Engineering Commons^™

Liquid Phase Sintering Of 20bi(Zn₀.₅Ti₀.₅)O₃-80batio₃ Dielectrics With Bismuth-Zinc-Borate And Bismuth Borosilicate Glasses, David I. Shahin

Masters Theses

"Dielectrics in the Bi(Zn₀.₅Ti₀.₅O₃-BaTiO₃ system (specifically 20BZT-80BT, in mol%) are promising candidates for high energy density capacitor applications due to broad temperature-dependent dielectric constant maxima and a relatively field-independent permittivity. Bulk samples require sintering temperatures of greater than 1180ºC to reach useful densities. Due to incompatibility of Bi with low-pO₂ processing, BZT-BT-based multilayer capacitors must utilize noble metal electrodes that resist oxidation during sintering. Sintering temperatures must be reduced to allow use of less expensive electrode materials (Cu, etc.). This work studies the reduced temperature sintering behavior and dielectric properties of BZT-BT sintered with 30 Bi₂O₃-30ZnO-40B₂O₃ and 50Bi₂O₃-25B₂O₃-25SiO₂ (mol%) liquid …

Bioactive Glass Scaffolds For The Regeneration Of Load-Bearing Bone, Xin Liu

Doctoral Dissertations

"Biocompatible scaffolds that replicate the structure and function of bone would be ideal bone substitutes for structural bone loss, provided they have the requisite mechanical properties for reliable long-term loading. In this dissertation, strong porous scaffolds of silicate 13-93 bioactive glass, created with two different microstructures, were evaluated to determine their mechanical properties and their capacity to regenerate bone in a rat calvarial defect model. Scaffolds with an oriented microstructure of columnar pores were prepared by unidirectional freezing of camphene-based suspensions, followed by thermal annealing and sintering. By optimizing the freezing conditions, annealing time, and sintering temperature, constructs (porosity = …

Processing And Properties Of Zrb₂-Zrsi₂ Matrix Composites Reinforced With Continuous Sic Fiber, Benjamin John Bowin Lai

Masters Theses

"The research presented in this thesis focuses on the processing, microstructure, and mechanical properties of ZrB₂-based composites. The main goal was to develop a process that incorporates high strength continuous SiC fiber in a ZrB₂-based matrix. In order to achieve this, the densification, microstructure, and mechanical properties of ZrB₂-ZrSi₂ monolithic ceramics were characterized along with various SiC fiber reinforced ceramic matrix composites (CMCs) utilizing the same matrix.

There were two main areas of study in this thesis. The initial study demonstrated that additions of ZrSi₂ into a ZrB₂ ceramic increases densification at significantly reduced processing temperatures ≤1600ºC). This study revealed …