could be replaced by molybdenum silicides and borosilicides based on Mo5SiB 2 (T2) phase due to their high melting point and mechanical properties. A major challenge, however, is to simultaneously achieve high oxidation resistance and acceptable mechanical properties at elevated temperatures. One novel approach to improve these properties is …

Breakaway Oxidation Behaviour Of Ferritic Stainless Steels At 1150 °C In Humid Air, Xiawei Cheng, Zhengyi Jiang, Brian J. Monaghan, Dongbin Wei, Raymond Longbottom, Jingwei Zhao, Jianguo Peng, Ming Luo, Li Ma, Suzhen Luo, Laizhu Jiang

Faculty of Engineering and Information Sciences - Papers: Part A

The breakaway oxidation behaviour of ferritic stainless steels 430, 443 and 445 has been investigatedat 1150◦C in humid air. The oxidation kinetics exhibited significant differences among the three ferriticstainless steels. A uniform and steady growing oxide scale was developed on the 430 steel with an evensteel/oxide interface. Local breakdown of the initially protective oxide scale occurred and oxide noduleswere developed on the 443 and 445 stainless steels, resulting in irregular and rough steel/oxide inter-faces. The breakaway oxidation behaviour was significantly influenced by the microstructure and thecomposition of the oxide scale. The Mn-Cr spinel oxide formed on top of the Cr2O3scale …

Correlation Between Zn-Rich Phase And Corrosion/Oxidation Behavior Of Sn-8zn-3bi Alloy, Xin Zhang, Chong Li, Zhiming Gao, Yongchang Liu, Zongqing Ma, Liming Yu, Hui Jun Li

Faculty of Engineering and Information Sciences - Papers: Part A

The microstructure of Sn-8Zn-3Bi alloy was refined by increasing the solidification rate and the correlation between Zn-rich phase and the corrosion/oxidation behavior of the alloy was investigated. The Zn-rich phase transforms from coarse flakes to fine needles dispersed in the β-Sn matrix with the increase of the cooling rate. The transformation of Zn-rich precipitates enhances the anticorrosive ability of Sn-8Zn-3Bi alloy in 3.5 wt.% NaCl solution. On the contrary, Sn-8Zn-3Bi alloy with a fine needle-like Zn-rich phase shows poor oxidation resistance under air atmosphere, due to the fast diffusion of Zn atoms in Sn matrix.

High Temperature Oxidation Of Indefinite Chill Roll Material Under Dry And Humid Atmospheres, Liang Hao, Zhengyi Jiang, Zhixin Chen, Dongbin Wei, Xiawei Cheng, Jingwei Zhao, Ming Luo, Li Ma, Suzhen Luo, Laizhu Jiang

Faculty of Engineering and Information Sciences - Papers: Part B

In this paper, the isothermal oxidation of the indefinite chill (IC) roll is investigated by using a thermogravimetric analyzer (TGA) from 550 to 700 °C under dry and humid atmospheres. It is found that the oxidation kinetics follow a linear trend and the oxide scale consists of two layers after the oxidation in dry air but three layers in humid air above 600 °C. In dry air, the graphite is covered by the oxide scale above 650 °C. The water vapor accelerates the oxidation of the matrix and the graphite. The graphite is covered by the extension of the oxide …

On The Degradation Of Lubricating Grease, Asghar Rezasoltani

LSU Doctoral Dissertations

A comprehensive literature review on physical and chemical degradation monitoring and life estimation models for lubricating greases is presented in chapter one. Degradation mechanisms for lubricating grease are categorized and described, and an extensive survey of the available empirical and analytical grease life estimation models including degradation monitoring standards and methods are presented. In chapter two, irreversible thermodynamic theory is employed to study the mechanical degradation of lubricating grease. A correlation between the mechanical degradation and entropy generation is established and the results are verified experimentally using a rheometer, a journal bearing test rig, and a modified grease worker machine. …

Oxidation Resistance Of Nanocrystalline 316l Stainless Steel Processed By High Pressure Torsion, Kevin J. Meisner

Williams Honors College, Honors Research Projects

High Pressure Torsion (HPT) is a materials processing method used to refine the grain size of metallic materials through the application of simultaneous axial and torsional strain. HPT is reported to result in nanocrystalline structure, which the current scientific literature suggests may improve the high temperature oxidation resistance by enhancing diffusion of solutes, particularly Cr, to the surface to form a protective external oxide scale. If oxidation resistance is improved, this possibly allows the use of 316L in oxidizing environments where more expensive alloys are typically used. However, the influence of grain refinement to nanoscale on various properties have been …

Investigation Of Ti-6al-4v Alloy Response To Atmospheric Re-Entry Exposure, Jessica Lynn Buckner

Open Access Theses & Dissertations

Ti-6Al-4V is a widely used aerospace alloy for its high strength-to-weight ratio and high operating temperature properties. Despite widespread use, titanium and its alloys have been shown to ignite in oxygen and nitrogen rich test streams. The reactivity of titanium is attributed to the high solubility for oxygen that increases with temperature, accelerating the oxidation rate and resulting in a combustion reaction. When introduced to the monatomic oxygen rich and high enthalpy re-entry environment, Ti-6Al-4V X-link components from the space shuttle Columbia exhibited accelerated oxidation and combustion behavior. Ti-6Al-4V metal plates tested in the simulated re-entry environment of an arc-jet …

Investigating The Influence Of Gold Nanoparticles On The Photocatalytic And Catalytic Reactivity Of Porous Tungsten Oxide Microparticles, Daniel P. Depuccio

Graduate College Dissertations and Theses

Tungsten oxide (WO3) is a semiconducting transition metal oxide with interesting electronic, structural, and chemical properties that have been exploited in applications including catalysis, gas sensing, electrochromic displays, and solar energy conversion. Nanocrystalline WO3 can absorb visible light to catalyze heterogeneous photooxidation reactions. Also, the acidity of the WO3 surface makes this oxide a good thermal catalyst in the dehydration of alcohols to various industrially relevant chemicals. This dissertation explores the photocatalytic and thermal catalytic reactivity of nanocrystalline porous WO3 microparticles. Furthermore, investigations into the changes in WO3 reactivity are carried out after modifying the porous WO3 particles with gold …