Engineering Commons^™

Linearized Theory Of Peridynamic States, S. A. Silling

US Department of Energy Publications

A state-based peridynamic material model describes internal forces acting on a point in terms of the collective deformation of all the material within a neighborhood of the point. In this paper, the response of a state-based peridynamic material is investigated for a small deformation superposed on a large deformation. The appropriate notion of a small deformation restricts the relative displacement between points, but it does not involve the deformation gradient (which would be undefined on a crack). The material properties that govern the linearized material response are expressed in terms of a new quantity called the modulus state. This determines …

Nebraska Statewide Wind Integration Study: Executive Summary April 2008 – January 2010, Enernex Corporation Knoxville, Tennessee, Ventyx Atlanta, Georgia, Nebraska Power Association Lincoln, Nebraska

US Department of Energy Publications

Wind generation is a source of electric energy that, in sufficient quantity, can cause concern for the operation of the bulk power system because of the variability and uncertainty of the wind. Most short-term planning and operational functions supporting the electric power grid are centered on supply resources that have capacity attributes – i.e. they can be dispatched (controlled up and down) to a specified power level for a specified period of time. The need to maintain very high levels of system reliability reinforces the preference in operations toward resources having capacity attributes. Wind generation usually has relatively low capacity …

Validation Of A Model For Static And Dynamic Recrystallization In Metals, Arthur Brown, Douglas Bammann

US Department of Energy Publications

In this paper, modifications are proposed to a phenomenological plasticity model to account for the evolution of recrystallization and the resultant softening behavior. The novel model includes internal state variables representing dislocation density and the spacing between geometrically necessary subgrain boundaries. In order to capture both single and multiple peak recrystallization, the model tracks the evolution of recrystallized volume fractions for multiple cycles of recrystallization, and has a set of state variables for each volume fraction. A rule of mixtures is used to determine the average stress. The model is capable of capturing static recrystallization as well as both single …

Fractionation Of Oxygen Isotopes In Phosphate During Its Interactions With Iron Oxides, Deb P. Jaisi, Ruth E. Blake, Ravi K. Kukkadapu

US Department of Energy Publications

Iron (III) oxides are ubiquitous in near-surface soils and sediments and interact strongly with dissolved phosphates via sorption, co-precipitation, mineral transformation and redox-cycling reactions. Iron oxide phases are thus, an important reservoir for dissolved phosphate, and phosphate bound to iron oxides may reflect dissolved phosphate sources as well as carry a history of the biogeochemical cycling of phosphorus (P). It has recently been demonstrated that dissolved inorganic phosphate (DIP) in rivers, lakes, estuaries and the open ocean can be used to distinguish different P sources and biological reaction pathways in the ratio of ¹⁸O/¹⁶O (δ¹⁸O …

Microbial And Mineralogical Characterizations Of Soils Collected From The Deep Biosphere Of The Former Homestake Gold Mine, South Dakota, Gurdeep Rastogi, Shariff Osman, Ravi K. Kukkadapu, Mark Engelhard, Parag A. Vaishampayan, Gary L. Andersen, Rajesh K. Sani

US Department of Energy Publications

A microbial census on deep biosphere (1.34 km depth) microbial communities was performed in two soil samples collected from the Ross and number 6Winze sites of the former Homestake gold mine, Lead, South Dakota using high-density 16S microarrays (PhyloChip). Soil mineralogical characterization was carried out using X-ray diffraction, X-ray photoelectron, and Mössbauer spectroscopic techniques which demonstrated silicates and iron minerals (phyllosilicates and clays) in both samples. Microarray data revealed extensive bacterial diversity in soils and detected the largest number of taxa in Proteobacteria phylum followed by Firmicutes and Actinobacteria. The archael communities in the deep gold mine environments were …

Microbial Reduction Of Uranium Under Iron- And Sulfate-Reducing Conditions: Effect Of Amended Goethite On Microbial Community Composition And Dynamics, H.S. Moon, L. Mcguinness, Ravi K. Kukkadapu, A.D. Peacock, John Komlos, L.J. Kerkhof, P.E. Long, Peter R. Jaffe

US Department of Energy Publications

There is a growing need for a better understanding of the biogeochemical dynamics involved in microbial U(VI) reduction due to an increasing interest in using biostimulation via electron donor addition as a means to remediate uranium contaminated sites. U (VI) reduction has been observed to be maximized during iron-reducing conditions and to decrease upon commencement of sulfate-reducing conditions. There are many unknowns regarding the impact of iron/sulfate biogeochemistry on U(VI) reduction. This includes Fe(III) availability as well as the microbial community changes, including the activity of iron-reducers during the uranium biostimulation period even after sulfate reduction becomes dominant. Column experiments …

Role Of Outer-Membrane Cytochromes Mtrc And Omca In The Biomineralization Of Ferrihydrite By Shewanella Oneidensis Mr-1, C. L. Reardon, Alice Dohnalkova, P. Nachimuthu, David Kennedy, D. A. Saffarini, B. W. Arey, L. Shi, Zheming Wang, D. Moore, J. S. Mclean, D. Moyles, M. J. Marshall, John M. Zachara, James K. Fredrickson, A. S. Beliaev

US Department of Energy Publications

In an effort to improve the understanding of electron transfer mechanisms at the microbe–mineral interface, Shewanella oneidensis MR-1 mutants with in-frame deletions of outer-membrane cytochromes (OMCs), MtrC and OmcA, were characterized for the ability to reduce ferrihydrite (FH) using a suite of microscopic, spectroscopic, and biochemical techniques. Analysis of purified recombinant proteins demonstrated that both cytochromes undergo rapid electron exchange with FH in vitro with MtrC displaying faster transfer rates than OmcA. Immunomicroscopy with cytochrome-specific antibodies revealed that MtrC co-localizes with iron solids on the cell surface while OmcA exhibits a more diffuse distribution over the cell surface. After 3-day …

Load-Locked Dc High Voltage Gaas Photogun With An Inverted-Geometry Ceramic Insulator, P. A. Adderley, J. Clark, J. Grames, J. Hansknecht, K. Surles-Law, D. Machie, M. Poelker, M. L. Stutzman, R. Suleiman

US Department of Energy Publications

A new dc high voltage spin-polarized photoelectron gun has been constructed that employs a compact inverted-geometry ceramic insulator. Photogun performance at 100 kV bias voltage is summarized.

I. INTRODUCTION

All of the nuclear physics experiments conducted at the Continuous Electron Beam Accelerator Facility (CEBAF) at the Thomas Jefferson National Accelerator Facility (Jefferson Lab) receive electron beams from a dc high voltage spin-polarized GaAs photoemission gun. Since 1995, the year the first polarized electron source was installed at CEBAF [1], there have been four different photogun designs with each new gun an improvement over its predecessor. The most recent design employs …

Valence-Shell Photoionization Of The Chlorinelike Ca3+ Ion, Ghassan A. Alna’Washi, M. Lu, M. Habibi, R. A. Phaneuf, A. L. D. Kilcoyne, A. S. Schlachter, C. Cisneros, B. M. Mclaughlin

US Department of Energy Publications

Absolute photoionization measurements were performed for a mixture of ²P^o_3/2 ground-state and ²P^o_1/2 metastable-state Ca³⁺ ions over the photon energy range 65.7–104.6 eV by merging an ion beam with a beam of monochromatized synchrotron radiation. The ionization threshold energy of the ²P^o_3/2 ground state was measured to be 67.063 ± 0.015 eV, which is 0.207 eV lower than the value tabulated in the NIST database. Most of the observed resonances associated with multiple Rydberg series of autoionizing states have been assigned spectroscopically using the quantum defect form of the Rydberg …

Confinement Resonances In Photoionization Of Xe@C+60, A. L. D. Kilcoyne, A. Aguilar, A. Muller, S. Schippers, C. Cisneros, G. Alna’Washi, N. B. Aryal, K. K. Baral, D. A. Esteves, C. M. Thomas, R. A. Phaneuf

US Department of Energy Publications

Experimental evidence is presented for confinement resonances associated with photoabsorption by a Xe atom in a C₆₀ cage. The giant 4d resonance in photoionization of Xe is predicted to be redistributed into four components due to multipath interference of photoelectron waves reflected by the cage. The measurements were made in the photon energy range 60–150 eV by merging a beam of synchrotron radiation with a mass/charge selected Xe@C⁺₆₀ ion beam. The phenomenon was observed in the Xe@C³⁺₅₈ product ion channel.

Ellipsometric Study Of Single-Crystal Γ-Inse From 1.5 To 9.2 Ev, S. G. Choi, D. E. Aspnes, A. L. Fuchser, C. Martinez-Tomas, V. Muñoz Sanjosé, D. H. Levi

US Department of Energy Publications

We report the component E ┴ c of the pseudodielectric-function tensor <ε(E)> = <ε₁(E)> + i< ε₂(E)> of γ-phase single-crystal InSe, obtained from 1.5 to 9.2 eV by vacuum-ultraviolet spectroscopic ellipsometry with the sample at room temperature. Overlayer artifacts were reduced as far as possible by measuring fresh surfaces prepared by cleavage. Accurate critical-point energies of observed structures were obtained by a combined method of spectral analysis.