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2012

Series

Australian Institute for Innovative Materials - Papers

Carbon

Articles 1 - 6 of 6

Full-Text Articles in Engineering

Microscopic Role Of Carbon On Mgb2 Wire For Critical Current Density Comparable To Nbti, Jung Ho Kim, Sangjun Oh, Yoon-Uk Heo, Satoshi Hata, Hiroaki Kumakura, Akiyoshi Matsumoto, Masatoshi Mitsuhara, Seyong Choi, Yusuke Shimada, Minoru Maeda, Judith Macmanus-Driscoll, S X. Dou Jan 2012

Microscopic Role Of Carbon On Mgb2 Wire For Critical Current Density Comparable To Nbti, Jung Ho Kim, Sangjun Oh, Yoon-Uk Heo, Satoshi Hata, Hiroaki Kumakura, Akiyoshi Matsumoto, Masatoshi Mitsuhara, Seyong Choi, Yusuke Shimada, Minoru Maeda, Judith Macmanus-Driscoll, S X. Dou

Australian Institute for Innovative Materials - Papers

Increasing dissipation-free supercurrent has been the primary issue for practical application of superconducting wires. For magnesium diboride, MgB2, carbon is known to be the most effective dopant to enhance high-field properties. However, the critical role of carbon remains elusive, and also low-field critical current density has not been improved. Here, we have undertaken malic acid doping of MgB2 and find that the microscopic origin for the enhancement of high-field properties is due to boron vacancies and associated stacking faults, as observed by high-resolution transmission electron microscopy and electron energy loss spectroscopy. The carbon from the malic acid almost uniformly encapsulates …


Free-Standing Single-Walled Carbon Nanotube/Sno2 Anode Paper For Flexible Lithium-Ion Batteries, Lukman Noerochim, Jia-Zhao Wang, Shulei Chou, David Wexler Jan 2012

Free-Standing Single-Walled Carbon Nanotube/Sno2 Anode Paper For Flexible Lithium-Ion Batteries, Lukman Noerochim, Jia-Zhao Wang, Shulei Chou, David Wexler

Australian Institute for Innovative Materials - Papers

Free-standingsingle-walledcarbonnanotube/SnO2 (SWCNT/SnO2) anodepaper was prepared by vacuum filtration of SWCNT/SnO2 hybrid material which was synthesized by the polyol method. From field emission scanning electron microscopy and transmission electron microscopy, the CNTs form a three-dimensional nanoporous network, in which ultra-fine SnO2 nanoparticles, which had crystallite sizes of less than 5 nm, were distributed, predominately as groups of nanoparticles on the surfaces of singlewalled CNT bundles. Electrochemical measurements demonstrated that the anodepaper with 34 wt.% SnO2 had excellent cyclic retention, with the high specific capacity of 454 mAh g−1 beyond 100 cycles at a current …


Enhanced Hydrogen Storage Properties Of Naalh4 Co-Catalysed With Niobium Fluoride And Single-Walled Carbon Nanotubes, Jianfeng Mao, Zaiping Guo, Hua-Kun Liu Jan 2012

Enhanced Hydrogen Storage Properties Of Naalh4 Co-Catalysed With Niobium Fluoride And Single-Walled Carbon Nanotubes, Jianfeng Mao, Zaiping Guo, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

The effects of single-walled carbon nanotubes (SWCNTs) as a co-catalyst with NbF5 on the dehydrogenation and hydrogenation kinetics of NaAlH4 were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, differential thermal analysis, temperature-programmed desorption, and isothermal hydrogen ab/desorption techniques. It has been revealed that there is a synergistic effect of SWCNTs and NbF5 on the de/rehydrogenation of NaAlH4, which improves the hydrogen de/absorption performance when compared to adding either SWCNTs or NbF5 alone. For example, the apparent activation energy for the first-step and the second-step dehydrogenation of the co-doped NaAlH4 sample is estimated to be 85.9 …


Irradiation Si On Carbon Nanotube Paper As A Flexible Anode Material For Lithium-Ion Batteries, Shulei Chou, Mihail Ionescu, Jia-Zhao Wang, Brad Winton, Hua-Kun Liu Jan 2012

Irradiation Si On Carbon Nanotube Paper As A Flexible Anode Material For Lithium-Ion Batteries, Shulei Chou, Mihail Ionescu, Jia-Zhao Wang, Brad Winton, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Silicon single walled carbon nanotube composite paper was modified by low energy ion implantation using 5i to obtain a flexible composite paper. Raman and FE-SEM results show that structure of SWCNT could be destroyed by the implantation. Electrochemical measurements display that the implanted SI can improve the specific capacity and the reversible capacity of CNT paper. After 50 cycles, the specific capacity of 5Hmplanted CNT paper is 30 per cent higher than the pristine CNT.


Hollow Nitrogen Containing Core/Shell Fibrous Carbon Nanomaterials As Support To Platinum Nanocatalysts And Their Tem Tomography Study, Cuifeng Zhou, Zongwen Liu, Xusheng Du, David Rg Mitchell, Yiu-Wing Mai, Yushan Yan, Simon Peter Ringer Jan 2012

Hollow Nitrogen Containing Core/Shell Fibrous Carbon Nanomaterials As Support To Platinum Nanocatalysts And Their Tem Tomography Study, Cuifeng Zhou, Zongwen Liu, Xusheng Du, David Rg Mitchell, Yiu-Wing Mai, Yushan Yan, Simon Peter Ringer

Australian Institute for Innovative Materials - Papers

Core/shell nanostructured carbon materials with carbon nanofiber (CNF) as the core and a nitrogen (N)-doped graphitic layer as the shell were synthesized by pyrolysis of CNF/polyaniline (CNF/PANI) composites prepared by in situ polymerization of aniline on CNFs. High-resolution transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared and Raman analyses indicated that the PANI shell was carbonized at 900 degress C. Platinum (Pt) nanoparticles were reduced by formic acid with catalyst supports. Compared to the untreated CNF/ PANI composites, the carbonized composites were proven to be better supporting materials for the Pt nanocatalysts and showed superior performance as catalyst …


Power To You: Carbon Nanotube Muscles Are Going Strong, Geoffrey M. Spinks Jan 2012

Power To You: Carbon Nanotube Muscles Are Going Strong, Geoffrey M. Spinks

Australian Institute for Innovative Materials - Papers

Just on a year ago my colleagues and I announced our discovery that carbon nanotube yarns could be made to twist and rotate at great speeds when electrically stimulated. In this way we had created "artificial muscles" that could change their shape in response to stimulus.