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2012

Series

Australian Institute for Innovative Materials - Papers

Synthesis

Articles 1 - 5 of 5

Full-Text Articles in Engineering

One-Pot Synthesis Of Colloidal Silicon Quantum Dots And Surface Functionalization Via Thiol-Ene Click Chemistry, Xiaoyu Cheng, Richard Gondosiswanto, Simone Ciampi, Peter J. Reece, J Justin Gooding Jan 2012

One-Pot Synthesis Of Colloidal Silicon Quantum Dots And Surface Functionalization Via Thiol-Ene Click Chemistry, Xiaoyu Cheng, Richard Gondosiswanto, Simone Ciampi, Peter J. Reece, J Justin Gooding

Australian Institute for Innovative Materials - Papers

A solution method for preparing surface functionalized colloidal silicon quantum dots (SiQDs) is presented. SiQDs prepared by this method are reasonably monodispersed and can be further functionalized via thiol-ene click reactions to introduce specific functionalities (i.e. -NH2, -COOH, -SO 3 -, alkane, alkene).


The Synthesis Of Lamellar Nano Mgb2 Grains With Nanoimpurities, Flux Pinning Centers And Their Significantly Improved Critical Current Density, Zongqing Ma, Yongchang Liu, Qi Cai Jan 2012

The Synthesis Of Lamellar Nano Mgb2 Grains With Nanoimpurities, Flux Pinning Centers And Their Significantly Improved Critical Current Density, Zongqing Ma, Yongchang Liu, Qi Cai

Australian Institute for Innovative Materials - Papers

MgB2 superconductors with unique microstructures were rapidly fabricated at low temperatures, and exhibited significantly improved critical current density (Jc). According to the microstructure observations, the prepared samples consisted of lamellar nano MgB2 grains with many embedded nanoimpurities (about 10 nm). The formation of these lamellar nano MgB2 grains is associated with the presence of a local Mg-Cu liquid at sintering temperatures as low as 575°C. The ball milling treatment of the original powders also plays a positive role in the growth of lamellar grains. Based on an analysis of the relationship between resistivity and temperature, the lamellar nano MgB2 grains …


Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou Jan 2012

Ferroelectric And Ferromagnetic Nanofibers: Synthesis, Properties And Applications, A Jalalian, A M. Grishin, S X. Dou

Australian Institute for Innovative Materials - Papers

As first time, ferroelectric (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ), biocompatible (Na0.5K0.5)NbO3 (NKN), and ferromagnetic Y3Fe5O12 (YIG) nanofibers were synthesized by sol-gel assisted electrospining technique. Non-woven, bead-free 100 μm long fiber mat was formed from close-packed nanocrystals after calcination in air at 800°C (BCTZ and NKN) and 1100°C (YIG). BCTZ fibers are 200 nm in width whereas NKN and YIG fibers have smaller 50-100 nm diameter. X-ray diffraction and Raman spectroscopy show that BCTZ and NKN crystallized in tetragonal and rhombohedral polar phases in the vicinity of morphotropic phase boundary. …


Synthesis And Electrochemical Characterization Of Lifepo4/C-Polypyrrole Composite Prepared By A Simple Chemical Vapor Deposition Method, Qiang Gong, Yu-Shi He, Yang Yang, Xiao Zhen Liao, Zi-Feng Ma Jan 2012

Synthesis And Electrochemical Characterization Of Lifepo4/C-Polypyrrole Composite Prepared By A Simple Chemical Vapor Deposition Method, Qiang Gong, Yu-Shi He, Yang Yang, Xiao Zhen Liao, Zi-Feng Ma

Australian Institute for Innovative Materials - Papers

A LiFePO4/C-polypyrrole (LiFePO4/C-PPy) composite as a high-performance cathode material is successfully prepared through a simple chemical vapor deposition (CVD) method. According to the transmission electron microscope (TEM) analysis, the surface of the LiFePO4/C is surrounded with PPy in the LiFePO4/C-PPy composite. The as-prepared LiFePO4/C-PPy material shows outstanding rate capability at 20°C and good cycle performance at 55°C in comparison with those of the bare LiFePO4/C material against Li anode. After 700 cycles, the discharge capacity of LiFePO4/C-PPy could still remain 110 mA h g−1 with …


Large Scale Synthesis Of V-Shaped Rutile Twinned Nanorods, Weigang Lu, Britain Bruner, Gilberto Casillas, Jibao He, Miguel Jose-Yacaman, Patrick J. Farmer Jan 2012

Large Scale Synthesis Of V-Shaped Rutile Twinned Nanorods, Weigang Lu, Britain Bruner, Gilberto Casillas, Jibao He, Miguel Jose-Yacaman, Patrick J. Farmer

Australian Institute for Innovative Materials - Papers

V-shaped rutile twinned nanorods (VRTNs) with different aspect ratios were synthesized on large scale using a one-pot organic solvothermal method. Although several different types of VRTNs were produced, (101) twinned nanorods were the major product with minor amounts of (301) twins and straight nanorods. STEM, TEM and XRD characterizations show that [001] is the growth direction of VRTNs, with surfaces dominated by {110} facets. Intermediate formation of both brookite and anatase nanorods provides dual pathways to VRTNs’ growth: one path in which anatase seeds trigger and promote brookite nanorod growth; and a second path in which anatase nanorods are formed …