Engineering Commons^™

Mechanically Activated Combustion Synthesis Of Molybdenum Borosilicides For Ultrahigh-Temperature Structural Applications, Alan Alberto Esparza Hernandez

Open Access Theses & Dissertations

The desire to improve the efficiency of power generation gas-turbines has led to a relentless quest for new, ultrahigh-temperature structural materials to replace the current nickel-based superalloys. These materials have reached the maximum allowable operating temperature determined by the melting temperature of these alloys, which is about 1150 °C. These materials could be replaced by molybdenum silicides and borosilicides based on Mo5SiB 2 (T2) phase due to their high melting point and mechanical properties. A major challenge, however, is to simultaneously achieve high oxidation resistance and acceptable mechanical properties at elevated temperatures. One novel approach to improve these properties is …

Magnesium-Based Combustion Synthesis Of Advanced Materials For Energy And Space Applications, Armando Delgado

Open Access Theses & Dissertations

As energy problems become more challenging, interest in low-energy-consuming methods for the fabrication of materials increases. Combustion synThesis is one such method because it is sustained by reaction heat release instead of external energy input. In the present work, combustion synThesis approaches are applied to the production of construction materials from lunar and Martian regolith and to the fabrication of magnesium silicide (Mg2Si), a promising thermoelectric material for high-temperature applications. In both cases, magnesium (Mg) was used as one of the main reactants and similar experimental approaches were employed.

Recently, it has been proposed to use combustion of lunar regolith …