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2012

Series

Australian Institute for Innovative Materials - Papers

Films

Articles 1 - 7 of 7

Full-Text Articles in Engineering

The Role Of Unbound Oligomers In The Nucleation And Growth Of Electrodeposited Polypyrrole And Method For Preparing High Strength, High Conductivity Films, Wen Zheng, Joselito M. Razal, Geoffrey M. Spinks, Van-Tan Truong, Philip G. Whitten, Gordon G. Wallace Jan 2012

The Role Of Unbound Oligomers In The Nucleation And Growth Of Electrodeposited Polypyrrole And Method For Preparing High Strength, High Conductivity Films, Wen Zheng, Joselito M. Razal, Geoffrey M. Spinks, Van-Tan Truong, Philip G. Whitten, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Polypyrrole is a material with immensely useful properties suitable for a wide range of electrochemical applications, but its development has been hindered by cumbersome manufacturing processes. Here we show that a simple modification to the standard electrochemical polymerization method produces polypyrrole films of equivalently high conductivity and superior mechanical properties in one-tenth of the polymerization time. Preparing the film as a series of electrodeposited layers with thorough solvent washing between layering was found to produce excellent quality films even when layer deposition was accelerated by high current. The washing step between the sequentially polymerized layers altered the deposition mechanism, eliminating …


Quasi-One-Dimensional Intermittent Flux Behavior In Superconducting Films, A J. Qviller, V V. Yurchenko, Y M. Galperin, J I. Vestgarden, P B. Mozhaeva, J B. Hansen, T H. Johansen Jan 2012

Quasi-One-Dimensional Intermittent Flux Behavior In Superconducting Films, A J. Qviller, V V. Yurchenko, Y M. Galperin, J I. Vestgarden, P B. Mozhaeva, J B. Hansen, T H. Johansen

Australian Institute for Innovative Materials - Papers

Intermittent filamentary dynamics of the vortex matter in superconductors is found in films of YBa2Cu3O7-δ deposited on tilted substrates. Deposition of this material on such substrates creates parallel channels of easy flux penetration when a magnetic field is applied perpendicular to the film. As the applied field is gradually increased, magneto-optical imaging reveals that flux penetrates via numerous quasi-one-dimensional jumps. The distribution of flux avalanche sizes follows a power law, and data collapse is obtained by finite-size scaling, with the depth of the flux front used as crossover length. The intermittent behavior shows no threshold …


Effects Of Atomic Layer Deposited Thin Films On Dye Sensitized Solar Cell Performance, Jonathan A. Campbell, Mervyn Deborniol, Attila J. Mozer, Peter J. Evans, Robert P. Burford, Gerry Triani Jan 2012

Effects Of Atomic Layer Deposited Thin Films On Dye Sensitized Solar Cell Performance, Jonathan A. Campbell, Mervyn Deborniol, Attila J. Mozer, Peter J. Evans, Robert P. Burford, Gerry Triani

Australian Institute for Innovative Materials - Papers

"The application of thin titania films by atomic layer deposition on top of a low temperature nanoparticulate TiO2 electrode was found to enhance the performance of dye sensitized solar cells. Dynamic measurements of photoinduced charge extraction showed that the atomic layer deposited top coat increased the electron lifetime at the same electron density. This was attributed to an increased electron trap concentration, which resulted in slower charge transport and increased charge carrier lifetimes.


All-Polymer Battery System Based On Polypyrrole (Ppy)/Para (Toluene Sulfonic Acid) (Pts) And Polypyrrole (Ppy)/Indigo Carmine (Ic) Free Standing Films, Irin Sultana, Md. Mokhlesur Rahman, Jiazhao Wang, Caiyun Wang, Gordon G. Wallace, Hua-Kun Liu Jan 2012

All-Polymer Battery System Based On Polypyrrole (Ppy)/Para (Toluene Sulfonic Acid) (Pts) And Polypyrrole (Ppy)/Indigo Carmine (Ic) Free Standing Films, Irin Sultana, Md. Mokhlesur Rahman, Jiazhao Wang, Caiyun Wang, Gordon G. Wallace, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

In this study, we introduce a novel all-polymer battery system based on conducting polymer (polypyrrole, PPy) doped with dopants of para (toluene sulfonic acid) (pTS) and indigo carmine (IC), respectively. The performance of the systems consisting of polypyrrole-para (toluene sulfonic acid) (PPy-pTS) as cathode and polypyrrole-indigo carmine (PPy-IC) as anode in conjunction with either a polymer based electrolyte or a commercial organic electrolyte of 1M LiPF6 in a 50:50 (v/v) mixture of ethylene carbonate (EC) and dimethyl carbonate (DMC) was evaluated. In the system, all the free-standing PPy-pTS and PPy-IC films were directly …


Mechanism For Flux Guidance By Micrometric Antidot Arrays In Superconducting Films, J I. Vestgarden, V V. Yurchenko, R Wordenweber, T H. Johansen Jan 2012

Mechanism For Flux Guidance By Micrometric Antidot Arrays In Superconducting Films, J I. Vestgarden, V V. Yurchenko, R Wordenweber, T H. Johansen

Australian Institute for Innovative Materials - Papers

"A study of magnetic flux penetration in a superconducting film patterned with arrays of micron-sized antidots (microholes) is reported. Magneto-optical imaging (MOI) of a YBa(2)Cu(3)O(x) film shaped as a long strip with perpendicular antidot arrays revealed both strong guidance of flux and, at the same time, large perturbations of the overall flux penetration and flow of current. These results are compared with a numerical flux creep simulation of a thin superconductor with the same antidot pattern. To perform calculations on such a complex geometry, an efficient numerical scheme for handling the boundary conditions of the antidots and the nonlocal electrodynamics …


Strain Modulated Transient Photostriction In La And Nb Codoped Multiferroic Bifeo3 Thin Films, Zuanming Jin, Yue Xu, Zhengbing Zhang, Xian Lin, Guohong Ma, Zhenxiang Cheng, Xiaolin Wang Jan 2012

Strain Modulated Transient Photostriction In La And Nb Codoped Multiferroic Bifeo3 Thin Films, Zuanming Jin, Yue Xu, Zhengbing Zhang, Xian Lin, Guohong Ma, Zhenxiang Cheng, Xiaolin Wang

Australian Institute for Innovative Materials - Papers

The coherent longitudinal acoustic (LA) phonons in La and Nb codoped polycrystalline BiFeO3 (Bi0.8La0.2Fe 0.99Nb0.01O3 (BLFNO)) films are photo-induced and detected by the ultrafast reflectance spectroscopy. The generation mechanism of LA phonons is strongly connected with the ferroelectric polarization and is attributed to the transient photostriction effect, which is a combination of the optical rectification effect and the electrostriction effect. The strain modulation of sound velocity and out-of-plane elastic properties are demonstrated in BLFNO film on SrTiO3, which gives the insight on the dynamical coupling between electrical polarization and lattice deformation. Our findings are desired for the design of BiFeO3-based …


Fabrication And Magneto-Transport Properties Of P-Type Bi0.5sb1.5te3 Thin Films On Glass By Pulsed Laser Deposition, Zhenwei Yu, Xiaolin Wang, Yi Du, Chao Zhang Jan 2012

Fabrication And Magneto-Transport Properties Of P-Type Bi0.5sb1.5te3 Thin Films On Glass By Pulsed Laser Deposition, Zhenwei Yu, Xiaolin Wang, Yi Du, Chao Zhang

Australian Institute for Innovative Materials - Papers

Bi0.5Sb1. 5Te3 thin films were deposited on glass substrates by pulsed laser deposition (PLD) method at room temperature. Annealing effect on properties of the films was studied by structural, morphology and physical characterizations. It was found that the as-grown amorphous film crystallizes at annealing temperature of 473 K. A semiconductor-metal transition was observed in annealed films. A linear magnetoresistance (MR) was investigated in the annealed films in a magnetic field up to 13 T without saturation at low temperature.