Engineering Commons^™

Photocatalytic Reduction Of Co2 With Tunable Bandgap And Bandedge Materials, Thuhuong T. Ngo

USF Tampa Graduate Theses and Dissertations

Solar energy is a sustainable resource which has substantial potential to meet the increasing demand for renewable energy. Though there has been some success in harvesting solar energy for electricity production, converting solar energy to chemical energy as fuels is still a challenge due to low efficiency.

Since the discovery of TiO₂ photocatalysts for splitting water (4) and reducing CO₂ (5) to form useful chemical feedstock such as H₂, CO and CH₄, much research has been done to increase the efficiency of photocatalysts. However, the current conversion efficiency of photocatalysts remains low (~5%) (6, …

Reduced Dimensionality Effects In Gd-Based Magnetocaloric Materials, Hillary Faith Belliveau

USF Tampa Graduate Theses and Dissertations

Magnetic refrigeration based on the magnetocaloric effect (MCE) is a promising alternative to conventional gas compression based cooling techniques. Understanding impacts of reduced dimensionality on the magnetocaloric response of a material such as Gadolinium (Gd) or its alloys is essential in optimizing the performance of cooling devices, which is also the overall goal of this thesis. We have determined, in the first part of the thesis, that laminate structures of pure Gd produced by magnetron sputtering have several disadvantages. The target material (pure Gd), ultra-high vacuum components, and the electrical energy it takes to run the manufacturing process are all …

Improved 2d And 3d Resistivity Surveys Using Buried Electrodes And Optimized Arrays: The Multi-Electrode Resistivity Implant Technique (Merit), Henok Gidey Kiflu

USF Tampa Graduate Theses and Dissertations

This thesis presents a novel resistivity method called Multi-Electrode resistivity technique (MERIT) that is used for high resolution imaging of complex geologic features at depth and near the edges of survey lines. The MERIT electrodes are especially shaped and designed to be self-driven using a robust-direct push technique. Measurements are taken using optimized arrays that are generated using a modified version of the “Compare-R” optimization algorithm. This work focused on both two-dimensional (MERIT2D) and three-dimensional (MERIT3D) applications of the buried array and show the relevance of the additional information gained by the addition of deep electrodes especially in sites with …

Frequency Tunable Antennas And Surface Microwave Imaging System Using Microfluidic Reconfiguration Techniques, Abhishek Dey

USF Tampa Graduate Theses and Dissertations

Reconfigurable radio frequency (RF) devices are attractive for miniaturization of wireless components and systems by handling functionality of multiple distinct devices. Existing reconfiguration techniques rely on device loadings with semiconductor diodes, ferrite/ferroelectric materials, and microelectromechanical system (MEMS) switches and capacitors. However, it is well-recognized that these techniques cannot fully address important system metrics such as high efficiency, wide frequency tuning range, high power handling capability and cost. Therefore, novel alternative techniques are highly desirable to advance the state of the art in reconfigurable RF devices. The aim of this dissertation is to investigate the novel concept of microfluidically loaded reconfigurability …

Confinement Effects And Magnetic Interactions In Magnetic Nanostructures, Kristen Lee Stojak Repa

USF Tampa Graduate Theses and Dissertations

Multifunctional nanocomposites are promising for a variety of applications ranging from microwave devices to biomedicine. High demand exists for magnetically tunable nanocomposite materials. My thesis focuses on synthesis and characterization of novel nanomaterials such as polymer nanocomposites (PNCs) and multi-walled carbon nanotubes (MWCNTs) with magnetic nanoparticle (NP) fillers.

Magnetite (Fe₃O₄) and cobalt ferrite (CoFe2O4) NPs with controlled shape, size, and crystallinity were successfully synthesized and used as PNC fillers in a commercial polymer provided by the Rogers Corporation and poly(vinylidene fluoride). Magnetic and microwave experiments were conducted under frequencies of 1-6 GHz in the presence of …

Advancements In Thermal Integrity Profiling Data Analysis, Kevin Russell Johnson

USF Tampa Graduate Theses and Dissertations

Thermal Integrity Profiling (TIP) is a relatively new non-destructive test method for evaluating the post-construction quality of drilled shafts. Therein anomalies in a shaft are indicated by variations in its thermal profile when measured during the curing stages of the concrete. A considerable benefit with this method is in the ability to detect anomalies both inside and outside the reinforcement cage, as well as provide a measure of lateral cage alignment. Similarly remarkable, early developments showed that the shape of a temperature profile (with depth) matched closely with the shape of the shaft, thus allowing for a straightforward interpretation of …

Towards Computational Human Behavior Modeling For Just-In-Time Adaptive Interventions, Tylar Murray

USF Tampa Graduate Theses and Dissertations

The advent of powerful wearable devices and smartphones has enabled a new generation of “in-the-wild” user studies, adaptive behavioral intervention strategies, and context measurement. Though numerous proof-of-concept studies continue to push the limitations of what a behavioral scientist can do with these technologies, there remains a major methodological roadblock separating behavioral theory and application. Avatar-user interaction theory, for example, is not well defined in its formulation, and thus guidelines for intervention designers depend on heuristic methods and designer intuition. Computational modeling has been slow to move into behavioral science in general, but a growing population of behavioral scientists recognize this …

Optimal Demand Response Models With Energy Storage Systems In Smart Grids, Mohemmed Masooud Alhaider

USF Tampa Graduate Theses and Dissertations

This research aims to develop solutions to relieve system stress conditions in electric grids. The approach adopted in this research is based on a new concept in the Smart Grid, namely, demand response optimization. A number of demand response programs with energy storage systems are designed to enable a community to achieve optimal demand side energy management.

The proposed models aim to improve the utilization of the demand side energy through load management programs including peak shaving, load shifting, and valley lling. First, a model is proposed to nd the optimal capacity of the battery energy storage system (BESS) to …

Scheduling Design For Advance Virtual Network Services, Hao Bai

USF Tampa Graduate Theses and Dissertations

Network virtualization allows operators to host multiple client services over their base physical infrastructures. Today, this technique is being used to support a wide range of applications in cloud computing services, content distribution, large data backup, etc. Accordingly, many different algorithms have also been developed to achieve efficient mapping of client virtual network (VN) requests over physical topologies consisting of networking infrastructures and datacenter compute/storage resources. However as applications continue to expand, there is a growing need to implement scheduling capabilities for virtual network demands in order to improve network resource utilization and guarantee quality of service (QoS) support.

Now …

A Framework For Studying Meshfree Geometry And A Method For Explicit Boundary Determination, Joseph Bradley Alford

USF Tampa Graduate Theses and Dissertations

Patient-specific biomechanical analysis is an important tool used to understand the complex processes that occur in the body due to physical stimulation. Patient-specific models are generated by processing medical images; once an object from the image is identified via segmentation, a point cloud representation of the object is extracted. Generating an analysis suitable representation from the point cloud has traditionally required generating a finite element mesh, which often requires a well defined surface to accomplish. Point clouds lack a well defined geometry, meaning that the surface definition is incomplete at best. Point clouds that have been generated from images have …

Novel Magnetic Nanostructures For Enhanced Magnetic Hyperthermia Cancer Therapy, Zohreh Nemati Porshokouh

USF Tampa Graduate Theses and Dissertations

In this dissertation, I present the results of a systematic study on novel multifunctional nanostructure systems for magnetic hyperthermia applications. All the samples have been synthesized, structurally/magnetically characterized, and tested for magnetic hyperthermia treatment at the Functional Materials Laboratory of the University South Florida. This work includes studies on four different systems: (i) Core/shell Fe/γ-Fe₂O₃ nanoparticles; (ii) Spherical and cubic exchange coupled FeO/Fe₃O₄ nanoparticles; (iii) Fe₃O₄ nano-octopods with different sizes; (iv) High aspect ratio FeCo nanowires and Fe₃O₄ nanorods.

In particular, we demonstrated the enhancement of the heating …

Development Of An Anaerobic-Phototrophic Bioreactor System For Wastewater Treatment, Onur Yilmaz Ozcan

USF Tampa Graduate Theses and Dissertations

For decades, mainstream domestic wastewater treatment has relied on activated sludge processes to remove organic matter, and on biological nutrient removal systems like the A²/O process to remove nutrients. Recently, membrane filtration was also added to the realm of possible technologies for domestic wastewater treatment, with aerobic membrane bioreactors (MBRs) becoming increasingly popular, especially for decentralized, and small to medium scale applications. However, the aerobic activated sludge and MBR processes, which are often combined with biological nutrient removal processes, have high energy costs associated with supplying oxygen to the process, and end up converting the organic matter into …

Phasor Measurement Unit Data-Based States And Parameters Estimation In Power System, Hossein Ghassempour Aghamolki

USF Tampa Graduate Theses and Dissertations

The dissertation research investigates estimating of power system static and dynamic states (e.g. rotor angle, rotor speed, mechanical power, voltage magnitude, voltage phase angle, mechanical reference point) as well as identification of synchronous generator parameters. The research has two focuses:

i. Synchronous generator dynamic model states and parameters estimation using real-time PMU data.

ii.Integrate PMU data and conventional measurements to carry out static state estimation.

The first part of the work focuses on Phasor Measurement Unit (PMU) data-based synchronous generator states and parameters estimation. In completed work, PMU data-based synchronous generator model identification is carried out using Unscented Kalman Filter …

Effective Post-Tensioned Splicing System For Prestressed Concrete Piles, Zhongxin Wu

USF Tampa Graduate Theses and Dissertations

Precast prestressed concrete piles are widely used in deep foundation construction. Due to unexpected site soil conditions and difficulties associated with transportation and handling long precast piles, splicing is sometimes necessary at the construction site.

Available splicing methods utilize steel type connections that are more suitable for reinforced concrete construction and result in limited tensile capacity at the splice. This dissertation describes studies associated with the development of a new post-tensioned splicing system using staggered, embedded anchorages. The new system has the potential to provide the same tensile capacity as a one piece prestressed pile.

To develop the post-tensioned splicing …

Intraocular Pressure Sensing And Control For Glaucoma Research, Simon Antonio Bello

USF Tampa Graduate Theses and Dissertations

Animal models of ocular hypertension are important for glaucoma research but come with experimental costs. Available methods of intraocular pressure (IOP) elevation are not always successful, the amplitude and time course of IOP changes are unpredictable and irreversible, and IOP measurement by tonometry is laborious. This dissertation focuses on the development and implementation of two novel systems for monitoring and controlling IOP without these limitations. The first device consists of a cannula implanted in the anterior chamber of the eye, a pressure sensor that continually measures IOP, and a bidirectional pump driven by control circuitry that can infuse or withdraw …

Experimental And Computational Study On Fracture Mechanics Of Multilayered Structures, Hai Thanh Tran

USF Tampa Graduate Theses and Dissertations

Many devices in electronics are in the form of multilayered structures. These structures can fail catastrophically if they contain defects or cracks. Enhancing their fracture properties is therefore critical to improve the reliability of the systems. The interface-dominated fracture mechanics of multilayered structure was studied using experiments and finite element (FE) modeling by considering two examples: thin films on polymer substrates in flexible electronics and Cu leadframe/epoxy molding compound (EMC) in micro-electronics packaging.

In the first example, aluminum-manganese (Al-Mn) thin films with Mn concentration up to 20.5 at.% were deposited on polyimide (PI) substrates. A variety of phases, including supersaturated …

Molybdenum Disulfide-Conducting Polymer Composite Structures For Electrochemical Biosensor Applications, Hongxiang Jia

USF Tampa Graduate Theses and Dissertations

Lactic acid is widely existing in human bodies, animals and microorganisms. Recently, using biosensor to detect the concentration of lactic acid and diagnose disease have attracted great research and development interests. Nanocomposites is one of the best material used for biosensor because their wonderful conductivity, optical and electrochemical properties. In the study, MoS₂ and polypyrrole (PPY) are used for the composite material electrode. To determine whether lactate oxidase (LOD) was helpful for the biosensor’s detective properties, both PPY-MoS₂ film with LOD and PPY-MoS₂ film without LOD are being tested. The fourier transform infrared spectroscopy (FTIR) and Raman …

Behavioral Modeling And Fpga Synthesis Of Ieee 802.11n Orthogonal Frequency Division Multiplexing (Ofdm) Scheme, Ragahv Sharma

USF Tampa Graduate Theses and Dissertations

In the field of communications, a high data rate and low multi-path fading is required for efficient information exchange. Orthogonal Frequency Division Multiplexing (OFDM) is a widely accepted IEEE 802.11n (and many others) standard for usage in communication systems operating in fading dispersive channels. In this thesis, we modeled the OFDM algorithm at the behavioral level in VHDL/Verilog that was successfully synthesized/verified on an FPGA. Due to rapid technology scaling, FPGAs have become popular and are low-cost and high performance alternatives to (semi-) custom ASICs. Further, due to reprogramming flexibility, FPGAs are useful in rapid prototyping. As per the IEEE …

Simulation And Verification Of Fluid Jet Polishing, Senmiao Hu

USF Tampa Graduate Theses and Dissertations

Fluid jet polishing (FJP) is a new advanced polishing technology that finds applications in many industries, especially in the optics industry. With the broad application of various surfaces in optics, the sub-micrometric scale and the nanometric surface roughness accuracy are major challenges. Fluid jet polishing is a technology developed from abrasive water jet machining. This technology is a water jet cutting technology, which uses high-pressure flow to cut/remove materials.

In this thesis, the working principle, and simulations, as well as verification of fluid jet polishing are thoroughly investigated. The verification of fluid jet polishing in this thesis includes velocity distribution …

Formation Of Trihalomethanes (Thms) As Disinfection By-Products (Dbps) When Treated Municipal Wastewater Is Disinfected With Sodium Hypochlorite, Helene Kassouf

USF Tampa Graduate Theses and Dissertations

Disinfection is an essential process in the treatment of municipal wastewater before the treated wastewater can be discharged to the environment. Hillsborough County's Northwest Regional Water Reclamation Facility (NWRWRF) in Tampa, Florida, currently uses ultraviolet (UV) light for disinfection. However, this method has proven expensive to implement and maintain, and may not be effective if the light transmission is poor. For these reasons, Hillsborough County is considering switching from UV light to sodium hypochlorite for disinfection. However, hypochlorite (chlorine) disinfection has disadvantages as well, such as the production of disinfection by-products (DBPs) such as trihalomethanes (THM) and haloacetic acids (HAAs), …

Pepper Mild Mottle Virus As A Surrogate For Enteric Viruses: Implications For Assessing Water Quality, Erin Michelle Symonds

USF Tampa Graduate Theses and Dissertations

Less than 10% of the world’s domestic wastewater is disinfected prior to discharge into surface waters; therefore, human exposure to diverse wastewater-related pathogens results in millions of cases of illness each year. Among the enteric pathogens, viruses represent an important group of emerging pathogens and are frequently the cause of food- and water-borne outbreaks of illness. Although the World Health Organization and many government agencies mandate the use of bacterial indicators to identify poor microbial water quality, it is well known that these indicators poorly correlate with fecal pollution contamination events and risk of disease. The field of public health-related …

Corrosion Characteristics Of Magnesium Under Varying Surface Roughness Conditions, Yahya Efe Yayoglu

USF Tampa Graduate Theses and Dissertations

The biggest challenge with magnesium alloy biodegradable implants is the rapid corrosion at the earlier stages of the healing process after implantation. In this research, the impact of surface roughness generated by different means on the corrosion rate of AZ31 magnesium alloy in a simulated biologic environment is investigated. In order to perform accurate experimentation, an in vitro setup is assembled that simulates the human body environment accurately has been prepared using Schinhammer’s in vitro immersion testing setup and Kokubo’s Simulated Body Fluid (SBF). For the immersion test of Mg in SBF, several surface texture groups of Mg have been …

Cracking Potential And Temperature Sensitivity Of Metakaolin Concrete, Andrew Robert Williams

USF Tampa Graduate Theses and Dissertations

Metakaolin is a pozzolanic material with the potential to reduce permeability and chloride ingress; however, quantification of the effects of metakaolin use on the cracking sensitivity of concrete mixtures is needed to ensure that these improvements in performance are not compromised. This study was conducted to investigate the early age cracking potential due to restraint stresses from incorporating metakaolin in concrete. Calorimetry testing showed that metakaolin was more sensitive to temperature than mixtures with only Portland cement. Results showed more shrinkage, less stress relaxation, and higher restraint stress from the inclusion of metakaolin, potentially increasing cracking sensitivity of mixtures.

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Biomarker Detection At Risk Forecasting Level Using Metal-Enhanced Fluorescence Combined With Surface Acoustic Wave, Jun Liu

USF Tampa Graduate Theses and Dissertations

In this paper, metal-enhanced fluorescence (MEF) technique is used to lower the detection limit of carcinoembryonic antigen (CEA) which is able to be utilized in forecasting the risk of having certain kinds of cancers, especially colon and rectal cancer. By incubating silver nanocubes (Ag NCs) on the surface of the chips, the detection limit goes down to below 1ng/mL of CEA. Also, when combining MEF with surface acoustic wave (SAW) devices, the incubation time between antigen and antibody will decrease significantly with the fluorescence signal keeping similar or higher level.

The Effect Of The Antecedent Dry Conditions On Nitrogen Removal For A Modified Bioretention System, Mackenzie Peterson

USF Tampa Graduate Theses and Dissertations

Eutrophication is defined as the ‘over enrichment’ of a water body from nutrients, resulting in uncontrolled growth of primary producers, leading to periods of oxygen depletion from decomposition of the algal organic matter. According to the 2010 Water Infrastructure Needs and Investment (a U.S. Congressional Report), 40% of U.S. water bodies are contaminated with pollutants, including nutrients. Non-point sources of nutrient pollution are a major cause of this reduction in water quality. One way to decrease eutrophication is to manage nutrients found in stormwater runoff, before they reach a receiving water body.

Bioretention cells containing an internal water storage zone …

Threshold Voltage Defined Switches And Gates To Prevent Reverse Engineering, Ithihasa Reddy Nirmala

USF Tampa Graduate Theses and Dissertations

¹Semiconductor supply chain is increasingly getting exposed to variety of security attacks such as Trojan insertion, cloning, counterfeiting, reverse engineering (RE), piracy of Intellectual Property (IP) or Integrated Circuit (IC) and side-channel analysis due to involvement of untrusted parties. In this thesis, we use threshold voltage-defined switches to design a logic gate that will camouflage the conventional logic gates both logically and physically to resist RE and IP piracy. The proposed gate can function as NAND, AND, NOR, OR, XOR, and XNOR robustly using threshold defined switches. We also propose a flavor of camouflaged gate that represents reduced functionality …

Time Dependent Effect Of Drilling Slurries On Side Shear Resistance Of Drilled Shafts, Warren Allen

USF Tampa Graduate Theses and Dissertations

Drilled shafts are cylindrical deep foundations constructed by casting fluid concrete into an excavated hole. These elements rely largely on side shear resistance generated by their substantial diameters and lengths to effectively transfer loads. Therefore, an exceptional concrete to soil interface is essential for proper performance of these structures. The FDOT preferred stabilization fluid, bentonite slurry, has been proven to degrade this interface with increased exposure time due to filter cake formation. For this reason, slurry exposure time has been limited to 36 hours by FDOT. Alternately, polymer slurries do not form a filter cake but rather stabilize excavations through …

Metal-Organic Frameworks As Potential Platforms For Carbon Dioxide Capture And Chemical Transformation, Wenyang Gao

USF Tampa Graduate Theses and Dissertations

The anthropogenic carbon dioxide (CO₂) emission into the atmosphere, mainly through the combustion of fossil fuels, has resulted in a balance disturbance of the carbon cycle. Overwhelming scientific evidence proves that the escalating level of atmospheric CO₂ is deemed as the main culprit for global warming and climate change. It is thus imperative to develop viable CO₂ capture and sequestration (CCS) technologies to reduce CO₂ emissions, which is also essential to avoid the potential devastating effects in future. The drawbacks of energy-cost, corrosion and inefficiency for amine-based wet-scrubbing systems which are currently used in industry, …

Methodologies To Exploit Atpg Tools For De-Camouflaging, Deepak Reddy Vontela

USF Tampa Graduate Theses and Dissertations

Semiconductor supply chain is increasingly getting exposed to Reverse Engineering (RE) of Intellectual Property (IP). Camouflaging of gates in integrated circuits are typically employed to hide the gate functionality to prevent reverse engineering. The functionalities of these gates cannot be found by De-layering as they don’t leave any layout clues. Adversaries perform reverse engineering by replacing the camouflaged gate with the known gate and by developing custom software to determine test patterns. These test patterns are used to analyze the outputs and to conclude the functionality of the camouflaged gate.

In this thesis, we show that reverse engineering of camouflaged …

Investigation Of Future Flow Reducer Sizes In Houses Added To An Existing Gravity Flow Water System To Ensure Its Sustainability, Michelle Roy

USF Tampa Graduate Theses and Dissertations

Goal 6 of the United Nations Development Program’s new Sustainable Development Goals aims to ensure availability of clean water and sustainable management practices to all by the year 2030. Peace Corps Panama partners with communities in order to help provide sustainable water solutions to communities in need. Water, Sanitation, and Hygiene (WASH) Volunteers spend at least two years living in a community to identify and implement solutions to water problems and train local water committees on how to maintain their improved systems. A common solution for unequal distribution of flow in the distribution network of a gravity flow water system …